Method for producing tungsten carbides by gas-phase carburization
View Patent ↗The invention relates to a method for producing wolfram carbides by gas-phase carburetion of wolfram powders and/or suitable wolfram precursor compounds in powder form at temperatures above 850° C. According to the method a CO 2 /CO mixture with a CO 2 content greater than the Boudouard equilibrium content corresponding to the carburetion temperature is used as carburetion gas phase.
1. A process for preparing tungsten carbide consisting of:
(a) carburizing a material selected from the group consisting of tungsten powder, tungsten precursor compound powder and combinations thereof, at a temperature ranging from 850° to 950°, and in the presence of a carburizing gas phase,
said carburizing gas phase comprising a mixture of CO and CO 2 , said carburizing gas phase having a CO 2 content which is above the Boudouard equilibrium content corresponding to the carburization temperature, and
wherein the carburizing step is carried out with a carbon activity ranging from 0.4 to less than 1; and
(b) heat treating the tungsten carbide formed in step (a) at a temperature ranging from 1,150° C. to 1,800° C., and at a carburizing atmosphere sufficient for the carbon content of the tungsten carbide to approach the theoretical, thereby forming tungsten carbide.
2. The process of claim 1 , wherein carburizing step (a) is carried out with a carbon activity ranging from 0.4 to 0.9.
3. The process of claim 1 , wherein carburizing step (a) is conducted at a temperature of from 900° C. to 950° C.
4. The process of claim 1 , wherein carburizing step (a) is conducted over a period ranging from 4 to 10 hours.
5. The process of claim 1 , wherein the tungsten precursor compound powder is tungsten oxide powder.
6. A process for preparing tungsten carbide consisting of:
(a) carburizing a material selected from the group consisting of tungsten powder, tungsten precursor compound powder and combinations thereof, at a temperature ranging from 850° to 950°, and in the presence of a carburizing gas phase,
said carburizing gas phase comprising a mixture of CO and CO 2 , said carburizing gas phase having a CO 2 content which is above the Boudouard equilibrium content corresponding to the carburization temperature, and
wherein the carburizing step is carried out with a carbon activity ranging from 0.4 to less than 1; and
(b) heat treating the tungsten carbide formed in step (a) at a temperature ranging from 1,150° C. to 1,800° C., thereby forming tungsten carbide, wherein said tungsten carbide is characterized by a relationship between coherence length x and lattice strain y according to Formula (I):
y <(−4.06 10 −4 nm −1 x+ 0.113)%.