IP Library Granted Patent US 6,863,843
Granted Patent B2
US 6,863,843 · App. 09/746,322 · Granted Mar 8, 2005

Naphthopyran compounds, photoresponsive compositions and lenses

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Quick Facts
Patent No.
US 6,863,843
App. No.
09/746,322
Granted
Mar 8, 2005
Kind
B2
Abstract

A photochromic [1,2-b] naphthopyran having a fluoro substituent in at least one of the 7-position or the 9-position of the naphthopyran provides a stable photochromic compound with a narrow range of absorption. A preferred photochromic naphthopyran has the 2-position of the naphthopyran with two aromatic substituents thereon. It is further preferred to have at least one 2-position aromatic substituent comprising a phenyl group. The photochromic naphthopyran may also have at least one 2-position aromatic substituent comprise a phenyl group having one substituent selected from the group consisting of an anthranilyl, azepinyl, benzoxazolyl, dialkylamino, diazepinyl, diazolyl, imidazolidinyl, imidazolyl, imidazolinyl, indazolyl, indo eninyl, indolinyl, indolizinyl, indolyl, indoxazinyl, isobenzazolyl, isoindolyl, isooxazolyl, isooxazyl, isopyrrol, isoquinolyl, isothiazolyl, julolideno, morpholino, morpholinyl, oxadiazolyl, oxathiazolyl, oxathiazyl, oxathiolyl, oxatriazolyl, oxazolyl, piperazinyl, piperazyl, piperidyl, purinyl, pyranopyrrolyl, pyrazinyl, pyrazolidinyl, pyrazolinyl, pyrazolyl, pyrazyl, pyridazinyl, pyridazyl, pyridyl, pyrimidinyl, pyrimidyl, pyridenyl, pyrrolidinyl, pyrrolinyl, pyrroyl, quinolizinyl, quinocyclidinyl, quinolyl, thiazolyl, triazolyl and triazyl group.

Claims (3)

1. A naphthopyran comprising 2,2-(4-methoxy-4′-pyrrolidino)diphenyl-5-methylol-7-fluoro-9-methoxy-[2H]-naphtho[1,2-b]pyran.

2. A photochromic composition containing at least one photochromic naphthopyran compound according to claim 1 and a polymeric host material selected from the group consisting of polycarbonates and polyvinyl alcohol.

3. A photochromic article having a layer thereon comprising the photochromic composition according to claim 2 characterized that the article is an ophthalmic lens.

Assignments (14)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 29, 2022
From: VISION EASE, LP
To: HOYA OPTICAL LABS OF AMERICA, INC.
Reel/Frame 059825/0497 →
RELEASE OF SECURITY INTEREST Recorded Aug 1, 2017
From: ANTARES CAPITAL LP
To: VISION EASE, LP
Reel/Frame 043402/0306 →
CHANGE OF NAME Recorded Nov 23, 2015
From: INSIGHT EQUITY A.P. X, LP
To: VISION EASE, LP
Reel/Frame 037154/0842 →
RELEASE OF SECURITY INTEREST Recorded Oct 30, 2015
From: PNC BANK, NATIONAL ASSOCIATION
To: INSIGHT EQUITY A.P. X, LP
Reel/Frame 036922/0053 →
RELEASE OF SECURITY INTEREST Recorded Oct 30, 2015
From: ANTARES CAPITAL LP, AS AGENT
To: VISION EASE, LP (F/N/A INSIGHT EQUITY A.P. X, LP)
Reel/Frame 037009/0180 →
SECURITY INTEREST Recorded Oct 27, 2015
From: VISION EASE, LP (D/B/A VISION-EASE LENS)
To: ANTARES CAPITAL LP, AS ADMINISTRATIVE AGENT
Reel/Frame 036981/0268 →
ASSIGNMENT OF INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Sep 15, 2015
From: GENERAL ELECTRIC CAPITAL CORPORATION, AS RETIRING AGENT
To: ANTARES CAPITAL LP, AS SUCCESSOR AGENT
Reel/Frame 036616/0161 →
RELEASE OF SECURITY INTEREST Recorded Sep 23, 2014
From: PNC BANK, NATIONAL ASSOCIATION, AS REVOLVING AGENT
To: INSIGHT EQUITY A.P. X, LP
Reel/Frame 033810/0185 →
RELEASE OF SECURITY INTEREST Recorded Sep 23, 2014
From: PNC BANK, NATIONAL ASSOCIATION, AS TERM LOAN AGENT
To: INSIGHT EQUITY A.P. X, LP
Reel/Frame 033810/0143 →
SECURITY INTEREST Recorded Sep 23, 2014
From: INSIGHT EQUITY A.P. X, LP (D/B/A VISION-EASE LENS)
To: GENERAL ELECTRIC CAPITAL CORPORATION, AS AGENT
Reel/Frame 033810/0209 →
SECURITY AGREEMENT Recorded Nov 8, 2012
From: INSIGHT EQUITY A.P. X, LP (D/B/A VISION-EASE LENS)
To: PNC BANK, NATIONAL ASSOCIATION, AS REVOLVING AGENT
Reel/Frame 029261/0832 →
SECURITY AGREEMENT Recorded Nov 8, 2012
From: INSIGHT EQUITY A.P. X, LP (D/B/A VISION-EASE LENS)
To: PNC BANK, NATIONAL ASSOCIATION, AS TERM LOAN AGENT
Reel/Frame 029261/0912 →
RELEASE OF SECURITY INTEREST Recorded Oct 30, 2012
From: ORIX CORPORATE CAPITAL INC. (F/K/A ORIX FINANCE CORP.)
To: INSIGHT EQUITY A.P. X, LP
Reel/Frame 029209/0771 →
RELEASE OF SECURITY INTEREST Recorded Oct 30, 2012
From: REGIMENT CAPITAL SPECIAL SITUATIONS FUND IV, L.P.
To: INSIGHT EQUITY A.P. X, LP
Reel/Frame 029209/0926 →