IP Library Granted Patent US 6,851,463
Granted Patent B1
US 6,851,463 · App. 09/288,589 · Granted Feb 8, 2005

Composite comprising organic fibers having a low twist multiplier and improved compressive modulus

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Quick Facts
Patent No.
US 6,851,463
App. No.
09/288,589
Granted
Feb 8, 2005
Kind
B1
Abstract

The present invention provides an improved fiber-reinforced article comprised of at least two plies. Each of the plies comprises (a) rubber and (b) cord made from melt-spinnable, non-metallic, multifilament fibers for which the cord has a twist multiplier of less than or equal to about 375, a stress at 1% strain greater than or equal to about 1.7 grams/denier, and an initial compressive modulus greater than or equal to about 7 grams/denier, and the at least two plies have a fiber orientation angle of greater than or equal to about 23°. The composite is useful as a tire belt in a passenger tire.

Claims (83)

1. A fiber-reinforced article comprised of at least two plies wherein each of said plies comprises (a) rubber and (b) cord made from melt-spinnable, non-metallic, multifilament fiber, said cord having

a twist multiplier of less than or equal to about 375,

a stress at 1% strain greater than or equal to about 1.7 grams/denier, and

an initial compressive modulus greater than or equal to about 7 grams/denier, and

said at least two plies having a ply orientation angle of greater than or equal to about 26° with respect to the longitudinal direction of the article.

2. The article of claim 1 wherein said twist multiplier is less than or equal to about 310.

3. The article of claim 1 wherein said initial compressive modulus is greater than or equal to about 9 grams per denier.

4. The article of claim 1 wherein said at least two plies are three plies, wherein two plies have said ply orientation angle of about 30° and the third ply has a ply orientation angle of about 0°.

5. The article of claim 4 wherein said third ply has said cord at 4 to 20 ends per inch.

6. The article of claim 1 comprising four plies wherein two plies have said fiber orientation angle of about 26° and two plies have a fiber orientation angle of about 45°.

7. The article of claim 6 wherein said two inner plies have said cord at 4 to 20 ends per inch.

8. The article of claim 1 wherein said cord is made from polyethylene naphthalate.

9. A tire comprising a belt which belt comprises the article in accordance with claim 8 .

10. A tire comprising a belt which belt comprises the article in accordance with claim 1 .

11. The article of claim 1 having fiber reinforcement in a third dimension.

12. The article of claim 11 wherein said third dimension of reinforcement comprises folds.

13. The article of claim 1 wherein said cord further comprises said cord having a denier per filament of greater than or equal to about 2.

14. The article of claim 1 said cord further comprises said cord having an initial tensile modulus of at least about 165 grains per denier.

15. The article of claim 1 wherein said article has an in-plane shear modulus of at least about 730 pounds-force per inch.

16. The article of claim 1 wherein said article has an in-plane shear modulus of at least about 830 pounds-force per inch.

17. The article of claim 1 wherein said article has a fatigue of at least about 2700 cycles to failure.

18. The article of claim 1 wherein said article has a fatigue of at least about 5550 cycles to failure.

19. The article of claim 1 wherein said article is a tire belt.

20. A fiber-reinforced article comprised of at least two plies wherein each of said plies comprises (a) rubber and (b) cord made from melt-spinnable, non-metallic, multifilament fiber, said cord having

a twist multiplier of less than or equal to about 375,

a stress at 1% strain greater than or equal to about 1.7 grams/denier, and

an initial compressive modulus greater than or equal to about 7 grams/denier, and

said at least two plies having a ply orientation angle of greater than or equal to about 23° with respect to the longitudinal direction of the article; and having fiber reinforcement in a third dimension, wherein said third dimension of reinforcement comprises folds; and

wherein said folds form the edges of the longitudinal direction of the article.

21. A fiber-reinforced article comprised of at least two plies wherein each of said plies comprises (a) rubber and (b) cord made from melt-spinnable, non-metallic, multifilament fiber, said cord having

a twist multiplier of less than or equal to about 375,

a stress at 1% strain greater than or equal to about 1.7 grams/denier, and

an initial compressive modulus greater than or equal to about 7 grams/denier, and

said at least two plies having a ply orientation angle of greater than or equal to about 23° with respect to the longitudinal direction of the article; and having fiber reinforcement in a third dimension; wherein said third dimension of reinforcement comprises folds; and

wherein said third dimension is formed by braiding.

22. A fiber-reinforced article comprised of at least two plies wherein each of said plies comprises (a) rubber and (b) cord made from melt-spinnable, non-metallic, multifilament fiber, said cord having

a twist multiplier of less than or equal to about 375,

stress at 1% strain greater than or equal to about 1.7 grams/denier, and

an initial compressive modulus greater than or equal to about 7 grams/denier, and

said at least two plies having a ply orientation angle of greater than or equal to about 23° with respect to the longitudinal direction of the article; and

wherein said article has substantially no cut cord ends along its longitudinal edges.

23. A fiber-reinforced article comprised of at least two plies wherein each of said plies comprises (a) rubber and (b) cord made from melt-spinnable, non-metallic, multifilament fiber, said cord having

a twist multiplier of less than or equal to about 375,

a stress at 1% strain greater than or equal to about 1.7 grams/denier, and

an initial compressive modulus greater than or equal to about 7 grams/denier, and

said at least two plies having a ply orientation angle of greater than or equal to about 23° with respect to the longitudinal direction of the article;

the article further having fiber reinforcement in a third dimension, wherein said third dimension of reinforcement comprises stitches or folds, and wherein when folds are present, said folds form the edges of the longitudinal direction of the composite.

