Resin composition
Resin compositions including (A) a compound containing a radical polymerizable group having a carbodiimide structure, and at least any one of (B) a compound containing a radical polymerizable group not having a carbodiimide structure and (C) a thermosetting resin can afford a cured product having excellent mechanical strength and plating adhesion property.
1 . A resin composition, comprising
(A) at least one compound containing a radical polymerizable group having a carbodiimide structure, and
(B) at least one compound containing a radical polymerizable group not having a carbodiimide structure, and
optionally further comprising
(C) at least one thermosetting resin,
wherein the component (A) comprises a compound containing a radical polymerizable group represented by formula (1):
wherein,
each R independently represents a hydrogen atom or a methyl group;
each X 1 independently represents a carbonyl group, a methylene group, a phenylene group, or a phenylene-methylene group;
each X 2 independently represents a saturated divalent hydrocarbon group having 2 to 4 carbon atoms;
each Y independently represents a saturated divalent hydrocarbon group having 2 to 30 carbon atoms optionally having a substituent group, or an unsaturated divalent hydrocarbon group having 2 to 30 carbon atoms optionally having a substituent group;
each Z independently represents a saturated divalent hydrocarbon group having 2 to 300 carbon atoms optionally having a substituent group, or an unsaturated divalent hydrocarbon group having 2 to 300 carbon atoms optionally having a substituent group;
each a independently represents 0, or an integer of 1 or more;
each b independently represents an integer of 1 or more;
each c independently represents an integer of 0 or more; and
d represents an integer of 1 or more, and
wherein the component (B) comprises at least one selected from the group consisting of a modified polyphenylene ether resin, a polyfunctional (meth) acryloyl group-containing compound, a polyfunctional vinylaryl group-containing compound, a polyfunctional allyl group-containing compound, and a maleimide compound.
2 . The resin composition according to claim 1 , wherein a content of the component (A) relative to 100% by mass of nonvolatile components in the resin composition is in a range of 0.05% by mass to 10% by mass.
3 . The resin composition according to claim 1 , wherein the component (C) comprises an epoxy resin.
4 . The resin composition according to claim 3 , wherein the component (C) further comprises an active ester type curing agent.
5 . The resin composition according to claim 3 , wherein the component (C) further comprises a phenol type curing agent.
6 . The resin composition according to claim 1 , further comprising (D) an inorganic filler.
7 . The resin composition according to claim 6 , wherein the component (D) is silica.
8 . The resin composition according to claim 6 , wherein a content of the component (D) relative to 100% by mass of nonvolatile components in the resin composition is 40% by mass or more.
9 . The resin composition according to claim 1 , further comprising a phenoxy resin.
10 . The resin composition according to claim 1 , wherein a dielectric dissipation factor (Df) of a cured product of the resin composition is 0.006 or less when measured at 5.8 GHz and 23° C.
11 . The resin composition according to claim 1 , wherein an elongation at a breaking point of a cured product of the resin composition is 1.2% or more when measured at 23° C.
12 . The resin composition according to claim 1 , wherein the resin composition is for forming an insulating layer to form a conductive layer.
13 . The resin composition according to claim 1 , wherein the resin composition is for forming an insulating layer of a printed wiring board.
14 . A cured product of the resin composition according to claim 1 .
15 . A sheet-like laminate material comprising the resin composition according to claim 1 .
16 . A resin sheet comprising:
a support; and
a resin composition layer formed on the support, the resin composition layer being formed from the resin composition according to claim 1 .
17 . A printed wiring board comprising an insulating layer composed of a cured product of the resin composition according to claim 1 .
18 . A semiconductor device comprising the printed wiring board according to claim 17 .
19 . The resin composition according to claim 1 , wherein, in formula (1), c represents an integer of 1 or more.
20 . The resin composition according to claim 19 , wherein, in formula (1), each Z independently represents a divalent hydrocarbon group having 300 or less carbon atoms and having a structural unit selected from formulae (Z1) to (Z8):
21 . The resin composition according to claim 19 , wherein, in formula (1), each Z independently represents a divalent hydrocarbon group having 300 or less carbon atoms and having a structural unit represented by formula (Z1):
22 . The resin composition according to claim 19 , wherein, in formula (1), each Z independently represents a divalent hydrocarbon group having 300 or less carbon atoms represented by formula (Z1′):
wherein,
n z represents an integer of 1 or more; and
* indicates a bonding site.
23 . The resin composition according to claim 1 , wherein the component (A) comprises a compound represented by formula (S5):
wherein,
b′ represents an average degree of polymerization of a carbodiimide group;
d′ represents an average degree of polymerization of a combined unit of polybutadiene and polycarbodiimide; and
e′ represents an average degree of polymerization of a butadiene unit.