Catalyst for the selective oxidation of sulfur compounds to elemental sulfur
View Patent ↗The invention provides a catalyst, a method for making the catalyst and a method for using the catalyst to promote the selective oxidation of hydrogen sulfide into elemental sulfur. The catalyst may be prepared by contacting a catalyst support, such as silica, with a mixed oxide having atomically mixed iron ions and zinc ions, to produce a support material impregnated with a mixed oxide having atomically mixed iron ions and zinc ions in an oxidic lattice. This impregnated catalyst support is then dried and calcined, preferably with chloride ions present, to produce a catalyst of an iron and zinc oxide mixture supported on silica. It has been found that when chloride is added to the impregnated catalyst support prior to calcination and drying, the sintering of the iron and zinc can be controlled more easily and the formation of iron and zinc oxide is promoted. It has also been found that the catalyst of the invention exhibits improved selectivity characteristics when compared to a catalyst prepared without the chloride.
1. A catalyst on a support for the selective oxidation of sulfur-containing compounds to elemental sulfur, comprising at least one catalytically active material that is present on a support material, wherein the catalytically active material comprises a mixed oxide having atomically mixed iron ions and zinc ions in an oxidic lattice, which catalyst has a specific surface area of more than 20 m 2 /g and exhibits substantially no Claus activity under the reaction conditions of said selective oxidation.
2. A catalyst according to claim 1 , wherein the atomic ratio of iron to zinc is between 25/75 and 97.5/25.
3. A catalyst according to claim 1 , wherein the atomic ratio of iron to zinc is between 95/5 and 50/50.
4. A catalyst according to claim 1 , which catalyst has a specific surface area of more than 25 m 2 /g, and an average pore radius within a range of about 100 Å to 500 Å.
5. A catalyst according to claim 1 or claim 4 , wherein the support is SiO 2 .
6. A catalyst according to claim 1 or claim 4 , wherein the catalytically active material is present on the support in an amount of 0.1-50% by weight, calculated on the total mass of the catalyst.
7. A catalyst according to claim 1 , wherein said catalyst has a specific surface area of more than 20 and up to 300 m 2 /g.
8. A catalyst according to claim 1 , wherein said catalyst has a specific surface area of more than 20 and up to 300 m 2 /g and an average pore radius within a range of 100 to 500 Å.
9. A method for the preparation of a catalyst according to claim 1 , comprising atomically mixing iron and zinc compounds for an oxide lattice, applying the atomically mixed iron and zinc compounds to the surface of a support material, followed by drying and calcination of the support material, during which calcination, an amount of chloride is present on the support material, wherein the prepared catalyst has a specific surface area of more than 20 m 2 /g and exhibits substantially no Claus activity under reaction conditions for the selective oxidation of sulfur-containing compounds to elemental sulfur.
10. A method according to claim 9 , wherein the applying step comprises impregnating the support material with said atomically mixed iron and zinc compounds in solution, and further comprising, during or after the impregnation, applying an amount of chloride to the surface of the support material.
11. A method according to claim 9 or 10 , wherein the amount of chloride is between 0.1 and 20% by weight, based on the amount by weight of the metals.
12. A method according to claim 9 or 10 , wherein the chloride is ammonium chloride.
13. A method according to claim 11 , wherein the chloride is ammonium chloride.