Flexographic printing plate precursor
An object of the present invention is to provide a flexographic printing plate precursor which exhibits excellent rear end ink receptivity and microcell reproducibility in a case of being used for a flexographic printing plate. The flexographic printing plate precursor of the present invention includes a support and a photosensitive layer disposed above the support, in which all of the following conditions A and B are satisfied. Condition A: in a case where R=(Ef/Eb)×(t−0.6)/0.54, a value of R is 12 or more and 30 or less, Condition B: Ef is 5,000 or more, Here, Eb is a back exposure amount (unit: mJ/square centimeter), and refers to an exposure amount at which a relief depth is 600 μm, Ef is a main exposure amount (unit: mJ/square centimeter), and refers to an exposure amount at which a difference in height between an end part as a convex portion and a central part as a concave portion in a case of forming an image area consisting of a 200 μm convex thin line reaches 4 μm, and t refers to a thickness of the flexographic printing plate precursor from a bottom surface of the support to a surface of the photosensitive layer.
1 . A flexographic printing plate precursor comprising:
a support; and
a photosensitive layer disposed above the support,
wherein the photosensitive layer contains at least water-dispersible particles, a binder, a monomer, a photopolymerization initiator, and a polymerization inhibitor, and
the flexographic printing plate precursor satisfies all of the following conditions A and B,
Condition A: in a case where R=(Ef/Eb)×(t−0.6)/0.54, a value of R is 12 or more and 30 or less,
Condition B: Ef is 5,000 or more,
here,
Eb is a back exposure amount (unit: mJ/square centimeter), and refers to an exposure amount at which a relief depth is 600 μm,
Ef is a main exposure amount (unit: mJ/square centimeter), and refers to an exposure amount at which a difference in height between an end part as a convex portion and a central part as a concave portion in a case of forming an image area consisting of a 200 μm convex thin line reaches 4 μm, and
t refers to a thickness of the flexographic printing plate precursor from a bottom surface of the support to a surface of the photosensitive layer.
2 . The flexographic printing plate precursor according to claim 1 ,
wherein, in a case where a content (% by mass) of the monomer contained in the photosensitive layer is denoted as M and a content (% by mass) of the photopolymerization initiator contained in the photosensitive layer is denoted as I, the following condition C is satisfied,
15≤ M×I 1/2 ≤28. Condition C:
3 . The flexographic printing plate precursor according to claim 2 ,
wherein the value of R indicated by the condition A is 16 or more and 30 or less.
4 . The flexographic printing plate precursor according to claim 2 ,
wherein a value of Ef indicated by the condition B is 7,300 or more.
5 . The flexographic printing plate precursor according to claim 2 ,
wherein the binder contains at least one type of non-fluid rubber.
6 . The flexographic printing plate precursor according to claim 5 ,
wherein the non-fluid rubber is at least one selected from the group consisting of natural rubber, isoprene rubber, butadiene rubber, styrene butadiene rubber, butyl rubber, and ethylene-propylene rubber.
7 . The flexographic printing plate precursor according to claim 2 ,
wherein the binder contains at least one type of thermoplastic elastomer.
8 . The flexographic printing plate precursor according to claim 2 ,
wherein the water-dispersible particles are composed of a polymer obtained by polymerizing at least one monomer selected from the group consisting of isoprene, butadiene, styrene, butyl, ethylene, propylene, acrylic acid ester, and methacrylic acid ester.
9 . The flexographic printing plate precursor according to claim 2 ,
wherein a content of the polymerization inhibitor is 0.01% by mass or more.
10 . The flexographic printing plate precursor according to claim 2 ,
wherein a content of the polymerization inhibitor is 0.01% by mass or more and 0.5% by mass or less.
11 . The flexographic printing plate precursor according to claim 1 ,
wherein the value of R indicated by the condition A is 16 or more and 30 or less.
12 . The flexographic printing plate precursor according to claim 11 ,
wherein a value of Ef indicated by the condition B is 7,300 or more.
13 . The flexographic printing plate precursor according to claim 11 ,
wherein the binder contains at least one type of non-fluid rubber.
14 . The flexographic printing plate precursor according to claim 1 ,
wherein a value of Ef indicated by the condition B is 7,300 or more.
15 . The flexographic printing plate precursor according to claim 1 ,
wherein the binder contains at least one type of non-fluid rubber.
16 . The flexographic printing plate precursor according to claim 15 ,
wherein the non-fluid rubber is at least one selected from the group consisting of natural rubber, isoprene rubber, butadiene rubber, styrene butadiene rubber, butyl rubber, and ethylene-propylene rubber.
17 . The flexographic printing plate precursor according to claim 1 ,
wherein the binder contains at least one type of thermoplastic elastomer.
18 . The flexographic printing plate precursor according to claim 1 ,
wherein the water-dispersible particles are composed of a polymer obtained by polymerizing at least one monomer selected from the group consisting of isoprene, butadiene, styrene, butyl, ethylene, propylene, acrylic acid ester, and methacrylic acid ester.
19 . The flexographic printing plate precursor according to claim 1 ,
wherein a content of the polymerization inhibitor is 0.01% by mass or more.
20 . The flexographic printing plate precursor according to claim 1 ,
wherein a content of the polymerization inhibitor is 0.01% by mass or more and 0.5% by mass or less.