24. A fiber reinforced article comprised of at least two plies wherein each of said plies comprises (a) rubber and (b) cord made from melt-spinnable, non-metallic, multifilament fiber, said cord having

a twist multiplier of less than or equal to about 375,

a stress at 1% strain greater than or equal to about 1.7 grams/denier, and

an initial compressive modulus greater than or equal to about 7 grams/denier, and

said at least two plies having a ply orientation angle of greater than or equal to about 23° with respect to the longitudinal direction of the article;

the article further having fiber reinforcement in a third dimension, wherein said third dimension of reinforcement comprises braiding.

25. A fiber-reinforced article comprised of at least two plies wherein each of said plies comprises (a) rubber and (b) cord made from melt-spinnable, non-metallic, multifilament fiber, said cord having

a twist multiplier of less than or equal to about 375,

a stress at 1% strain greater than or equal to about 1.7 grams/denier, and

an initial compressive modulus greater than or equal to about 7 grams/denier, and

said at least two plies having a ply orientation angle of greater than or equal to about 23° with respect to the longitudinal direction of the article, and wherein said article has substantially no cut cord ends along its longitudinal edges.

26. A method of making a tire comprising the step of:

incorporating a fiber-reinforced article therein, which fiber-reinforced article is comprised of at least two plies wherein each of said piles comprises (a) rubber and (b) cord made from melt-spinnable, non-metallic, multifilament fiber, said cord having

a twist multiplier of less than or equal to about 375,

a stress at 1% strain greater than or equal to about 1.7 grams/denier, and

an initial compressive modulus greater than or equal to about 7 grams/denier, and

said at least two plies having a ply orientation angle of greater than or equal to about 26° with respect to the longitudinal direction of the article.

27. A method of making a fiber reinforced article said fiber-reinforced article comprised of at least two plies wherein each of said plies comprises (a) rubber and (b) cord made from melt-spinnable, non-metallic, multifilament fiber, said cord having

a twist multiplier of less than or equal to about 375,

a stress at 1% strain greater than or equal to about 1.7 grams/denier, and

an initial compressive modulus greater than or equal to about 7 grams/denier, and

said at least two plies having a ply orientation angle of greater than or equal to about 23° with respect to the longitudinal direction of the article;

said article having fiber reinforcement in a third dimension wherein said third dimension of reinforcement comprises folds and wherein said folds form the edges of the longitudinal direction of the article; the method comprising the step of:

folding a unidirectional composite sheet in a spiral manner to produce a composite having continuous fiber reinforcement and uncut, folded edges.

28. A method of forming an annular object comprising the steps of:

forming a fiber-reinforced article comprised of at least two plies wherein each of said plies comprises (a) rubber and (b) cord made from melt-spinnable, non-metallic, multifilament fiber, said cord having

a twist multiplier of less than or equal to about 375,

a stress at 1% strain greater than or equal to about 1.7 grams/denier, and

an initial compressive modulus greater than or equal to about 7 grams/denier, and

said at least two plies having a ply orientation angle of greater than or equal to about 23° with respect to the longitudinal direction of the article;

said article of claim 1 having fiber reinforcement in a third dimension wherein said third dimension of reinforcement comprises folds and wherein said folds form the edges of the longitudinal direction of the article;

folding the article into a ring shape,

overlapping the ends of said article,

causing one of said ends to have a notch and the second of said ends to have a reciprocal flap, and

folding said flap into said notch,

wherein said annular object has no cut cord ends along its circumferential edges.

Assignments (6)
CONFIRMATION OF PATENT SECURITY INTEREST ASSIGNMENT Recorded Mar 23, 2015
From: PERFORMANCE FIBERS HOLINDGS FINANCE, INC.
To: DFT DURAFIBER TECHNOLOGIES HOLDINGS, INC.
Reel/Frame 035258/0783 →
SECURITY AGREEMENT Recorded May 21, 2009
From: PERFORMANCE FIBERS, INC.
To: PERFORMANCE FIBERS HOLDINGS FINANCE, INC.
Reel/Frame 022719/0612 →
RELEASE OF SECURITY INTEREST Recorded Mar 5, 2008
From: GENERAL ELECTRIC CAPITAL CORPORATION
To: PERFORMANCE FIBERS, INC.; PERFORMANCE FIBERS HOLDINGS, INC.; PERFORMANCE FIBERS ENTERPRISES, INC.
Reel/Frame 020599/0191 →
SECURITY AGREEMENT Recorded Mar 5, 2008
From: PERFORMANCE FIBERS, INC.
To: WELLS FARGO FOOTHILL, INC.
Reel/Frame 020599/0290 →
SECURITY INTEREST Recorded Jan 31, 2005
From: PERFORMANCE FIBERS, INC.; PERFORMANCE FIBERS HOLDINGS, INC.; PERFORMANCE FIBERS ENTERPRISES, INC.
To: GENERAL ELECTRIC CAPITAL CORPORATION
Reel/Frame 016195/0354 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 21, 2005
From: HONEYWELL INTERNATIONAL, INC., A CORP. OF DELAWARE
To: PERFORMANCE FIBERS, INC.
Reel/Frame 016164/0705 →