Golf ball having a urethane cover
View Patent ↗The invention provides an improved golf ball having a thermosetting polyurethane cover that enables the ball to maintain its ball characteristics even under a severe condition such as a rainy weather or a very hot weather under a burning sun. The golf ball has a cover made of the polyurethane prepared by curing a urethane prepolymer having an isocyanate group at a terminal thereof with a curing agent. The urethane prepolymer contains a polycarbonate polyol component having a number-average molecular weight of from 300 to 3000.
1. A golf ball comprising a core, and a thermoset polyurethane cover covering the core, wherein:
the polyurethane cover is formed by curing a urethane prepolymer having an isocyanate group at a terminal thereof with a curing agent;
the urethane prepolymer contains a polycarbonate polyol component having a number-average molecular weight of from 300 to 3000; and
the polycarbonate polyol is poly(hexamethylene carbonate) or poly(1,4 cyclohexamethylene carbonate).
2. The golf ball according to claim 1 , wherein:
the urethane prepolymer has a free NCO group content of from 5% to 15% by mass; and
the curing agent is a diol or a diamine each having a number-average molecular weight of from 50 to 500 and is used in an amount such that the equivalent ratio of the amino or hydroxyl group of the curing agent to the free NCO group of the urethane prepolymer (OH/NCO or NH2/NCO) is from 0.8 to 1.2.
3. The golf ball according to claim 1 , wherein the polyurethane cover has a Shore D hardness of from 40 to 63 at a non-dimpled portion thereof.
4. The golf ball according to claim 1 , wherein the core is solid core.
5. The golf ball according to claim 4 , wherein: the urethane prepolymer has a free NCO group content of from 5% to 15% by mass; and
the curing agent is a diol or a diamine each having a number-average molecular weight of from 50 to 500 and is used in an amount such that the equivalent ratio of the amino or hydroxyl group of the curing agent to the free NCO group of the urethane prepolymer (OH/NCO or NH2/NCO) is from 0.8 to 1.2.
6. The golf ball according to claim 4 , wherein the polyurethanecover has a Shore D hardness of from 40 to 63 at a non-dimpled portion thereof.