IP Library Granted Patent US 7,026,038
Granted Patent B2
US 7,026,038 · App. 10/108,854 · Granted Apr 11, 2006

Wear resistant laminates

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Quick Facts
Patent No.
US 7,026,038
App. No.
10/108,854
Granted
Apr 11, 2006
Kind
B2
Abstract

Laminates of improved wear resistant are made using decor sheets prepared by treating printed décor paper with a mordant so that decorative ink is bonded to the paper. The decor sheets are then suitable for use in high pressure or low pressure laminates.

Claims (7)

1. A high pressure decorative laminate including a décor sheet bonded to a substrate, and a protective overcoating comprising particles of an abrasion resistant mineral said décor sheet comprising paper having a print on a surface thereof, and said décor sheet being impregnated with a thermosettable resin and a mordant, said mordant adhering said print to said surface, and wherein the abrasion resistant mineral particles comprise larger particles and smaller particles, said smaller particles having a mean particle diameter of approximately one-half of said larger particles.

2. The décor sheet of claim 1 wherein the paper sheet is formed of cellulose.

3. The décor sheet of claim 1 wherein said mordant is selected from the group consisting of citric acid, aluminum phosphate, sodium format, calcium acetate, aluminum sulfate, zirconium salts, potassium aluminum sulfate, potassium dichromate or bichromate, copper sulfate, ferrous sulfate, stannous chloride, sodium dithionite, sodium hydrosulfite, ammonium hydroxide, potassium bitartrate, sodium sulfate, calcium oxide, sodium hydroxide, oxalic acid, tannic acid, urea, acetic acid, sodium carbonate, iron salts, copper salts, tin salts, citric acid, calcium acetate and mixtures thereof.

4. The décor sheet of claim 1 wherein said print is from a water-based ink.

5. The decorative laminate of claim 1 wherein said larger particles are alumina particles of a mean particles size of approximately 30˜35 μm, and said smaller particles are silica gel particles.

6. The decorative laminate according to claim 1 wherein the mordant is applied in an amounts of from about 0.0045 to 0.28 g/m 2 of paper.

7. The décor sheet of claim 3 wherein the mordant is selected from the group consisting of calcium acetate, aluminum phosphate and citric acid.

Assignments (15)
NOTICE OF SECURITY INTEREST IN PATENTS Recorded Jul 28, 2016
From: PANOLAM INDUSTRIES INTERNATIONAL, INC.; NEVAMAR COMPANY, LLC
To: SJC DLF III-D, LLC
Reel/Frame 039502/0831 →
SECURITY INTEREST Recorded Jun 6, 2016
From: PANOLAM INDUSTRIES INTERNATIONAL, INC.; NEVAMAR COMPANY, LLC
To: BANK OF AMERICA, N.A.
Reel/Frame 038814/0017 →
RELEASE OF SECURITY INTEREST Recorded Jun 3, 2016
From: CORTLAND CAPITAL MARKET SERVICES LLC
To: NEVAMAR COMPANY, LLC
Reel/Frame 038804/0446 →
RELEASE OF SECURITY INTEREST Recorded Jun 3, 2016
From: ANTARES CAPITAL LP
To: NEVAMAR COMPANY, LLC
Reel/Frame 038803/0209 →
ASSIGNMENT OF INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Oct 5, 2015
From: GENERAL ELECTRIC CAPITAL CORPORATION, AS RETIRING AGENT
To: ANTARES CAPITAL LP, AS SUCCESSOR AGENT
Reel/Frame 036754/0494 →
SUCCESSOR AGENT AGREEMENT Recorded Oct 14, 2014
From: APOLLO LAMINATES AGENT, LLC
To: CORTLAND CAPITAL MARKET SERVICES LLC
Reel/Frame 033987/0539 →
LIEN Recorded Sep 5, 2012
From: NEVAMAR COMPANY, LLC
To: APOLLO LAMINATES AGENT, LLC
Reel/Frame 028897/0306 →
SECURITY AGREEMENT Recorded Aug 27, 2012
From: NEVAMAR COMPANY, LLC
To: GENERAL ELECTRIC CAPITAL CORPORATION, AS AGENT
Reel/Frame 028851/0014 →
RELEASE OF SECURITY INTEREST Recorded Aug 24, 2012
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: NEVAMAR COMPANY, LLC
Reel/Frame 028846/0144 →
GRANT OF PATENT SECURITY INTEREST Recorded Dec 28, 2009
From: NEVAMAR COMPANY, LLC
To: APOLLO LAMINATES AGENT, LLC, AS ADMINISTRATIVE AGENT
Reel/Frame 023708/0214 →
GRANT OF SECURITY INTEREST (FIRST LIEN) Recorded Dec 24, 2009
From: NEVAMAR COMPANY, LLC
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH AS ADMINISTRATIVE AGENT
Reel/Frame 023699/0771 →
RELEASE OF SECURITY INTEREST Recorded Mar 2, 2006
From: GENERAL ELECTRIC CAPITAL CORPORATION
To: NEVAMAR COMPANY, LLC
Reel/Frame 017240/0480 →
SECURITY AGREEMENT Recorded Dec 16, 2003
From: NEVAMAR COMPANY, LLC
To: GENERAL ELECTRIC CAPITAL CORPORATION, AS AGENT
Reel/Frame 014201/0292 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 2, 2003
From: INTERNATIONAL PAPER COMPANY
To: NEVAMAR COMPANY, LLC
Reel/Frame 013767/0714 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 16, 2002
From: FRANZOI, ERIC; LAPRADE, SCOTT; PRASAD, SRIKANTH
To: INTERNATIONAL PAPER
Reel/Frame 013087/0063 →