Organic light emitting device
Provided is an organic light emitting device comprising: an anode, a cathode, a light emitting layer between the anode and the cathode, an electron inhibition layer between the anode and the light emitting layer, and a hole transport layer between the electron inhibition layer and the anode, wherein the light emitting layer comprises a compound of the following Chemical Formula 1, a compound of the following Chemical Formula 2, and a compound of the following Chemical Formula 3 as defined in the specification: having improved driving voltage, efficiency, and lifetime.
1 . An organic light emitting device comprising:
an anode,
a cathode,
a light emitting layer between the anode and the cathode,
an electron inhibition layer between the anode and the light emitting layer, and
a hole transport layer between the electron inhibition layer and the anode,
wherein the light emitting layer comprises a compound of the following Chemical Formula 1, a compound of the following Chemical Formula 2, and a compound of the following Chemical Formula 3:
wherein in Chemical Formula 1:
Y 1 is O or S;
each X 1 is independently CH, or N, provided that at least one of X 1 is N;
L 1 is a direct bond, a substituted or unsubstituted C 6-60 arylene, or a substituted or unsubstituted C 2-60 heteroarylene containing any one or more selected from the group consisting of N, O and S;
Ar 1 and Ar 2 are each independently phenyl, biphenylyl, dibenzofuranyl, carbazol-9-yl, or (phenyl) carbazol-9-yl, wherein the Ar 1 and Ar 2 are each independently unsubstituted or substituted with at least one deuterium;
R 1 is hydrogen, deuterium, a substituted or unsubstituted C 6-60 alkyl, a substituted or unsubstituted C 6-60 aryl, or a substituted or unsubstituted C 2-60 heteroaryl containing any one or more selected from the group consisting of N, O and S; and
a is an integer of 1 to 7;
wherein in Chemical Formula 2:
Ar 3 and Ar 4 are each independently a substituted or unsubstituted C 6-60 aryl or a substituted or unsubstituted C 2-60 heteroaryl containing any one or more selected from the group consisting of N, O and S;
R 2 and R 3 are each independently hydrogen, deuterium, a substituted or unsubstituted C 6-60 aryl, or a substituted or unsubstituted C 2-60 heteroaryl containing any one or more selected from the group consisting of N, O and S; and
b and c are each independently an integer of 1 to 7;
wherein in Chemical Formula 3;
B is a benzene ring fused with two adjacent pentagonal rings;
each X 2 is independently CH or N, provided that at least one of X 2 is N;
L 2 is a direct bond or phenylene, provided that when L 2 is phenylene, it is unsubstituted or substituted with at least one deuterium
Ar 5 and Ar 6 are each independently a substituted or unsubstituted C 6-60 aryl or a substituted or unsubstituted C 2-60 heteroaryl containing any one or more selected from the group consisting of N, O and S; and
C is the following Chemical Formula 4-1 or 4-2;
wherein in Chemical Formulas 4-1 and 4-2:
the dotted line is a bond that is fused with B;
Y 2 is CRR′, C(CH 3 ) 2 , O, S, or NAr 7 ,
wherein R and R′ are each independently a substituted or unsubstituted C 6-60 alkyl, or a substituted or unsubstituted C 6-60 aryl, and
Ar 7 is a substituted or unsubstituted C 6-60 aryl, or a substituted or unsubstituted C 2-60 heteroaryl containing any one or more selected from the group consisting of N, O and S;
R 4 is hydrogen, deuterium, a substituted or unsubstituted C 6-60 aryl, or a substituted or unsubstituted C 2-60 heteroaryl containing any one or more selected from the group consisting of N, O and S; and
d is an integer of 1 to 10.
2 . The organic light emitting device according to claim 1 , wherein:
the Chemical Formula 1 is any one of the following Chemical Formulas 1-1 to 1-4:
wherein in Chemical Formulas 1-1 to 1-4:
Y 1 , X 1 , L 1 , Ar 1 , Ar 2 , R 1 , and a are as defined in claim 1 .
3 . The organic light emitting device according to claim 1 , wherein:
two or three of X 1 are N.
4 . The organic light emitting device according to claim 1 , wherein:
L 1 is a direct bond.
5 . The organic light emitting device according to claim 1 , wherein:
R 1 is phenyl, biphenylyl, (phenyl) biphenylyl, terphenylyl, naphthyl, phenanthrenyl, triphenylenyl, dimethylfluorenyl, spirobifluorenyl, dibenzofuranyl, dibenzothiophenyl, carbazol-9-yl, (phenyl) carbazol-9-yl, (diphenyl) carbazol-9-yl, 9-phenyl-9H-carbazolyl, 12-phenyl-11,12-dihydroindolo[2,3-a]carbazol-11-yl, or 1,1-dimethyl-1,3-dihydroindeno[2,1-b]carbazol-3-yl; and
the R 1 is unsubstituted or substituted with at least one deuterium.
6 . The organic light emitting device according to claim 1 , wherein:
the compound of Chemical Formula 1 is any one compound selected from the group consisting of the following compounds:
7 . The organic light emitting device according to claim 1 , wherein:
the Chemical Formula 2 is the following Chemical Formula 2-1:
wherein in Chemical Formula 2-1;
Ar 3 , Ar 4 , R 3 , R 4 , b and c are as defined in claim 1 .
8 . The organic light emitting device according to claim 1 , wherein:
Ar 3 and Ar 4 are each independently phenyl, biphenylyl, terphenylyl, naphthyl, dimethylfluorenyl, dibenzofuranyl, or dibenzothiophenyl.
9 . The organic light emitting device according to claim 1 , wherein:
R 2 and R 3 are each independently hydrogen or phenyl.
10 . The organic light emitting device according to claim 9 , wherein:
one of R 2 and R 3 is phenyl and the rest is hydrogen, or both R 2 and R 3 are hydrogen.
11 . The organic light emitting device according to claim 1 , wherein:
the compound of Chemical Formula 2 is any one compound selected from the group consisting of the following compounds:
12 . The organic light emitting device according to claim 1 ,
wherein:
Ar 5 and Ar 6 are each independently phenyl, biphenylyl, (phenyl) biphenylyl, triphenylenyl, dimethylfluorenyl, dibenzofuranyl, dibenzothiophenyl, carbazol-9-yl, or 9-phenyl-9H-carbazolyl; and
the Ar 5 and Ar 6 are each independently unsubstituted or substituted with at least one deuterium.
13 . The organic light emitting device according to claim 1 , wherein:
Y 2 is C(CH 3 ) 2 , C(C 6 C 5 ) 2 , O, S, or NAr 7 ,
wherein Ar 7 is phenyl, biphenylyl, terphenylyl, dibenzofuranyl, or dibenzothiophenyl, with the Ar 7 being unsubstituted or substituted with at least one deuterium.
14 . The organic light emitting device according to claim 1 , wherein:
R 4 is hydrogen or deuterium.
15 . The organic light emitting device according to claim 1 , wherein:
the compound of Chemical Formula 3 is any one compound selected from the group consisting of the following compounds: