Plastic optical fiber, optical fiber cable, plugged optical fiber cable, and production methods thereof
View Patent ↗The present invention relates to a production method of a plastic optical fiber which comprises the steps of heat drawing an undrawn plastic optical fiber obtained by melt spinning and annealing the drawn fiber at a circumferential velocity ratio between the front and rear rollers (circumferential velocity of a rear roller/circumferential velocity of a front roller) of 0.5 to 1.2 under heating conditions which satisfy 4≦y≦−1.5x+330 and (Tgc−5)° C.≦x≦(Tgc+110)° C. [Tgc: a glass transition temperature of a core, x: an annealing temperature (° C.), and y: an annealing time (seconds)]. According to the present invention, a plastic optical fiber having a small thermal shrinkage ratio and excellent heat resistance can be provided.
1. A production method of a plastic optical fiber, comprising the step of, at least once, annealing a plastic optical fiber obtained by heat-drawing an undrawn fiber obtained by melt spinning, at a circumferential velocity ratio between the front and rear rollers (circumferential velocity of a rear roller/circumferential velocity of a front roller) of 0.5 to 1.2 under heating conditions which satisfy 4≦y≦−1.5x+330 and (Tgc−5)° C.≦x≦(Tgc+110)° C. wherein Tgc represents a glass transition temperature of a core, x represents an annealing temperature (° C.), and y represents an annealing time (seconds).
2. The production method as claimed in claim 1 , wherein a homopolymer of methyl methacrylate, or a copolymer comprising a methyl methacrylate unit and another monomer unit is used as the core.
3. The production method as claimed in claim 1 , wherein the core of the plastic optical fiber comprises a homopolymer of methyl methacrylate, the heat drawing is carried out such that the birefringence absolute value of the core becomes 3×10 −4 or higher, and the annealing is carried out at a circumferential velocity ratio between the front and rear rollers (circumferential velocity of the rear roller/circumferential velocity of the front roller) of not higher than 1 under conditions which satisfy x≦(Tgc+20)° C., wherein Tgc represents the glass transition temperature of the core, and x represents an annealing temperature (° C.).
4. The production method as claimed in claim 1 , which has the step of carrying out annealing under the heating conditions twice or more.
5. A production method of a plastic optical fiber, comprising the step of fixed length annealing a plastic optical fiber obtained by the method as claimed in claim 1 at a temperature not higher than (a glass transition temperature of a core+8°)C.
6. A plastic optical fiber obtained by the method as claimed in any one of claims 1 to 5 and having a shrinkage stress occurring temperature obtained by thermomechanical analysis of not lower than (a glass transition temperature of a core−35)° C.
7. The plastic optical fiber as claimed in claim 6 , wherein the core comprises a homopolymer of methyl methacrylate and has a birefringence absolute value of not larger than 2.0×10 −4 .
8. A plastic optical fiber obtained by the method as claimed in any one of claims 1 to 5 , having a core which comprises a homopolymer of methyl methacrylate and has a birefringence absolute value of not smaller than 1.5×10 −4 , and having a shrinkage stress occurring temperature obtained by thermomechanical analysis of not lower than (a glass transition temperature of the core−20)° C.
9. The plastic optical fiber as claimed in claim 6 , which exhibits a shrinkage ratio of not higher than 2% when heated at 90° C. for 65 hours.
10. A plastic optical fiber cable obtained by forming a coating layer around the plastic optical fiber as claimed in claim 6 .
11. A plugged plastic optical fiber cable obtained by attaching a plug on the tip of the plastic optical fiber cable as claimed in claim 10 .
12. The production method as claimed in claim 1 , wherein the annealing step and the heat-drawing step are carried out continuously.
13. The production method of a plastic optical fiber, comprising the step of fixed-length annealing a plastic optical fiber obtained by the method as claimed in claim 3 at a temperature not higher than (a glass transition temperature of a core+8)° C.
14. The plastic optical fiber as claimed in claim 8 , which exhibits a shrinkage ratio of not higher than 2% when heated at 90° C. for 65 hours.
15. A plastic optical fiber cable obtained by forming a coating layer around the plastic optical fiber as claimed in claim 8 .
16. The production method as claimed in claim 1 , wherein the annealing is carried out while a tension of 0.35×10 6 to 1.5×10 6 Pa is applied to the fiber.
17. The production method as claimed in claim 16 , wherein the annealing is carried out by introducing a plastic optical fiber into an annealing zone substantially vertically to a horizontal plane.
18. The production method as claimed in claim 16 , wherein the annealing is carried out by use of a heating furnace disposed substantially horizontally with a plastic optical fiber to be annealed supported by a heating medium which provides buoyancy to the plastic optical fiber so as to cause the plastic optical fiber to travel within an annealing zone in a non-contact manner.
19. The production method as claimed in claim 16 , wherein the annealing is carried out by alleviation treatment.
20. The production method as claimed in claim 16 , wherein the annealing is hot air annealing.
21. The production method as claimed in claim 16 , wherein the annealing is carried out such that a produced plastic optical fiber exhibits a shrinkage ratio when heated at 90° C. for 65 hours of not higher than 0.5%.
22. A production method of a plastic optical fiber cable, comprising the steps of obtaining a plastic optical fiber by the method as claimed in claim 1 , and then forming a coating layer around the obtained optical fiber.
23. A production method of a plugged plastic optical fiber cable, comprising the steps of obtaining a plastic optical fiber cable by the method of claimed in claim 22 , and then attaching a plug on the tip of the obtained optical fiber cable.
24. A production method of a plastic optical fiber, comprising the step of annealing a plastic optical fiber obtained by melt spinning, at a temperature from (a glass transition temperature of a core−5)° C. to (the glass transition temperature of the core+80)° C. while a tension of 0.35×10 6 to 1.5×10 6 Pa is applied to the fiber.
25. The production method as claimed in claim 24 , which has the step of heat-drawing a plastic optical fiber and carrying out the annealing after heat-drawing the plastic optical fiber.
26. The production method as claimed in claim 24 or 25 , wherein a polymer containing a methyl methacrylate unit in an amount of not smaller than 70% by weight is used as the core of a plastic optical fiber.
27. The production method as claimed in claim 24 or 25 , wherein a homopolymer of methyl methacrylate is used as the core of a plastic optical fiber and the annealing is carried out at a temperature not higher than (a glass transition temperature of the core+30)° C. such that the core has a birefringence absolute value of not smaller than 1.5×10 −4 and the plastic optical fiber has a shrinkage stress occurring temperature obtained by thermomechanical analysis of not lower than (the glass transition temperature of the core−20)° C.
28. The production method as claimed in claim 24 or 25 , wherein the annealing is carried out by introducing a plastic optical fiber into an annealing zone substantially vertically to a horizontal plane.
29. The production method as claimed in claim 24 or 25 , wherein the annealing is carried out by use of a heating furnace disposed substantially horizontally with a plastic optical fiber to be annealed supported by a heating medium which provides buoyancy to the plastic optical fiber so as to cause the plastic optical fiber to travel within an annealing zone in a non-contact manner.
30. The production method as claimed claim 24 or 25 , wherein the annealing is carried out by alleviation treatment.
31. The production method as claimed in claim 24 or 25 , wherein the annealing is hot air annealing.
32. The production method as claimed claim 24 or 25 , wherein the annealing is carried out such that a produced plastic optical fiber exhibits a shrinkage ratio when heated at 90° C. for 65 hours of not higher than 0.5%.
33. A production method of a plastic optical fiber cable, comprising the steps of obtaining a plastic optical fiber by the method as claimed in claim 24 or 25 , and then forming a coating layer around the obtained optical fiber.
34. A production method of a plugged plastic optical fiber cable, comprising the steps of obtaining a plastic optical fiber cable by the method as claimed in claim 33 , and then attaching a plug on the tip of the obtained optical fiber cable.