Thermoplastic resin composition and process for preparing the same
View Patent ↗There is provided a polyester resin composition excellent in mechanical properties, heat deformation temperature, surface appearance, dimensional stability and mold releasing ability, and a process for preparing the same. The polyester resin composition contains a thermoplastic polyester resin and layered phyllosilicate, wherein the layered phyllosilicate in the resin composition satisfies at least one of the following conditions (a) to (c): (a) ratio of layered phyllosilicate having equivalent area circle diameter [D] of at most 3,000 Å is at least 20%; (b) a mean value of equivalent area circle diameter [D] is at most 5000 Å; (c) the number of particles [N] per unit ratio of layered phyllosilicate present in 100 μm 2 of a resin composition is at least 30.
1. A process for producing a polyester resin composition containing a thermoplastic polyester resin and layered phyllosilicate consisting of untreated phyllosilicate comprising:
(A) a step for preparing a dispersion of layered phyllosilicate and water containing layered phyllosilicate and water;
(B) a step for adding said dispersion of layered phyllosilicate, in an amount from 0.1 to 45 parts by weight of layered phyllosilicate based on 100 parts by weight of the thermoplastic resin, and water continuously or successively to a component having low polymerization degree of the thermoplastic polyester resin at a rate of 0.01 to 10.0 parts by weight per minute based on 100 parts by weight of the component having low polymerization degree of the thermoplastic polyester resin; and
(C) a step for polymerizing the thermoplastic polyester resin.