Recycle of hydrogen from hydroprocessing purge gas
View Patent ↗The present invention relates to an integrated gasification and hydroprocessing process. A hydrocarbonaceous fuel is first gasified to produce syngas, and then a portion of the hydrogen is removed from the syngas. The hydrogen is compressed and used as an excess reactant in a hydroprocessing unit. Hydrogen gas is recovered from the hydroprocessing unit product, purified, compressed and recycled to the hydroprocessing unit. The hydrogen-poor syngas is expanded in an expander that drives the compressor that compresses the recycled hydrogen gas. The expanded syngas is then combined with light hydrocarbons removed from the recycle hydrogen gas stream, combusted in a gas turbine and used for power generation.
1. An integrated gasification and hydroprocessing process comprising:
reacting a hydrocarbonaceous fuel with a free oxygen containing gas to produce syngas comprising hydrogen;
removing a portion of the hydrogen from the syngas;
expanding the syngas in an expander;
processing the hydrogen and make-up hydrogen in a hydroprocessing unit, producing a hydroprocessing unit gas product comprising purge hydrogen and purge hydrocarbons;
compressing the hydroprocessing unit gas product in a compressor, wherein the compressor is driven by power generated from the expander;
separating the purge hydrogen from the purge hydrocarbons in the hydroprocessing unit gas product; and
supplying the purge hydrogen as the make-up hydrogen to the hydroprocessing unit.
2. The process of claim 1 further comprising purifying the syngas prior to removing hydrogen from the syngas.
3. The process of claim 2 , wherein the purification of the syngas comprises removing hydrogen sulfide from the syngas.
4. The process of claim 1 , wherein the hydrogen is removed from the syngas using a pressure swing adsorption unit.
5. The process of claim 1 , wherein the hydrogen is removed from the syngas using membrane separation.
6. The process of claim 1 , wherein the hydrogen is compressed prior to being processed in the hydroprocessing unit.
7. The process of claim 1 further comprising purifying the hydroprocessing unit gas product prior to compressing the hydroprocessing unit gas product in the compressor.
8. The process of claim 7 , wherein the purification of the hydroprocessing unit gas product comprises removing hydrogen sulfide from the purge gas.
9. The process of claim 8 , wherein the hydrogen sulfide is removed from the hydroprocessing unit gas product by counter current contact with a solvent that selectively removes hydrogen sulfide.
10. The process of claim 1 , wherein the purge hydrogen is separated from the purge hydrocarbons in the hydroprocessing unit gas product using a pressure swing adsorption unit.
11. The process of claim 1 , wherein the purge hydrogen is separated from the purge hydrocarbons in the hydroprocessing unit gas product using membrane separation.
12. The process of claim 1 further comprising processing the expanded syngas in a gas turbine to produce power.
13. The process of claim 1 further comprising processing the purge hydrocarbons in a gas turbine to produce power.
14. The process of claim 1 , wherein the hydroprocessing unit is selected from the group consisting of a hydrodesulfurization unit, a denitrification unit, and a hydrocracking unit.