Coal tar and hydrocarbon mixture pitch production using a high efficiency evaporative distillation process
View Patent ↗Described are methods that utilize high efficiency evaporative distillation to make a high softening point coal tar pitch, a quinoline insoluble-free and ash-free coal tar pitch having a desired softening point, and a mesophase coal tar pitch. Each of the methods uses a feed coal tar pitch having a softening point in the range of 70° C. to 160° C. The methods may be carried out using appropriate conventional distillation equipment, a wiped film evaporator, or a thin film evaporator.
1. A method of making a quinoline insoluble-free and ash-free coal tar pitch having a desired softening point, comprising the steps of: feeding a feed coal tar pitch having an initial softening point in the range of 70° C. to 160° C. into a processing vessel, wherein said processing vessel is heated to a temperature in the range of 300° C. to 600° C. and wherein a pressure inside said processing vessel is 5 Torr or less; obtaining a distillate from said processing vessel, said distillate having a softening point in the range of 25° C. to 60° C. and being quinoline insoluble-free and ash-free; heat treating said distillate at a temperature in the range of 350° C. to 595° C. for between five minutes and forty hours; and distilling the heat treated distillate to obtain a pitch having the desired softening point.
2. A method according to claim 1 , said feeding step comprising introducing said feed coal tar pitch into a wiped film evaporator, said wiped film evaporator comprising said processing vessel.
3. A method according to claim 1 , said feeding step comprising introducing said feed coal tar pitch into a thin film evaporator, said thin film evaporator comprising said processing vessel.
4. A method according to claim 1 , said feeding step comprising introducing said feed coal tar pitch into a conventional distillation apparatus, said conventional distillation apparatus comprising said processing vessel.
5. A method according to claim 1 , wherein said heat treated distillate has a softening point in the range of 60° C. to 110° C.
6. A method of making a mesophase coal tar pitch, comprising of the steps of: feeding a feed coal tar pitch having a softening point in the range of 70° C. to 160° C. into a processing vessel, wherein said processing vessel is heated to a temperature in the range of 300° C. to 600° C. and wherein a pressure inside said processing vessel is 5 Tow or less; obtaining a distillate from said processing vessel, said distillate having a softening point in the range of 25° C. to 60° C. and being quinoline insoluble-free and ash-free; and heat treating said distillate at a temperature in the range of 370° C. to 595° C. for between three and forty hours.
7. A method according to claim 6 , said feeding step comprising introducing said feed coal tar pitch into a wiped film evaporator, said wiped film evaporator comprising said processing vessel.
8. A method according to claim 6 , said feeding step comprising introducing said feed coal tar pitch into a thin film evaporator, said thin film evaporator comprising said processing vessel.
9. A method according to claim 6 , said feeding step comprising introducing said feed coal tar pitch into a conventional distillation apparatus, said conventional distillation apparatus comprising said processing vessel.
10. A method of making a quinoline insoluble-free and ash-free coal tar pitch, comprising of the steps of: feeding a feed coal tar pitch having a softening point in the range of 70° C. to 160° C. into a first processing vessel, wherein said first processing vessel is heated to a temperature in the range of 300° C. to 600° C. and wherein a pressure inside said first processing vessel is 5 Torr or less; obtaining a distillate from said first processing vessel, said distillate having a softening point in the range of 25° C. to 60° C. and being quinoline insoluble-free and ash-free; heat treating said distillate at a temperature in the range of 350° C. to 595° C. for between five minutes and forty hours; distilling the heat treated distillate to obtain a pitch having a desired softening point; feeding said pitch having a desired softening point into a second processing vessel, wherein said second processing vessel is heated to a temperature in the range of 300° C. to 600° C.; and withdrawing an output coal tar pitch from said second processing vessel.
11. A method according-to claim 10 , wherein said first processing vessel and said second processing vessel are the same vessel.
12. A method according to claim 11 , wherein said first and second processing vessel is a wiped film evaporator.
13. A method according to claim 10 , wherein said first processing vessel comprises a wiped film evaporator.
14. A method according to claim 10 , wherein said second processing vessel comprises a wiped film evaporator.
15. A method according to claim 11 , wherein said first and second processing vessel is a thin film evaporator.
16. A method according to claim 10 , wherein said first processing vessel comprises a thin film evaporator.
17. A method according to claim 10 , wherein said second processing vessel comprises a thin film evaporator.
18. A method according to claim 11 , wherein said first and second processing vessel are comprised of a conventional distillation apparatus.
19. A method according to claim 10 , wherein said first processing vessel further comprises a conventional distillation apparatus.
20. A method according to claim 10 , wherein said second processing vessel further comprises a conventional distillation apparatus.
