Polymide-free alignment layer for LCD fabrication and method
View Patent ↗An inexpensive polyimide-free alignment layer comprising a mixture of an epoxy and a reactive liquid crystal material is used for fabricating liquid crystal displays (LCDs). The alignment layer can be cast onto a previously aligned layer, without destroying the alignment of the underlying layer, thus allowing for monolithic fabrication of compensator stacks, without film transfer lamination.
1. An alignment layer for a liquid crystal display, comprising a cured isotropic transparent and non-birefringent polymer film formed from a mixture of:
a curable epoxy and
a reactive mesogen
the cured mixture of said epoxy and reactive mesogen constituting an isotropic transparent and non-birefringent polymer film comprising polymerized liquid crystal molecules randomly oriented in cured epoxy, said polymerized liquid crystal molecules at an exposed surface of the isotropic transparent and non-birefringent polymer film capable of being subsequently aligned.
2. The alignment layer of claim 1 , wherein said composition is polyimide free.
3. The alignment layer of claim 1 , wherein the epoxy is UV curable.
4. The alignment layer of claim 1 , further comprising a photo-initiator mixed with said epoxy.
5. The alignment layer of claim 4 , further comprising a thermal-inhibitor mixed with said epoxy, reactive mesogen and photo-initiator.
6. The alignment layer of claim 1 , wherein said epoxy comprises between 10% and 80% by weight of said isotropic alignment layer.
7. The alignment layer of claim 1 wherein the randomly oriented liquid crystals in the cured film are capable of being azimuthally oriented by rubbing the film.
8. The alignment layer of claim 1 wherein the reactive mesogen is a UV curable monoacrylate or diacrylate monomer or oligomer.
9. The alignment layer of claim 1 wherein the cured polymer film is formed from the curable epoxy and reactive mesogen dissolved in a solvent which does not damage other layers of the liquid crystal device upon which it is coated.
10. The alignment layer of claim 9 wherein the solvent is a ketone.
11. The alignment layer of claim 9 wherein the solvent is chosen from the group consisting of cyclohexanone, methylethylketone, acetone, cyclopentanone, toluene and chlorobenzene.