Process for continuously producing polybutylene terephthalate
View Patent ↗Polybutylene terephthalate having good heat stability and excellent hydrolysis resistance is continuously produced in a series of a first reactor for reacting an aromatic dicarboxylic acid comprising terephthalic acid as a main ingredient or a derivative thereof with a glycol comprising 1,4-butanediol as a main ingredient, a second reactor for polycondensating the oligomer from the first reactor, and a third reactor for further polycondensating the low polymerization product from the second reactor, or followed by a fourth reactor for further polycondensing the polyester from the third reactor. Another third reactor or a plurality of third reactors can be provided in parallel to the third reactor.
1. A process for continuously producing polybutylene terephthalate by esterification of an aromatic dicarboxylic acid with a glycol and subsequent polycondensation of the esterification product obtained, comprising:
(a) continuously feeding said aromatic dicarboxylic acid and said glycol into a first esterification reactor as a first process stage;
(b) carrying out esterification during the first process stage at temperatures of 220° C. to 250° C. and at 33 kPa to 150 kPa;
(c) precondensing the esterification product from the first process stage during a second stage at temperatures of 230° C. to 255° C. and at 100 kPa to 0.133 kPa, to produce a precondensate;
(d) continuously polycondensing said precondensate at temperatures of 230° C. to 255° C. and at 0.665 kPa to 0.067 kPa;
(e) removing water and tetrahydrofuran from an output volatile component from said first esterification reactor to produce said glycol;
(f) condensing an output volatile component obtained in steps (c) and (d); and
(g) recycling to the first esterification reactor said glycol obtained in step (e) and condensed component obtained in step (f).
2. The process for continuously producing polybutylene terephthalate according to claim 1 , wherein said aromatic dicarboxylic acid is terephthalic acid and said glycol is 1,4-butanediol.