Nanosized copper catalyst precursors for the direct synthesis of trialkoxysilanes
View Patent ↗The present invention provides a process for using nanosized copper, nanosized copper oxides, nanosized copper chlorides, other nanosized copper salts, and mixtures thereof, as sources of catalytic copper in the Direct Synthesis of trialkoxysilanes of the formula HSi(OR) 3 wherein R is an alkyl group containing from 1 to 6 carbon atoms inclusive. The nanosized copper, nanosized copper oxides, nanosized copper chlorides, other nanosized copper salts, and their mixtures of this invention have average particle sizes that are in the range from about 0.1 to about 600 nanometers, preferably from about 0.1 to about 500 nanometers, and most preferably from about 0.1 to about 100 nanometers. Nanosized sources of catalytic copper afford high dispersion of catalytic sites on silicon and contribute to high reaction rates, high selectivity and high silicon conversion. The nanosized copper catalyst precursors of the invention permit the use of substantially reduced levels of copper compared to conventional practice.
1. A process for using a nanosized copper catalyst precursor selected from the group consisting of nanosized copper, nanosized copper oxides, nanosized copper chlorides, other nanosized copper salts, and mixtures thereof as sources of catalytic copper in the direct synthesis of trialkoxysilane of formula HSi(OR) 3 wherein R is an alkyl group containing from 1 to 6 carbon atoms inclusive, said process comprising:
(a) forming a reaction mixture comprising a thermally stable solvent, silicon metal, a catalytically effective amount of said nanosized copper catalyst precursor having an average particle size in a range from about 0.1 to about 60 nanometers;
(b) agitating and heating this mixture to form copper-activated silicon in situ and injecting into said reaction mixture an alcohol to react with said copper-activated silicon to produce said trialkoxysilane; and
(c) recovering said trialkoxysilane from the reaction product.
2. The process of claim 1 further comprising:
(d) remediating and reusing the reaction solvent in the Direct Synthesis of trialkoxysilanes.
3. The process of claim 1 wherein forming said reaction mixture includes mixing with a solvent that has been used in preparation of said nanosized copper catalyst precursor.
4. The process of claim 1 wherein forming said reaction mixture includes providing a foam control agent.
5. The process of claim 1 wherein the trialkoxysilane is trimethoxysilane or triethoxysilane and the direct synthesis of trimethoxysilane or triethoxysilane occurs with about 300 to about 5000 parts per million copper based on an amount of silicon.
6. The process of claim 1 wherein alcohol introduction into the reaction mixture is delayed until thermal decomposition and dehydration of the catalyst precursor are complete.