Polyamide compounds
View Patent ↗An acid-dyeable polyester composition comprising (a) polyester and (b) secondary amine or secondary amine salt in an amount effective to promote acid-dyeability. The acid-dyeable polyester composition may be prepared by melt blending: the polyester; and polymeric additive prepared from (i) triamine containing secondary amine or secondary amine salt unit(s) and (ii) one or more other monomer and/or polymer units. One polymeric additive comprises polyamide selected from the group consisting of poly-imino-bisalkylene-terephthalamide, -isophthalamide and -1,6-naphthalamide, and salts thereof. Also, the polymeric additive, the blends, shaped articles (e.g., fibers and films), processes of dyeing, and processes for preparing an acid dyeable polyester composition.
1. A polymeric additive for incorporating secondary amine units into the polymer chain of a polyester composition comprising a compound having the following formula:
wherein A or B, which may be the same or different, are select from aliphatic or aromatic substituents, wherein n is 10-30, a is 3-20 and b is 3-20, wherein the polymer composition comprises about 0.5 mol % to about 15 mol % secondary amine units.
2. The polymeric additive of claim 1 wherein n is 10-20.
3. The polymeric additive of claim 2 wherein A or B, which may be the same or different, are selected from alkyl and aryl and each may contain 0-20 alkyl units and 0-3 aryl units, provided that each contains at least one aryl unit or at least two alkyl units.
4. The polymeric additive of claim 1 wherein n is 15.
5. The polymeric additive of claim 1 wherein a is 5-20.
6. The polymeric additive of claim 1 wherein a is 5-12.
7. The polymeric additive of claim 1 wherein b is 5-20.
8. The polymeric additive of claim 1 wherein b is 5-12.
9. The polymeric additive of claim 1 wherein a is 5-20 and b is 5-20.
10. The polymeric additive of claim 9 wherein A or B, which may be the same or different, are selected from alkyl and amyl and each may contain 0-20 alkyl units and 0-3 aryl units, provided that each contains at least one aryl unit or at least two alkyl units.
11. The polymeric additive of claim 1 wherein a is 5-12 and b is 5-12.
12. The polymeric additive of claim 11 wherein A or B, which may be the same or different, are selected from alkyl and aryl and each may contain 0-20 alkyl units and 0-3 aryl units, provided that each contains at least one aryl unit or at least two alkyl units.
13. The polymeric additive of claim 1 wherein n is 10-20, a is 5-20 and b is 5-20.
14. The polymeric additive of claim 13 wherein A or B, which may be the same or different, are selected from alkyl and aryl and each may contain 0-20 alkyl units and 0-3 aryl units, provided that each contains at least one aryl unit or at least two alkyl units.
15. The polymeric additive of claim 1 wherein n is 10-20, a is 5-12 and b is 5-12.
16. The polymeric additive of claim 15 wherein A or B, which may be the same or different, are selected from alkyl and aryl and each may contain 0-20 alkyl units and 0-3 aryl units, provided that each contains at least one aryl unit or at least two alkyl units.
17. The polymeric additive of claim 1 wherein A or B, which may be the same or different, are selected from alkyl and aryl and each may contain 0-20 alkyl units and 0-3 aryl units, provided that each contains at least one aryl unit or at least two alkyl units.
18. The polymeric additive of claim 1 further comprising a compound formed from hexamethylene diamine and bis(hexamethylene triamine) and a diacid, wherein the ratio of hexamethylene diamine and bis(hexamethylene triamine) to the diacid is about 1:1.
19. The polymeric additive of claim 1 , wherein the polymeric composition comprises about 0.5 mol % to about 10 mol % secondary amine units.
20. The polymeric additive of claim 19 , wherein the polymeric composition comprises about 1 mol % to about 10 mol % secondary amine units.
21. The polymeric additive of claim 20 , wherein the polymeric composition comprises about 2 mol % to about 5 mol % secondary amine units.
22. A polymeric additive for incorporating secondary amine units into the polymer chain of a polyester composition comprising poly(6,6′-imino-bishexamethylene terephthalamide) having repeat units according to the formula:
wherein n is 10-30, wherein the polymeric composition comprises about 0.5 mol % to about 15 mol % secondary amine units.
23. Poly(6,6′-imino-bishexamethylene terephthalamide) as claimed in claim 22 wherein n is 10-20.
24. Poly(6,6′-imino-bishexamethylene terephthalamide) as claimed in claim 22 wherein n is 15.
25. A polymeric additive for use in forming an acid-dyeable polyester composition, said polymeric additive prepared from a triamine containing one or more secondary amine salt units and one or more other units selected from monomer units, polymer units and salts thereof, said polymeric additive comprising secondary amine units in a ratio of about 1.005:1 to about 1.15:1 to other monomer units, wherein the amount of secondary amine units is effective to promote acid-dyeability of said polyester composition.
26. The polymeric additive of claim 25 wherein said other monomer units are terephthalate units or naphthalene dicarboxylate units.
27. The polymeric additive of claim 25 , comprising about a 1 mole % to about a 10 mole % excess of said triamine such that said polymeric additive is end capped with primary amine units.