IP Library Granted Patent US 12709782
Granted Patent B2
US 12709782 · App. 18/037,344 · Granted Aug 18, 2026

Ferritic stainless steel sheet and production method

Inventors: Ryo Kobayashi (Tokyo, JP); Masaharu Hatano (Tokyo, JP)
Assignee: NIPPON STEEL STAINLESS STEEL CORPORATION
C21D9/46C21D8/1233C21D8/1272C22C38/001C22C38/002C22C38/02C22C38/04C22C38/06C22C38/22C21D2201/05C21D2211/005C22C2202/02
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Quick Facts
Patent No.
US 12709782
App. No.
18/037,344
Granted
Aug 18, 2026
Kind
B2
Abstract

There is provided a ferritic stainless steel sheet including a magnetized area fraction of 50% or more wherein the ferritic stainless steel sheet chemical composition includes, in mass %: C: 0.015% or less, Si: 3.0% or less, Mn: 1.0% or less, S: 0.0040% or less, P: 0.08% or less, Al: 0.80% or less, N: 0.030% or less, Cr: 15.0 to 25.0%, Mo: 0.5 to 3.0%, Ti: 0 to 0.50%, Nb: 0 to 0.50%, Ni: 0 to 0.50%, Cu: 0% or more to less than 0.1%, Zr: 0 to 1.0%, V: 0 to 1.0%, REM: 0 to 0.05%, and B: 0 to 0.01%, with the balance: Fe and impurities, and satisfies Formula (i): 0.10≤Ti+Nb≤0.50.

Claims (64)

1 . A ferritic stainless steel sheet, wherein

a chemical composition consists of, in mass %:

C: 0.015% or less,

Si: 3.0% or less,

Mn: 1.0% or less,

S: 0.0040% or less,

P: 0.08% or less,

Al: 0.80% or less,

N: 0.030% or less,

Cr: 15.0 to 25.0%,

Mo: 0.5 to 3.0%,

Ti: 0 to 0.50%,

Nb: 0 to 0.50%,

Ni: 0 to 0.50%,

Cu: 0% or more to less than 0.1%,

Zr: 0 to 1.0%,

V: 0 to 1.0%,

REM: 0 to 0.05%, and

B: 0 to 0.01%,

with the balance: Fe and impurities, and

satisfies Formula (i) shown below:

0.10≤Ti+Nb≤0.50  (i)

where symbols of elements in the formula indicate contents (mass %) of the elements contained in the steel, and when an element is not contained, zero will be set to the corresponding symbol;

a maximum grain size of grains is 343 μm or more; and

the ferritic stainless steel sheet comprises a magnetized area fraction of 70% or more, wherein the magnetized area fraction is an area fraction of a magnetized region, the magnetized region being determined by the following steps using a magnetic domain observation microscope:

(a) an amount of change in reflection light intensity is measured in a state where no magnetic field is applied to a sample, and a threshold is specified for an amount of change in reflection light intensity with which 99% of an observation region is determined to be unmagnetized;

(b) with a magnetic field of 1000 Oe applied to the sample, a region having an amount of change in reflection light intensity exceeding the specified threshold of step (a) is extracted as a magnetized region; and

(c) the observation is performed in three visual fields with a magnification within a range of x1000 to x2500, and

in a rolling direction crystal orientation,

F1 that is given by Formula (iii) shown below and is a ratio between a total area S <00> of grains having orientations parallel to a <001> direction and a total area S 111> of grains having orientations parallel to a <111> direction is 5.0 or more:

F1=S <001> /S <111>   (iii)

2 . The ferritic stainless steel sheet according to claim 1 , wherein the chemical composition contains, in mass %,

Si: 0.60% or less.

3 . The ferritic stainless steel sheet according to claim 1 , wherein the chemical composition contains one or more elements selected from, in mass %:

Ni: 0.05 to 0.50%,

Cu: 0.01% or more to less than 0.1%,

Zr: 0.01 to 1.0%,

V: 0.01 to 1.0%,

REM: 0.005 to 0.05%, and

B: 0.0002 to 0.01%.

4 . The ferritic stainless steel sheet according to claim 1 , wherein

a pitting resistance equivalent number PREN that is calculated by Formula (ii) shown below is 20.0 or more:

PREN=Cr+3.3Mo+16N  (ii)

where symbols of elements in Formula (ii) shown above indicate contents (mass %) of the elements contained in the steel, and when an element is not contained, zero will be set to the corresponding symbol.

5 . The ferritic stainless steel sheet according to claim 1 , wherein a maximum grain size of grains observed is 500 μm or more.

6 . The ferritic stainless steel sheet according to claim 2 , wherein the chemical composition contains one or more elements selected from, in mass %:

Ni: 0.05 to 0.50%,

Cu: 0.01% or more to less than 0.1%,

Zr: 0.01 to 1.0%,

V: 0.01 to 1.0%,

REM: 0.005 to 0.05%, and

B: 0.0002 to 0.01%.

7 . The ferritic stainless steel sheet according to claim 2 , wherein

a pitting resistance equivalent number PREN that is calculated by Formula (ii) shown below is 20.0 or more:

PREN=Cr+3.3Mo+16N  (ii)

where symbols of elements in Formula (ii) shown above indicate contents (mass %) of the elements contained in the steel, and when an element is not contained, zero will be set to the corresponding symbol.

8 . The ferritic stainless steel sheet according to claim 3 , wherein

a pitting resistance equivalent number PREN that is calculated by Formula (ii) shown below is 20.0 or more:

PREN=Cr+3.3Mo+16N  (ii)

where symbols of elements in Formula (ii) shown above indicate contents (mass %) of the elements contained in the steel, and when an element is not contained, zero will be set to the corresponding symbol.

9 . The ferritic stainless steel sheet according to claim 6 , wherein

a pitting resistance equivalent number PREN that is calculated by Formula (ii) shown below is 20.0 or more:

PREN=Cr+3.3Mo+16N  (ii)

where symbols of elements in Formula (ii) shown above indicate contents (mass %) of the elements contained in the steel, and when an element is not contained, zero will be set to the corresponding symbol.