Methods of adjusting glass melting and forming temperatures without substantially changing bending and annealing temperatures and glass articles produced thereby
View Patent ↗A method is provided for adjusting, e.g., lowering, the melting and/or forming temperatures of a glass composition without substantially changing the bending and annealing temperatures of the glass composition. The method includes increasing the amount of CaO and decreasing the amount of MgO in the glass composition by the same or about the same amount.
1. A glass composition, comprising:
a. SiO 2 70 to 75 weight percent
b. Na 2 O 12 to 15 weight percent
c. K 2 O 0 to 5 weight percent
d. CaO>9 weight percent
e. MgO<4 weight percent
f. Al 2 O 3 0 to less than 1.6 weight percent
g. SO 3 0 to 1 weight percent
h. Fe 2 O 3 0 to less than 0.65 weight percent wherein
SiO 2 +Al 2 O 3 ≧70 weight percent
Na 2 O+K 2 O 12 to 15 weight percent
CaO+MgO 12 to less than 13.4 weight percent
CaO/MgO 2.33 to 5
wherein the glass composition has a log 2 viscosity in the range of about 2570° F. to about 2590° F. (1410° C. to 1421° C.) and a log 4 viscosity in the range of about 1850° F. to about 1894° F. (1010° C. to 1034° C.).
2. The composition according to claim 1 , wherein CaO is in the range of greater than 9 to 12 weight percent.
3. The composition according to claim 1 , wherein CaO is in the range of 9.1 to 11 weight percent.
4. The composition according to claim 1 , wherein MgO is in the range of 2 to less than 4 weight percent.
5. The composition according to claim 1 , wherein CaO+MgO is in the range of 12.5 to less than 13 weight percent.
6. The composition according to claim 1 , wherein the ratio of CaO to MgO is 2.77 to 5.
7. The composition according to claim 1 , wherein the glass composition has a log 7.6 viscosity in the range of about 1300° F. to about 1350° F. (704 to 732) and log 13 viscosity in the range of about 1016° F. to about 1020° F. (547° C. to 449° C.).
8. The composition according to claim 1 , wherein the melting point of the glass composition from the log 2 viscosity reduces fuel usage in preparing the glass.
9. The composition according to claim 7 , wherein the melting point of the glass composition from the log 2 viscosity reduces fuel usage in preparing the glass and the bending and annealing temperatures of the glass from the log 7.6 viscosity in the range of about 1300° F. to about 1350° F. (704° C. to 732° C.) and a log 13 viscosity in the range of about 1016° F. to about 1020° F. (547° C. to 549° C.) are in the range for a higher melting glass.