Fuel lubricity additives derived from hydrocarbyl succinic anhydrides and hydroxy amines, and middle distillate fuels containing same
View Patent ↗A middle distillate fuel additive comprising the reaction product resulting from the combining of a hydrocarbyl succinic anhydride and a hydroxyamine. The lubricating properties of low sulfur-content middle distillate fuels, such as diesel, jet or bio-diesel fuels, can be significantly improved by inclusion therein of such additive compounds. The use of these middle distillate fuel additives makes it possible to avoid mechanical failure problems, such as fuel pump or injector failure, otherwise caused by inadequate fuel lubricity, while still retaining the environmental benefits of using a low sulfur fuel.
1. A low sulfur-content fuel composition comprising a low sulfur-content middle distillate fuel and an additive comprising the reaction product resulting from the combining of a substituted hydrocarbyl succinic anhydride and 3-amino-1,2-propanediol, wherein the hydrocarbyl group that is substituted on the succinic anhydride is a branched or a mixture of straight and branched hydrocarbyl groups having 8 to 24 carbon atoms.
2. The fuel composition of claim 1 , wherein the middle distillate fuel is selected from diesel fuel, jet fuel or bio-diesel fuel.
3. The fuel composition of claim 1 , wherein the sulfur content of the fuel composition is no more than 500 ppm.
4. The fuel composition of claim 1 , wherein the additive compound is present in the fuel composition in an amount of 10 to 1000 ppm.
5. A middle distillate fuel composition comprising a major amount of a low sulfur-content middle distillate fuel comprising a sulfur content of less than 0.2% by weight or less, and a minor amount of an additive comprising the reaction product of a hydrocarbyl succinic anhydride and 3-amino-1,2-propanediol, wherein the hydrocarbyl group that is substituted on the succinic anhydride is a branched or mixture of straight and branched hydrocarbyl groups having 8 to 24 carbon atoms.
6. A The fuel composition comprising a major amount of a low sulfur-content middle distillate fuel comprising a sulfur content of less than 0.2% by weight or less, and a minor amount of an additive comprising the reaction product of a hydrocarbyl succinic anhydride and 3-amino- 1,2-propanediol, wherein the hydrocarbyl succinic anydride comprises a mixture of hexadecenyl succinic anhydride and octadecenyl succinic anhydride.
7. The fuel composition of claim 5 , wherein the hydrocarbyl group is monounsaturated.
8. The middle distillate fuel composition of claim 5 , wherein the middle distillate fuel has a maximum sulfur content of 500 ppm by weight.
9. The middle distillate fuel composition of claim 5 , wherein additive is present in the fuel composition in an amount of 10 to 1000 ppm by weight.
10. The middle distillate fuel composition of claim 5 , wherein additive is present in an amount of 25 to 250 ppm by weight.
11. The middle distillate fuel composition of claim 5 , wherein the middle distillate fuel comprises diesel fuel.
12. The middle distillate fuel composition of claim 5 , wherein the additive is non-acidic.
13. A method of reducing wear on a middle distillate fuel pump pumping middle distillate fuel, said method comprising adding to the middle distillate fuel a minor amount of an additive comprising the reaction product resulting from the combining of a substituted hydrocarbyl succinic anhydride and 3-amino-1,2-propanediol, wherein the hydrocarbyl group that is substituted on the succinic anhydride is a branched or a mixture of straight and branched hydrocarbyl groups having 8 to 24 carbon atoms.
14. A method of improving the lubricity of a middle distillate fuel, said method comprising adding to the middle distillate fuel a minor amount of an additive comprising the reaction product resulting from the combining of a substituted hydrocarbyl succinic anhydride and 3-amino-1,2-propanediol, wherein the hydrocarbyl group that is substituted on the succinic anhydride is a branched or mixture of straight and branched hydrocarbyl groups having 8 to 24 carbon atoms.