Fuel emulsion compositions having reduced NOx emissions
View Patent ↗Oil continuous fuel emulsion composition having high stability and reduced nitrogen oxide emissions. The fuel emulsion formulation includes diesel fuel, purified water, and an additive package that includes, among other additives, a combination of surfactants, including a primary surfactant, such as a fatty acid diethanolamide, a block copolymer, and a polymeric dispersant.
1. A high stability, low emission, invert fuel emulsion composition for an internal combustion engine comprising
purified water;
hydrocarbon petroleum distillate fuel as the continuous phase of the emulsion;
a surfactant package comprising a primary surfactant, a block copolymer stabilizer, and a polymeric dispersant; and
a coupling agent for maintaining phase stability at high temperatures and shear pressures in said internal combustion engine wherein said coupling agent is selected from a group consisting of: a di-acid of a Diels-Alder adduct of unsaturated fatty acids and a tri-acid of a Diels-Alder adduct of unsaturated fatty acids neutralized with an alkanolamine to form a water soluble salt;
wherein said emulsion has an average droplet size ranging from about 0.1 microns to about 1 micron.
2. The invert fuel emulsion composition of claim 1 comprising 5-50 wt % purified water and 50-95 wt. % hydrocarbon petroleum distillate fuel.
3. The invert fuel emulsion composition of claim 1 comprising at least 4000 ppm primary surfactant.
4. The invert fuel emulsion composition of claim 3 wherein said primary surfactant is an amide.
5. The invert fuel emulsion composition of claim 4 wherein said primary surfactant is selected from the group consisting of unsubstituted, mono- and di-substituted amides of saturated C 12 -C 22 fatty acids and unsubstituted, mono- and di-substituted amides of unsaturated C 12 -C 22 fatty acids,
wherein said mono and di substituted amides are substituted by substituents
selected, independently of each other, from the group consisting of straight and branched, unsubstituted and substituted alkyls having 1 to 4 carbon atoms, straight and branched, unsubstituted and substituted alkanols having 1 to 4 carbon atoms, and aryls.
6. The invert fuel emulsion composition of claim 5 wherein said primary surfactant is a 1:1 fatty acid diethanolamide of oleic acid.
7. The invert fuel emulsion composition of claim 1 comprising from about 1,000 ppm to about 5,000 ppm block copolymer.
8. The invert fuel emulsion composition of claim 7 wherein said block copolymer is an EO/PO block copolymer.
9. The invert fuel emulsion composition of claim 1 comprising about 100 ppm to about 1,000 ppm polymeric dispersant.
10. The invert fuel emulsion composition of claim 1 comprising
10-50% purified water;
50-90% hydrocarbon petroleum distillate fuel;
at least 4000 ppm amide primary surfactant;
between about 2000 and about 3000 ppm EO/PO block copolymer; and
between about 600 and about 800 ppm polymeric dispersant.
11. The invert fuel emulsion composition of claim 10 wherein said amide primary surfactant is a 1:1 fatty acid diethanolamide.
12. The invert fuel emulsion composition of claim 1 wherein said coupling agent selected is said di-acid.
13. The invert fuel emulsion composition of claim 1 wherein said coupling agent selected is said tri-acid.
14. An additive package for use in a fuel emulsion for an internal combustion engine comprising a primary surfactant, a block copolymer acting as a surfactant stabilizer, a polymeric dispersant, a coupling agent for maintaining phase stability at high temperatures and shear pressures in said internal combustion engine and water, wherein said emulsion has an average droplet size ranging from about 0.1 microns to about 1 micron and wherein said coupling agent is selected from a group consisting of: a di-acid of a Diels-Alder adduct of unsaturated fatty acids and a tri-acid of a Diels-Alder adduct of unsaturated fatty acids neutralized with an alkanolamine to form a water soluble salt.
15. The additive package of claim 14 comprising about 3,000 to about 10,000 parts per million of said fuel emulsion of primary surfactant.
16. The additive package of claim 15 comprising about 5,000 to about 6,000 parts per million of said fuel emulsion of primary surfactant.
17. The additive package of claim 14 wherein said primary surfactant is an amide.
18. The additive package of claim 16 wherein said primary surfactant is selected from the group consisting of unsubstituted, mono- and di-substituted amides of saturated C 12 -C 22 fatty acids, unsubstituted, mono- and di-substituted amides of unsaturated C 12 -C 22 fatty acids, and mixtures thereof,
wherein said mono and di substituted amides are substituted by substituents
selected, independently of each other, from the group consisting of straight and branched, unsubstituted and substituted alkyls having 1 to 4 carbon atoms, straight and branched, unsubstituted and substituted alkanols having 1 to 4 carbon atoms, and aryls.
19. The additive package of claim 16 wherein said primary surfactant is a 1:1 fatty acid diethanolamide of oleic acid.
20. The additive package of claim 14 comprising about 1,000 to about, 5,000 parts per million of said fuel emulsion of block copolymer.
21. The additive package of claim 20 comprising about 2,000 to about 3,000 parts per million of said fuel emulsion of block copolymer.
22. The additive package of claim 14 wherein said block copolymer is an EO/PO block copolymer.
23. The additive package of claim 14 further comprising a dispersant comprising one or more components selected from the group consisting of wetting agents, amine oxides, bio-polymer surfactants, amine othoxilates and dinonylphenol ethoxylates.
24. The additive package of claim 23 comprising about 100 to about 1,000 parts per million of said fuel emulsion of said polymeric dispersant.
25. The additive package of claim 24 comprises about 600 to about 800 parts per million of said fuel emulsion of polymeric dispersant.
26. The additive package of claim 23 wherein said wetting agent is comprised of a decyne diol nonfoaming wetter.
27. The additive package of claim 14 further comprising an antifreeze.
28. The additive package of claim 27 wherein said antifreeze is an organic alcohol.
29. The additive package of claim 28 wherein said antifreeze is methanol.
30. The additive package of claim 14 further comprising an ignition delay modifier.
31. The additive package of claim 30 wherein said ignition delay modifier comprises one or more compounds selected from the group consisting of nitrates, nitrites and peroxides.
32. The additive package of claim 31 wherein said ignition delay modifier comprises 2-ethylhexylnitrate.
33. The additive package of claim 31 wherein said ignition delay modifier comprises ammonium nitrate.