Hollow capsule having a wall permeable to water or an aqueous solution
View Patent ↗This invention discloses, as an article of manufacture, a capsule having a hollow interior and an enclosing wall, referred to as a membrane. The membrane is not soluble in water, but is permeable to water or an aqueous solution. The membrane is comprised of a first material and can also include a second material. When the membrane is comprised of the first material and the second material, then it is referred to as a composite material wherein the first material forms sporting matrix having the second material fixed in the matrix. The first material is a urethane/vinyl hybrid polymer and is not soluble in, reactive with or a solvent for the second material. The second material is a particulate solid, different from the first material, and is not soluble in, reactive with or a solvent for the first material. The capsule of this invention is useful to maintain in the hollow interior thereof a solid, water-soluble first chemical composition which is not soluble in, reactive with or a solvent for the enclosing wall of the capsule. In operation, the exterior of the capsule, having the first composition maintained in the interior thereof, is placed in contact with a water-soluble second chemical composition which is not soluble in, reactive with or a solvent for the enclosing wall of the capsule, but which is reactive with the first chemical composition.
1. An article of manufacture comprising a capsule and a first chemical composition, said capsule having a hollow interior and an enclosing membrane wall having an interior surface and an exterior surface, wherein said first chemical composition is enclosed within said hollow interior of said capsule;
said membrane is permeable to water and aqueous solutions, but is not soluble in aqueous liquids, and includes at least a first material comprised of a polyurethane-vinyl polymer dispersion prepared by the simultaneous polymerization of a vinyl monomer and chain extension of an isocyanate-terminated polyurethane pre-polymer in the presence of water to thereby form a urethane/vinyl hybrid polymer; and
said first chemical composition is comprised of a solid, water-soluble chemical composition which is not reactive with, soluble in or a solvent for said membrane.
2. The article of claim 1 wherein said first chemical composition is selected from the group consisting of alkali, alkaline earth metal and ammonium halides, oxides, hydroxides, carbonates, bicarbonates, perborates, peroxides, percarbonates, bisulfates and persulfates.
3. The article of claim 2 wherein said membrane is a composite material comprised of said first material and further comprised of a second material, wherein said first material is a supporting matrix for said second material which is fixed in said supporting matrix;
said second material is a particulate solid, having a particle size in the range of from about 1 to about 15 microns, present in said composite material in an amount in the range of from an amount greater than about 0 to about 50 percent of said particulate solid by total weight of said composite material;
said second material is different from said first material, and is not reactive with, soluble in or a solvent for said first material or said first chemical composition; and
said composite material is present in said article in an amount in the range of from about 10 to about 50 percent by weight of said composite material by weight of said article.
4. The article of claim 2 wherein said first material is reacted with a cross linking agent selected from the group consisting of polyaziridines, carbodiimides, epoxies and metal ion cross linkers.
5. The article of claim 3 wherein said second material is selected from the group consisting of silica, calcium carbonate, titanium dioxide, barium sulfate, calcium sulfate and mixtures thereof.
6. The article of claim 2 wherein said first chemical composition has a particle size in the range of from about 10 to about 60 mesh US Sieve series.
7. The article of claim 5 wherein said first material is reacted with a cross linking agent selected from the group consisting of polyaziridines, carbodiimides, epoxies and metal ion cross linkers.
8. The article of claim 5 wherein said first chemical composition has a particle size in the range of from about 10 to about 60 mesh US Sieve series.
9. The article of claim 4 wherein said cross linking agent is a polyaziridine.
10. The article of claim 7 wherein said cross linking agent is a polyaziridine.
11. The article of claim 4 wherein said first chemical composition has a particle size in the range of from about 10 to about 60 mesh US Sieve series.
12. The article of claim 7 wherein said first chemical composition has a particle size in the range of from about 10 to about 60 mesh US Sieve series.
13. The article of claim 7 wherein said second material is silica.
14. The article of claim 7 wherein said second material is calcium carbonate.
15. The article of claim 13 wherein said cross linking agent is a polyaziridine.
16. The article of claim 13 wherein said cross linking agent is a carbodiimide.
17. The article of claim 14 wherein said cross linking agent is a carbodiimide.
18. The article of claim 5 wherein said first material is reacted with a polyaziridine cross linking agent.
19. The article of claim 6 wherein said first material is reacted with a polyaziridine cross linking agent.