IP Library Granted Patent US 6,855,073
Granted Patent B1
US 6,855,073 · App. 09/040,798 · Granted Feb 15, 2005

Golf ball which includes fast-chemical-reaction-produced component and method of making same

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Quick Facts
Patent No.
US 6,855,073
App. No.
09/040,798
Granted
Feb 15, 2005
Kind
B1
Abstract

Disclosed herein is a golf ball comprising fast-chemical-reaction-produced component, such as a component which comprises a reaction injection molded polyurethane material. A process of making a golf ball by forming at least one core and/or cover component of the ball by mixing two or more reactants that react and form a reaction product with a flex modulus of 5-310 kpsi in a reaction time of about 5 minutes or less, the component having a thickness of at least 0.01 inches and a demold time of 10 minutes or less is disclosed. In one preferred form of the invention, excess polyurethane from forming golf ball covers is recycled by using it to form golf ball cores.

Claims (36)

1. A process of making a conventional multi-piece golf ball having at least one uniformed, spherical cover component and core component comprising making at least one of the cover component and the core component of the ball by mixing two or more reactants that react and form a reaction product with a flex modulus of 5-310 kpsi in a reaction time of about 5 minutes or less, the at least one component having a thickness of at least 0.01 inches and a demold time of 10 minutes or less.

2. A process according to claim 1 , wherein the reaction product comprises at least one member selected from the group consisting of polyurethanes, polyureas, epoxies and unsaturated polyesters.

3. A process according to claim 1 , wherein the reaction process comprises reaction injection molding.

4. A process according to claim 1 , wherein the reaction product comprises at least one member selected from the group consisting of polyurethane and polyurea.

5. A process according to claim 4 , wherein the reaction product with a flex modulus of 5-300 kpsi is formed in a reaction time of about 3 minutes or less.

6. A process according to claim 4 , wherein the component has a thickness of at least 0.02 inches.

7. A process according to claim 4 , wherein the at least one component is a cover component.

8. A process according to claim 7 , wherein the cover component is a dimpled cover layer and the cover component has a thickness of at least 0.02 inches.

9. A process according to claim 7 , wherein the cover component has a hardness of 20-95 Shore D.

10. A process according to claim 7 , wherein the cover component has a hardness of 30-75 Shore D.

11. A process according to claim 1 , wherein the at least one component is a core component.

12. A process according to claim 2 , further including the step of recycling at least a portion of the reaction product.

13. A process according to claim 12 , wherein the reaction product is recycled by glycolysis.

14. A multi-piece golf ball comprising a uniformed. spherical core and a uniformed, spherical cover formed thereon, wherein the core or the cover is formed from a reaction injection molded material comprising polyurethane/polyurea, wherein the polyurethane/polyurea material incorporates meta-tetramethyexylylene diisocyanate.

15. A golf ball according to claim 14 , wherein the reaction injection molded material comprising polyurethane/polyurea includes at least one of ether functional groups and ester functional groups.

16. A golf ball according to claim 14 , wherein at least 5% of the polyurethane/polyurea is formed from molecules obtained by recycling a material comprising one of polyurethane, polyurea, polyester, and polyethylene glycol.

17. A golf ball according to claim 16 , wherein recycling takes place by glycolysis.

18. A golf ball according to claim 14 , wherein be ball has a core and a cover and at least the cover comprises reaction injection molded polyurethane/polyurea material.

19. A golf ball according to claim 18 , wherein the ball includes an exterior coating surrounding the cover.

20. A golf ball according to claim 18 , wherein the core is solid, multi-layer, wound, liquid filled, metal filled and/or foamed.

21. A golf ball according to claim 18 , wherein the cover has a flex modulus of 5-310 kpsi.

22. A golf ball according to claim 18 , wherein the cover has a flex modulus of 5-100 kpsi.

23. A golf ball according to claim 18 , wherein the exterior coating is applied over the cover after molding of the cover.

24. A golf ball according to claim 18 , wherein the hardness of the cover is 20-95 Shore D.

25. A golf ball according to claim 18 , wherein the hardness of the cover is 30-75 Shore D.

26. A golf ball according to claim 25 , wherein the flexural modulus of the cover is in the range 5 to 100 kpsi.

27. A golf ball according to claim 18 , wherein the flexural modulus of the cover is higher than of the core.

28. A golf ball according to claim 18 , wherein the ball has a multi-layer cover.

29. A golf ball according to claim 18 , wherein the cover comprises a reaction injection molded material comprising polyurethane and further comprises at least one member selected from the group consisting of optical brightener, pigment, dye, antioxidant, and UV light stabilizer.

