Composition and article for reduced food adhesion

1. A resin composition comprising:

a) a polysulfone resin, a polyethersulfone resin or a blend containing one of the foregoing resins with a glass transition temperature of at least 180° C. wherein the polysulfone and/or polyethersulfone consist essentiallly of repeating units selected from the group consisting of

b) at least one fluorinated polyolefin in an amount up to about 4% by weight effective to reduce food deposit adhesion on cookware made from the composition; and

c) a fatty acid amide.

2. The composition of claim 1 , comprising the polysulfone resin.

3. The composition of claim 1 , comprising the polyethersulfone resin.

4. The composition of claim 1 , wherein the fluorinated polyolefin is a ploymer of a perfluorinated monoolefin or a partially fluorinated monolefin.

5. The composition fo claim 1 , wherein the fluorinatd polyolefin is a polymer of one or more fluorinated monomers containing ethylenic unsaturation and optionally, one or more other compounds containing ethylenic unsaturation.

6. The composition of claim 1 , wherein the fluorinated polyolefin is at least one of poly(vinyl fluoride), poly(vinylidene fluoride), polytrifluoroethylene, polychlorotrifluoroethylene, polybromotrifluoroethyiene, polytetrafluoroethylene, or copolymers thereof.

7. The comopsition of claim 1 , wherein the fluorinated polyolefin is a compolymer of tetrafluoroethylene and hexafluoropropylene.

8. The composition of claim 1 , wherein the fluorinated polyolefin is a fluorinated polyethylene comprising repeating units of the structural formula:

wherein b is an ingerger in excess of 50 and Y 1 to Y 4 , which may be the same or different, are selected from the group comsisting of hydrogen, chlorine, bromine and fluorine, whth the proviso that at least one Y 1 to Y 4 , is fluorine.

9. The composition of claim 1 , wherein the at least one fluorinated polyolefin is present at about 0.1% to about 4% by weight.

10. The composition of claim 1 , wherein the fatty acid amide is at leasr one of lauramide, palmitamide, behenamide, 1,-hydrox stearamide, oleamide, erucamide, recinoleamide, N-stearyl stearamide, N-behenyl behenamide, N-stearyl behenamide, N-behenyl stearamide, N-oleyl oleamide, N-oleyl stearamide, N-stearyl oleamide, N-stearyl erucamide, N-oleyl palamitamide, methylol stearamide, methylol be-henamide, methylene bis-stearamide, etheylene bis-isostearanudem ethylene bis-hydroxystearamide, ethylene bis-behenamide, hexamethylene bis-stearamide, hexamethylene bis-behenamide, hexamethylene bis-hydroxystearamide, N,N′-distearyl adipamide, N,N′-disterayl sebacamide, hexamethylene bis-oleamide, N,N′-dioleyl adipamide, N,N′-dioleyl sebacamide, N,N′-ethylenebisstearamide, N,N′-ethylenebisoleamide, erucycl enucamide, or erucyl stearamide.

11. The composition of claim 1 , wherein the fatty acid amide is at least one of behenamide, arachidamide, N,N′-ethylenebissearamide, oleyl palmitamide, oleamide, erucamide, oleamide, N,N′-ethylenebissearamide, N,N′-ethylenebisoleamide, stearyl erucamide, erucyl erucamide, stearyl stearamide, or erucyl stearamide.

12. The composition of claim 1 , wherein the fatty acid amid is N,N′-ethylenebisstearamide.

13. The composition of claim 1 , wherein the fatty acid amide is stearyl erucamide.

14. The composition of claim 1 , comprising about 0.1 to about 5 weight percent of the fatty acid amide.

15. The composition of claim 1 . further comprising a resin selected from the consisting of polycarbonates, polyimides, polyetherimides, polyamides, polyamideimides, polyetherketones, aromatic copolyesters and blends of the foregoing resins.

16. The compositon of claim 1 , further comprising a least one fluorinated siloxane or fluorinated polysiloxane.

17. The composition of claim 1 , further comprising a mineral filler selected form the group consisting of clays talcs, micas, barium sulfates, titanium dioxides, wollastonites, and zinc oxides.

18. The composition of claim 1 , further comprising a food release additive selected from the group consisting of fatty acid esters anionic surfactants, and mixtures thereof.

19. The composition clain 1 further comprising at least one additive selected from the group consisting of anti-oxidants, flame retardants, drip retardants, crystallazation nucleators dyes, pigments, colorants reinforcing agents, fillers, stabilizers, antistatic agents, and plasticizers.

20. An article comprising the composition of claim 1 .

21. A resin composition consisting essentially of:

a polysulfone or polyrethersulfone resin with a glass transistion temperature of at least 180° C. wherein the polysulfone or polyethersulfone consist essentially of repeating units selected from the group consisting of

about 0.1 to about 4% by weight of a fluorinated polyolenfin; and

about 0.1 to about 5% by weight of a fatty acid amide, wherein the amounts are based on the entire weight of the composition.

22. A resin composition consisting essentially of:

a polysulfone of polyetherasulfone resin with a glass transition temperature of at least 180° C. wherein the polysulfone and/or polyethersulfone consist essentially of repeating units selected from the group consisting of

about 0.1 to about 4% by weight of a fluorinated polyolefin;

about 0.1 to about 5% by weight of fatty acid amide; and

up to 50% by weight of mineral filler, wherein the amounts are based on the entire weight of the composition.

23. A resin composition comprising:

a) a polysulfone resin, a polyethersulfone resin or a blend containing one of the foregoing resins with a glass transition temperature of at least 180° C. wherein the polysulfone and/or polyethersulfone consist essentially of repeating units selected from the group consisting of

b) at least one fluorinated polyolefin ina a amount up to about 4% by weight effective to reduce food deposit adhesion on cookware made from the composition; and

c) a fatty acid amide, fatty acid ester and a mixture of the foregoing.