Fibrous absorbent articles having malodor counteractant

1. A tampon for absorbing malodor in a vagina consisting of:

a plurality of fibers that form a fibrous absorbent body, the fibrous absorbent body having an outer surface, and

an anionic surface active agent concentrated at said outer surface,

wherein said outer surface with said anionic surface active agent concentrated thereon forms an interface area between the fibrous absorbent body and the malodor,

wherein said interface area has an interfacial free energy that increases when said anionic surface active agent adsorbs malodor in the interface area,

wherein said anionic surface active agent is selected from the group consisting of sodium alkyl aryl ethoxy sulfate, alkylalkoxylated phosphate ester sodium salt, dioctylester of sodium sulfosuccinic acid, ammonium salt of polycarboxylic acid, potassium salt of complex organic phosphate ester, ammonium lauryl ether sulfate, and any combinations thereof, and

wherein said anionic surface active agent is present in the tampon in an amount about 0.001 wt. % to about 30 wt. %, based on a total weight of said tampon.

2. A tampon for absorbing malodor in a vagina consisting of:

a plurality of fibers that form a fibrous absorbent body, the fibrous absorbent body having an outer surface, and

a nonionic surface active agent concentrated at said outer surface,

wherein said outer surface with said nonionic surface active agent concentrated thereon forms an interface area between the fibrous absorbent body and the malodor,

wherein said interface area has an interfacial free energy that increases when said nonionic surface active agent adsorbs malodor in interface area,

wherein said nonionic surface active agent is selected from the group consisting of polyoxyethylene, polyoxyethylene stearic acid, polyoxyethylene 40 hydrogenated castor oil, alkanolamide, isostearyl alcohol, ethoxylated linear alcohols, PEG-2 stearate, polyoxyalkylated isostearyl alcohol, polyoxyethylene sorbitan monostearate, polysorbate 80, polyoxyethylene 20, polyoxyethylene 20 sorbitan monooleate, silicone glycol copolymer, glycol distearate, ethoxylated alcohol, glycol ester, and any combinations thereof, and

wherein said at least one nonionic surface active agent is present in the tampon in an amount about 0.001 wt. % to about 30 wt. %, based on a total weight of said tampon.

3. The tampon of claim 2 , wherein said nonionic surface active agent is polyoxyethylene 20, and is present in an amount of between 0.64 wt % to 1.25 wt %, based on a total weight of the tampon.

4. A tampon for absorbing malodor in a vagina consisting of:

a plurality of fibers that form a fibrous absorbent body, the fibrous absorbent body having an outer surface, and

a silicone-based surface active agent concentrated at the outer surface,

wherein said outer surface with said silicone-based surface active agent concentrated thereon forms an interface area between the fibrous absorbent body and the malodor,

wherein said interface area has an interfacial free energy that increases when said silicone-based surface active agent adsorbs malodor in the interface area,

wherein said silicone-based surface active agent is selected from the group consisting of cetyl dimethicone copolyol, dialkoxy dimethyl polysiloxane, polysiloxane polyalkyl copolymer, and any combinations thereof, and

wherein said silicone-based surface active agent is present in the tampon in an amount about 0.001 wt. % to about 30 wt. %, based on a total weight of said tampon.

5. A tampon for absorbing malodor in a vagina consisting of a plurality of fibers that form a fibrous absorbent body, the fibrous absorbent body having an outer surface, and

an acrylates/C10-30 alkyl acrylate crosspolymer adsorbed thereon and concentrated at said outer surface,

wherein said outer surface with said acrylates/C10-30 alkyl acrylate crosspolymer concentrated at said outer surface forms an interface area between the fibrous absorbent body and the malodor,

wherein said interface area has an interfacial free energy that increases when said acrylates/C10-30 alkyl acrylate crosspolymer adsorbs onto the interface area, and

wherein said acrylates/C10-30 alkyl acrylate crosspolymer is present in the tampon in an amount about 0.001 wt. % to about 30 wt. %, based on a total weight of said tampon.

6. A method for counteracting vaginal malodor comprising the steps of:

providing a tampon having a plurality of fibers that form a fibrous absorbent body, the fibrous absorbent body having an outer surface that forms an interface area between the fibrous absorbent body and the malodor; and

disposing about 0.001 wt. % to about 30 wt. %, based on a total weight of said tampon, of at least one surface active agent on said tampon, wherein said at least one surface active agent is concentrated at said outer surface, the interface area having an interfacial free energy that increases when the at least one surface active agent adsorbs malodor in the interface area, wherein the vaginal malodor has one or more malodor molecules that are chemically bound by the at least one surface active agent onto the interface area, and wherein said surface active agent is selected from the group consisting of:

anionic surface active agent selected from the group consisting of sodium alkyl aryl ethoxy sulfate, alkylalkoxylated phosphate ester sodium salt, dioctylester of sodium sulfosuccinic acid, ammonium salt of polycarboxylic acid, potassium salt of complex organic phosphate ester, ammonium lauryl ether sulfate;

nonionic surface active agent selected from the group consisting of polyoxyethylene, polyoxyethylene stearic acid, polyoxyethylene 40 hydrogenated castor oil, alkanolamide, isostearyl alcohol, ethoxylated linear alcohols, PEG-2 stearate, polyoxyalkylated isostearyl alcohol, polyoxyethylene sorbitan monostearate, polysorbate 80, polyoxyethylene 20, polyoxyethylene 20 sorbitan monooleate, silicone glycol copolymer, glycol distearate, ethoxylated alcohol, glycol ester;

cationic surface active agent selected from the group consisting of distearyl dimonium chloride, benzethonium chloride;

amphoteric surface active agent selected from the group consisting of coconut-based imidazoline, coconut-based dicarboxylate, coconut-based sodium salt, betaine derivative, octyl dipropionate, cocamphoglycinate;

silicone-based surface active agent selected from the group consisting of cetyl dimethicone copolyol, dialkoxy dimethyl polysiloxane, polysiloxane polyalkyl copolymer; and

any combinations of the above,

wherein the tampon consists of said plurality of fibers and said surface active agent.

7. The method of claim 6 , wherein said nonionic surface active agent is polyoxyethylene 20, and wherein between 0.64 wt % to 1.25 wt %, based on a total weight of the tampon, of said nonionic surface active agent is disposed on said tampon.

8. A method for counteracting vaginal malodor comprising the steps of:

providing a tampon having a plurality of fibers that form a fibrous absorbent body, the fibrous absorbent body having an outer surface that forms an interface area between the fibrous absorbent body and the malodor; and

disposing about 0.001 wt. % to about 30 wt. %, based on a total weight of said tampon, of an acrylates/C10-30 alkyl acrylate crosspolymer on said tampon, wherein said acrylates/C10-30 alkyl acrylate crosspolymer is concentrated at said outer surface, the interface area having an interfacial free energy that increases when the acrylates/C10-30 alkyl acrylate crosspolymer is adsorbs malodor in the interface area, and wherein the vaginal malodor has one or more malodor molecules that are chemically bound by said acrylates/C10-30 alkyl acrylate crosspolymer onto the interface area,

wherein the tampon consists of said plurality of fibers and said acrylates/C10-30 alkyl acrylate crosspolymer.