30. A golf ball according to claim 18 , wherein the cover further comprises a filler.

31. A golf ball according to claim 30 , wherein the filler includes at least one member selected from the group consisting of glass, metal, minerals, oxides, sulfides, titanates, polymeric resins and ceramics.

32. A golf ball according to claim 14 , wherein the ball has a core and a cover, and at least the core comprises a reaction injection molded polyurethane/polyurea material.

33. A golf ball according to claim 30 , wherein the core comprises at least two components and at least one core component comprises reaction injection molded polyurethane/polyurea material.

34. A golf ball according to claim 14 , wherein the ball has a core, and a cover, each of which comprises reaction injection molded polyurethane/polyurea material.

35. A golf ball according to claim 30 , wherein the cover comprises an ionomer.

36. A golf ball according to claim 18 , wherein the cover has a generally uniform consistency both at the seam and poles.

Assignments (9)
SECURITY INTEREST Recorded Feb 16, 2018
From: CALLAWAY GOLF COMPANY; CALLAWAY GOLF SALES COMPANY; CALLAWAY GOLF BALL OPERATIONS, INC.; OGIO INTERNATIONAL, INC.; CALLAWAY GOLF INTERACTIVE, INC.; CALLAWAY GOLF INTERNATIONAL SALES COMPANY
To: BANK OF AMERICA, N.A.
Reel/Frame 045350/0741 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 26, 2003
From: TOP-FLITE GOLF COMPANY, THE
To: CALLAWAY GOLF COMPANY
Reel/Frame 014007/0688 →
CHANGE OF NAME Recorded Jun 2, 2003
From: SPALDING SPORTS WORLDWIDE, INC.
To: THE TOP-FLITE GOLF COMPANY
Reel/Frame 013753/0072 →
SECURITY AGREEMENT Recorded Nov 4, 2002
From: SPALDING SPORTS WORLDWIDE, INC.
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 013438/0276 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 23, 1999
From: LISCO, INC.
To: SPALDING SPORTS WORLDWIDE, INC.
Reel/Frame 010232/0251 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 4, 1998
From: KELLER, VIKTOR M.; KENNEDY, THOMAS; RISEN, JR., WILLIAM M.
To: LISCO, INC., A DELAWARE CORPORATION
Reel/Frame 009249/0519 →
SECURITY INTEREST Recorded May 22, 1998
From: EVENFLO & SPALDING HOLDINGS CORPORATION; SPALDING & EVENFLO COMPANIES, INC.; EVENFLO COMPANY, INC.; ETONIC WORLDWIDE CORPORATION; LISCO, INC.; S&E FINANCE CO., INC.; SPALDING SPORTS CENTERS, INC.; ETONIC LISCO, INC.; LISCO FURNITURE, INC.; LISCO FEEDING, INC.; LISCO SPORTS, INC.
To: BANK OF AMERICA NATIONAL TRUST & SAVINGS ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 009227/0574 →
SECURITY AGREEMENT Recorded May 22, 1998
From: EVENFLO & SPALDING HOLDINGS CORPORATION; SPALDING & EVENFLO COMPANIES, INC.; EVENFLO COMPANY, INC.; ETONIC WORLDWIDE CORPORATION; LISCO, INC.; S&E FINANCE CO., INC.; SPALDING SPORTS CENTERS, INC.; ETONIC LISCO, INC.; LISCO FURNITURE, INC.; LISCO FEEDING, INC.; LISCO SPORTS, INC.
To: BANK OF AMERICA NATIONAL TRUST & SAVINGS ASSOCIATION
Reel/Frame 009516/0369 →
SECURITY AGREEMENT Recorded May 20, 1998
From: EVENFLO & SPALDING HOLDINGS CORPORATION; SPALDING & EVENFLO COMPANIES, INC.; EVENFLO COMPANY, INC.; ETONIC WORLDWIDE CORPORATION; LISCO, INC.; S&E FINANCE CO., INC.; SPALDING SPORTS CENTERS, INC.; ETONIC LISCO, INC.; LISCO FURNITURE, INC.; LISCO FEEDING, INC.; LISCO SPORTS, INC.
To: BANK OF AMERICA NATIONAL TRUST & SAVINGS ASSOCIATION AS ADMINISTRATIVE AGENT
Reel/Frame 009342/0379 →