Low gloss powder coating compositions
View Patent ↗The invention is directed to a low gloss powder coating composition comprising a first component (a) and a second component (b). The first component (a) comprises a mixture of (i) at least one glycidyl group-containing acrylic resin having epoxide equivalent weight of from about 250 to about 1500 and glass transition temperature of from about 30° C. to about 80° C.; and (ii) a curing agent. The second component (b) comprises at least one carboxyl-group containing material having acid number of from about 10 to about 300 and is not substantially compatible with the first component (a). The two components are dry-blended to obtain the powder coating composition.
1. A powder coating composition comprising:
a). a first component comprising a melt-blended mixture of
(i). at least one glycidyl group-containing acrylic resin having epoxide equivalent weight of from about 250 to about 1500 and glass transition temperature of from about 30° C. to about 80° C.; and
(ii). a curing agent selected from the group consisting of dicarboxylic acids, dicarboxylic acid anhydrides, and mixtures thereof; and
b). a second component dry-blended with said first component (a), comprising at least one carboxyl-group containing material that has acid number of from about 10 to about 300 and that is not substantially compatible with said first component (a).
2. The powder coating composition of claim 1 , wherein said first component (a) further comprises a catalyst.
3. The powder coating composition of claim 1 , wherein said second component (b) further comprises a catalyst.
4. The powder coating composition of claim 2 , wherein said second component (b) further comprises a catalyst.
5. The powder coating composition of claim 1 , wherein said second component (b) further comprises a crosslinker.
6. The powder coating composition of claim 1 , wherein said second component (b) is present in an amount of from about 1% to about 40% by weight, based on the total weight of said first component (a) and said second component (b).
7. The powder coating composition of claim 6 , wherein said second component (b) is present in an amount of from about 3% to about 25% by weight, based on the total weight of said first component (a) and said second component (b).
8. The powder coating composition of claim 7 , wherein said second component (b) is present in an amount of from about 5% to about 20% by weight, based on the total weight of said first component (a) and said second component (b).
9. The powder coating composition of claim 1 , wherein said carboxyl-group containing material comprised in second component (b) is selected from the group consisting of carboxyl-group containing polyester resins, carboxy-group containing acrylic resin, and carboxyl-group containing polyethylene and polypropylene.
10. The powder coating composition of claim 9 , wherein said carboxyl-group containing material is carboxyl-group containing polyester resins having an acid number or from about 25 to about 250.
11. The powder coating composition of claim 2 , wherein said catalyst is selected from the group consisting of stannous octanoate, stannous laurate, stannous stearate, stannous 2-ethylhexanoate, stannous chloride, stannous bromide, and mixtures thereof.
12. The powder coating composition of claim 3 , wherein said catalyst is selected from the group consisting of stannous octanoate, stannous laurate, stannous stearate, stannous 2-ethylhexanoate, stannous chloride, stannous bromide, and mixtures thereof.
13. The powder coating composition of claim 1 , wherein said ingredient (i) has epoxide equivalent weight of from about 250 to about 800 and glass transition temperature of from about 35° C. to about 65° C.
14. The powder coating composition of claim 1 , wherein said composition exhibits, upon cure, a 60° gloss of less than about 55.
15. The powder coating composition of claim 14 , wherein said composition exhibits, upon cure, a 60′ gloss of from about 10 to about 40.
16. The powder coating composition of claim 1 , wherein said composition exhibits, upon cure, a pencil hardness of from about H to about 6H.
17. The powder coating composition of claim 16 , wherein said composition exhibits, upon cure, a pencil hardness of from about 2H to about 6H.
18. The powder coating composition of claim 1 , wherein the curing agent (ii) is a dicarboxylic acid anhydride and the stoichiometric ratio of the curing agent (ii) to the glycidyl groups existing in ingredient (i) being from about 0.4 to about 0.7.
19. The powder coating composition of claim 18 , wherein said composition exhibits, upon cure on wood substrate, a substantially free of blooming appearance.
20. The powder coating composition of claim 1 , wherein the stoichiometric ratio of the curing agent (ii) to the glycidyl groups existing in component (i) is from about 0.7 to about 1.5.
21. The powder coating composition of claim 1 , wherein the curing agent (ii) is selected from the group consisting of succinic acid, adipic acid, azelaic acid, sebacic acid, eicosanedioic acid, dodecanedioic acid, glutaric acid, pimelic acid, and anhydrides thereof.
22. The powder coating composition of claim 1 , wherein said second component (b) has a particle size of from about 0.1 micron to about 250 micron.
23. The powder coating composition of claim 22 , wherein said second component (b) has a particle size of from about 1 micron to about 100 micron.
24. The powder coating composition of claim 23 , wherein said second component (b) has a particle size of from about 5 micron to about 60 micron.