Process for producing liquid polyalphaolefin polymer, metallocene catalyst therefor, the resulting polymer and lubricant containing same
View Patent ↗A liquid polyalphaolefin homo- or copolymer, preferably 1-decene, which is substantially amorphous is obtained by a polymerization process employing hydrogen and a particular type of metallocene catalyst. Additionally, liquid polyalphaolefin homo- or copolymer containing from 2 to about 12 carbon atoms possess a unique combination of properties, i.e., low molecular weight (M w ), low polydispersity index (M w /M n controllable kinematic viscosity (Kv 100 ), low Iodine Number (I 2 ) and low glass transition temperature (T g ) and are substantially amorphous. The liquid polyalphaolefin homo- or copolymers provided herein are useful for manufacturing a variety of products including lubricating oils in which the polyalphaolefin functions as a viscosity modifier.
1. A process for the polymerization of α-olefin to provide a liquid polyalphaolefin homo- or copolymer, the process comprising polymerizing at least one olefin in the presence of hydrogen and a catalytically effective amount of catalyst comprising the product obtained by combining a metallocene procatalyst with a cocatalyst, the metallocene procatalyst being at least one compound of general formula:
( Cp 1 R 1 m ) R 3 ( Cp 2 R 2 p ) MX q
wherein Cp 1 of ligand (Cp 1 R 1 m ) and Cp 2 of ligand (Cp 2 R 2 p ) are the same or different cyclopentadienyl rings, R 1 and R 2 each is, independently, hydrogen or a hydrocarbyl, halocarbyl, heterocarbyl, hydrocarbyl-substituted organometalloid or halocarbyl-substituted organometalloid group containing up to about 20 carbon atoms, m is 0 to 5, p is 0 to 5 and two R 1 and/or R 2 substituents on adjacent carbon atoms of the cyclopentadienyl ring associated therewith can be joined together to form a ring containing from 4 to about 20 carbon atoms, R 3 is a bridging group bridging Cp 1 with Cp 2 , M is a transition metal having a valence of from 3 to 6, each X is a non-cyclopentadienyl ligand and is, independently, halogen or a hydrocarbyl, oxyhydrocarbyl, halocarbyl, hydrocarbyl-substituted organometalloid, oxyhydrocarbyl-substituted organometalloid or halocarbyl-substituted organometalloid group containing up to about 20 carbon atoms, and q is equal to the valence of M minus 2, the cocatalyst being an aluminoxane and it being provided that ligand (Cp 1 R 1 m ) is different than ligand (Cp 2 R 2 p ) and bridging group R 3 contains at least two bulky groups.
2. The process of claim 1 wherein the metallocene procatalyst possesses the structure
in which groups R 4 and R 5 each, independently, is, or contains, a cyclic group of from 6 to about 20 carbon atoms, from 0 to 3 heteroatoms and hydrogen as the remaining atoms.
3. The process of claim 2 wherein in the metallocene procatalyst, the cyclic group is a cycloalkyl, heterocycloalkyl, cycloalkenyl, heterocycloalkenyl, aryl, heteroaryl, alkaryl, alkylheteroaryl, aralkyl or heteroaralkyl group.
4. The process of claim 3 wherein in the metallocene procatalyst, ligand (Cp 1 R m 1 ) is unsubstituted cyclopentadienyl, ligand (Cp 2 R p 2 ) is substituted or unsubstituted indenyl or fluorenyl, M 1 is zirconium, R 4 and R 5 each is phenyl and each ligand X is chlorine.
5. The process of claim 1 wherein the metallocene procatalyst based in terms of the transition metal M, is present in an amount from 0.0001 to about 0.02 millimoles/liter and the aluminoxane cocatalyst is present in an amount from 0.01 to about 100 millimoles/liter.
6. The process of claim 1 wherein the α-olefin contains from 2 to about 20 carbon atoms.
7. The process of claim 1 wherein the α-olefin contains from about 6 to about 12 carbon atoms.
8. The process of claim 1 wherein the α-olefin is 1-decane.
9. The process of claim 1 wherein the metallocene procatalyst is combined with the aluminoxane cocatalyst and hydrogen in any order thereof and in the presence or absence of αolefin.