21. A method of making a quinoline insoluble-free and ash-free hydrocarbon mixture pitch having a desired softening point, comprising the steps of feeding a feed hydrocarbon mixture pitch having an initial softening point in the range of 70° C. to 160° C. into a processing vessel, wherein said processing vessel is heated to a temperature in the range of 300° C. to 600° C. and wherein a pressure inside said processing vessel is 5 Torr or less; obtaining a distillate from said processing vessel, said distillate having a softening point in the range of 25° C. to 60° C. and being quinoline insoluble-free and ash-free; heat treating said distillate at a temperature in the range of 350° C. to 595° C. for between five minutes and forty hours; and distilling the heat treated distillate to obtain a pitch having the desired softening point.
22. A method according to claim 21 , said feeding step comprising introducing said feed hydrocarbon mixture pitch into a wiped film evaporator, said wiped film evaporator comprising said processing vessel.
23. A method according to claim 21 , said feeding step comprising introducing said feed hydrocarbon mixture pitch into a thin film evaporator, said thin film evaporator comprising said processing vessel.
24. A method according to claim 21 , said feeding step comprising introducing said feed hydrocarbon mixture pitch into a conventional distillation apparatus, said conventional distillation apparatus comprising said processing vessel.
25. A method according to claim 21 , wherein said heat treated distillate has a softening point in the range of 60° C. to 110° C.
26. A method according to claim 21 , said feed hydrocarbon mixture pitch comprising a mixture of coal tar pitch and petroleum pitch.
27. A method according to claim 26 , said feed hydrocarbon mixture pitch comprising at least 50% coal tar pitch.
28. A method of making a mesophase hydrocarbon mixture pitch, comprising of the steps of: feeding a feed hydrocarbon mixture pitch having a softening point in the range of 70° C. to 160° C. into a processing vessel, wherein said processing vessel is heated to a temperature in the range of 300° C. to 600° C. and wherein a pressure inside said processing vessel is 5 Torr or less; obtaining a distillate from said processing vessel, said distillate having a softening point in the range of 25° C. to 60° C. and being quinoline insoluble-free and ash-free; and heat treating said distillate at a temperature in the range of 370° C. to 595° C. for between three and forty hours.
29. A method according to claim 28 , said feeding step comprising introducing said feed hydrocarbon mixture pitch into a wiped film evaporator, said wiped film evaporator comprising said processing vessel.
30. A method according to claim 28 , said feeding step comprising introducing said feed hydrocarbon mixture pitch into a thin film evaporator, said thin film evaporator comprising said processing vessel.
31. A method according to claim 28 , said feeding step comprising introducing said feed hydrocarbon mixture pitch into a conventional distillation apparatus, said conventional distillation apparatus comprising said processing vessel.
32. A method according to claim 28 , said feed hydrocarbon mixture pitch comprising a mixture of coal tar pitch and petroleum pitch.
33. A method according to claim 32 , said feed hydrocarbon mixture pitch comprising at least 50% coal tar pitch.
34. A method of making a quinoline insoluble-free and ash-free hydrocarbon mixture pitch, comprising of the steps of: feeding a feed hydrocarbon mixture pitch having a softening point in the range of 70° C. to 160° C. into a first processing vessel, wherein said first processing vessel is heated to a temperature in the range of 300° C. to 600° C. and wherein a pressure inside said first processing vessel is 5 Torr or less; obtaining a distillate from said first processing vessel, said distillate having a softening point in the range of 25° C. to 60° C. and being quinoline insoluble-free and ash-free; heat treating said distillate at a temperature in the range of 350° C. to 595° C. for between five minutes and forty hours; distilling the heat treated distillate to obtain a pitch having a desired softening point; feeding said pitch having a desired softening point into a second processing vessel, wherein said second processing vessel is heated to a temperature in the range of 300° C. to 600° C.; and withdrawing an output hydrocarbon mixture pitch from said second processing vessel.
35. A method according to claim 34 , wherein said first processing vessel and said second processing vessel are the same vessel.
36. A method according to claim 35 , wherein said first and second processing vessel is a wiped film evaporator.
37. A method according to claim 34 , wherein said first processing vessel comprises a wiped film evaporator.
38. A method according to claim 34 , wherein said second processing vessel comprises a wiped film evaporator.
39. A method according to claim 35 , wherein said first and second processing vessel is a thin film evaporator.
40. A method according to claim 34 , wherein said first processing vessel comprises a thin film evaporator.
41. A method according to claim 34 , wherein said second processing vessel comprises a thin film evaporator.
42. A method according to claim 35 , wherein said first and second processing vessel are comprised of a conventional distillation apparatus.
43. A method according to claim 34 , wherein said first processing vessel further comprises a conventional distillation apparatus.
44. A method according to claim 34 , wherein said second processing vessel further comprises a conventional distillation apparatus.
45. A method according to claim 34 , said feed hydrocarbon mixture pitch comprising a mixture of coal tar pitch and petroleum pitch.
46. A method according to claim 45 , said feed hydrocarbon mixture pitch comprising at least 50% coal tar pitch.