Selective recovery of Li
A method for selectively removing Li from an input material comprising Li and one or more transition metals, comprising the steps of: contacting said input material with a leaching medium comprising formic acid; and leaching Li from the input material to form a leachate; wherein the concentration of formic acid in the leaching medium is at least 70 wt. %.
1 . A method for selectively removing Li from an input material comprising Li and one or more transition metals, comprising the steps of:
contacting said input material with a leaching medium comprising formic acid and a sulphate salt; and
leaching Li from the input material to form a leachate;
wherein the concentration of formic acid in the leaching medium is at least 70 wt. %.
2 . A method as claimed in claim 1 , wherein the input material comprises one or more of: nickel, manganese and/or cobalt, in addition to Li.
3 . A method as claimed in claim 1 , wherein the input material comprises nickel, manganese and cobalt, in addition to Li.
4 . A method as claimed in claim 1 , wherein the concentration of formic acid in the leaching medium is at least 80 wt. %.
5 . A method as claimed in claim 1 , wherein the concentration of formic acid in the leaching medium is at least 95 wt. %.
6 . A method as claimed in claim 1 , wherein the leaching medium comprises H 2 O 2 .
7 . A method as claimed in claim 1 , wherein the step of leaching Li from the input material to form a leachate involves heating to a temperature of at least 60° C.
8 . A method as claimed in claim 1 , wherein the step of leaching Li from the input material to form a leachate involves heating to a temperature of at least 80° C.
9 . A method as claimed in claim 1 , wherein the step of leaching Li from the input material to form a leachate involves heating to at least the boiling point of the leaching medium.
10 . A method as claimed in claim 1 , wherein the step of leaching Li from the input material to form a leachate involves heating under reflux.
11 . A method as claimed in claim 1 , wherein the leaching medium includes a non-metal sulphate salt.
12 . A method as claimed in claim 1 , wherein the leaching medium includes (NH 4 ) 2 SO 4 .
13 . A method as claimed in claim 1 , wherein the leaching is carried out with agitation of the input material.
14 . A method as claimed in claim 13 , wherein the agitation is carried out with stirring.
15 . A method as claimed in claim 13 , wherein the agitation is carried out with ultrasound.