IP Library Granted Patent US 12708683
Granted Patent B2
US 12708683 · App. 18/326,338 · Granted Aug 18, 2026

Surface disinfection with PR

Inventor: John N. Harris (Seattle, WA)
Assignee: THE BOEING COMPANY
A61L2/088C09K11/02C09K11/77064A61L2103/05
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Quick Facts
Patent No.
US 12708683
App. No.
18/326,338
Granted
Aug 18, 2026
Kind
B2
Abstract

Described herein are methods for disinfecting surfaces using a photon-emitting inorganic phosphor-doped substrate material. Methods for preparing the photon-emitting inorganic phosphor-doped substrate materials are additionally described.

Claims (27)

1 . A method for disinfecting a surface, comprising:

exposing a surface of a substrate material comprising an inorganic phosphor dopant to a UV light source;

wherein the inorganic phosphor dopant comprises Ca 2 Al 2 SiO 7 doped with Pr 3+ ;

wherein said exposing causes said inorganic phosphor dopant in said substrate material to emit photons; and

wherein said photons irradiate said surface, thereby disinfecting said surface.

2 . The method of claim 1 , wherein said inorganic phosphor dopant in said substrate material emits photons with a wavelength of light between about 200 nm and 280 nm.

3 . The method of claim 1 , wherein said UV light source has a wavelength between about 160 nm and 320 nm.

4 . The method of claim 1 , wherein said inorganic phosphor dopant further comprises a metal oxide or metal fluoride comprising a rare earth ion selected from the group consisting of Ce 3+ , Eu 3+ , Eu 2+ , Gd 3+ , Tb 3+ , and Dy 3+ , or a mixture thereof.

5 . The method of claim 4 , wherein said metal oxide is selected from the group consisting of silicates, phosphates, borates, oxides, oxynitrides, oxysulfides, and aluminates, or combinations thereof.

6 . The method of claim 1 , wherein said substrate material comprises one or more synthetic polymers.

7 . The method of claim 1 , wherein said exposing said substrate material comprising said inorganic phosphor dopant to a UV light source is for a time sufficient to charge said inorganic phosphor dopant in said substrate material.

8 . A photon-emitting inorganic phosphor-doped substrate material, comprising:

a substrate material comprising an inorganic phosphor dopant, wherein said inorganic phosphor dopant in said substrate material is capable of emitting photons upon exposure of a surface of said photon-emitting inorganic phosphor-doped substrate material to a UV light source; and

wherein the inorganic phosphor dopant comprises Ca 2 Al 2 SiO 7 doped with Pr 3+ .

9 . The photon-emitting inorganic phosphor-doped substrate material of claim 8 , wherein said substrate material comprises one or more synthetic polymers.

10 . The photon-emitting inorganic phosphor-doped substrate material of claim 9 , wherein said substrate material comprises a material selected from the group consisting of fluorinated thermoplastics, thermosetting resins, and electronegative resins.

11 . The photon-emitting inorganic phosphor-doped substrate material of claim 9 , wherein said substrate material further comprises a material selected from the group consisting of tetrafluoroethylene, polyvinyl fluoride, polyurethane, polyester, epoxy, phenolic, vinyl ester, polyamide, polyamide-imide, polyether imide, polyvinylchloride, polyether ketone ketone, polycarbonate, polyphenylsulphone, polymethylmethacrylate, polyacrylate, and benzoxazine.

12 . The photon-emitting inorganic phosphor-doped substrate material of claim 8 , wherein said inorganic phosphor dopant further comprises a metal oxide or metal fluoride comprising a rare earth ion selected from the group consisting of Ce 3+ , Eu 3+ , Eu 2+ , Gd 3+ , Tb 3+ , and Dy 3+ , or a mixture thereof.

13 . The photon-emitting inorganic phosphor-doped substrate material of claim 8 , wherein said inorganic phosphor dopant in said substrate material is capable of emitting photons with a wavelength of light between about 200 nm and 280 nm upon exposure of a surface of said photon-emitting inorganic phosphor-doped substrate material to a UV light source.

14 . A method for preparing a photon-emitting material for surface disinfection, comprising:

contacting a substrate material with an inorganic phosphor dopant to prepare a photon-emitting inorganic phosphor-doped substrate material, wherein said inorganic phosphor dopant in said photon-emitting inorganic phosphor-doped substrate material is capable of emitting photons upon exposure of a surface of said photon-emitting inorganic phosphor-doped substrate material to a UV light source; and

wherein the inorganic phosphor dopant comprises Ca 2 Al 2 SiO 7 doped with Pr 3+ .

15 . The method of claim 14 , wherein said inorganic phosphor dopant in said photon-emitting inorganic phosphor-doped substrate material is capable of emitting photons with a wavelength of light between about 200 nm and 280 nm.

16 . The method of claim 14 , wherein said inorganic phosphor dopant further comprises a metal oxide or metal fluoride comprising a rare earth ion selected from the group consisting of Ce 3+ , Eu 3+ , Eu 2+ , Gd 3+ , Tb 3+ , and Dy 3+ , or a mixture thereof.

17 . The method of claim 16 , wherein said metal oxide is selected from the group consisting of silicates, phosphates, borates, oxides, oxynitrides, oxysulfides, and aluminates, or combinations thereof.

18 . The method of claim 14 , wherein said substrate material comprises one or more synthetic polymers.

19 . The method of claim 18 , wherein said substrate material comprises a material selected from the group consisting of fluorinated thermoplastics, thermosetting resins, and electronegative resins.