IP Library Granted Patent US 6,861,023
Granted Patent B2
US 6,861,023 · App. 10/128,975 · Granted Mar 1, 2005

Process for making lyocell fiber from sawdust pulp

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Quick Facts
Patent No.
US 6,861,023
App. No.
10/128,975
Granted
Mar 1, 2005
Kind
B2
Abstract

A process for making lyocell fibers including the steps of pulping raw material in a digester to provide an alkaline pulp, wherein the raw material includes sawdust in an amount greater than 0% up to 100%; contacting the alkaline pulp including cellulose and at least about 7% hemicellulose under alkaline conditions with an amount of an oxidant sufficient to reduce the average degree of polymerization of the cellulose to the range of from about 200 to about 1100 without substantially reducing the hemicellulose content or substantially increasing the copper number of the pulp; and forming fibers from the pulp.

Claims (11)

1. A process for making lyocell fibers comprising the steps of:

(a) pulping raw material in a digester to provide an alkaline pulp, wherein the raw material comprises sawdust in an amount greater than 0% up to 100%;

(b) contacting the alkaline pulp comprising cellulose and at least about 7% hemicellulose under alkaline conditions with an amount of an oxidant sufficient to reduce the average degree of polymerization of the cellulose to the range of from about 200 to about 1100 without substantially reducing the hemicellulose content or substantially increasing the copper number of the pulp; and

(c) forming fibers from the pulp treated in accordance with step (b).

2. The process of claim 1 , wherein the oxidant is selected from the group consisting of a chemical with a peroxide group, oxygen, hydrogen peroxide, chlorine dioxide, ozone, and combinations thereof.

3. The process of claim 1 , wherein the reduction in the average degree of polymerization of the cellulose occurs in the presence of a ratio of magnesium to transition metals of less than about 50%.

4. The process of claim 1 , wherein the hemicellulose content is reduced less than about 15%.

5. The process of claim 1 , wherein the copper number increases less than about 25%.

6. The process of claim 1 , wherein the contacting step occurs in the substantial absence of an inhibitor to the degradation of the cellulose by the oxidant.

7. The process of claim 1 , wherein the alkaline pulp and oxidant are contacted at a pH greater than about 8.0.

8. The process of claim 1 , further comprising a step of dissolving the pulp after step (b) in a solvent for forming into a spinnable dope, wherein the pulp is readily dissolved in NMMO monohydrate within 10 minutes using the test of Example 3.

Assignments (3)
SECURITY INTEREST Recorded Aug 8, 2025
From: EXFO INC. (A CORPORATION RESULTING FROM THE AMALGAMATION OF 11172239 CANADA INC. AND EXFO INC.); ONTOLOGY-PARTNERS LIMITED
To: NATIONAL BANK OF CANADA
Reel/Frame 072338/0500 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 5, 2019
From: WEYERHAEUSER NR COMPANY
To: INTERNATIONAL PAPER COMPANY
Reel/Frame 049964/0838 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 21, 2009
From: WEYERHAEUSER COMPANY
To: WEYERHAEUSER NR COMPANY
Reel/Frame 022835/0233 →