IP Library Granted Patent US 7,244,481
Granted Patent B2
US 7,244,481 · App. 10/142,160 · Granted Jul 17, 2007

Nylon food casing having a barrier core layer

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Quick Facts
Patent No.
US 7,244,481
App. No.
10/142,160
Granted
Jul 17, 2007
Kind
B2
Abstract

Tubular, biaxially stretched, heat shrinkable multilayer film food casings comprising inner and outer polyamide layers on either side of a core layer of EVOH surrounded by an inner and outer adhesive layer, and a coextrusion process for making the film.

Claims (20)

1. A tubular, biaxially stretched, heat shrinkable, multilayer film, food casing comprising:

(a) from at least about 8% to about 15% by weight of the total weight of the casing, an inner layer comprising a polyamide that is meat-adhering;

(b) from at least about 15% to about 20% by weight of the total weight of the casing, an inner adhesive layer adjacent to said inner layer, comprising a LLDPE or blend of LLDPE and EVA;

(c) from at least about 3% to about 5% by weight of the total weight of the casing, a core layer adjacent to said inner adhesive layer comprising EVOH;

(d) from at least about 15% to about 20% by weight of the total weight of the casing, an outer adhesive layer adjacent to said core layer, comprising a LLDPE or blend of LLDPE and EVA; and

(e) from at least about 45% to about 55% by weight of the total weight of the casing, an outer layer comprising a copolyamide;

wherein said multilayer film has a shrinkage value of at least 15% in both the transverse direction and the machine direction at 90° C.

2. A casing, as defined in claim 1 , wherein said film has a shrinkage value of at least 15% to about 20% at 90° C.

3. A casing, as defined in claim 1 , wherein said layers (a), (b), (c), (d) and (e) are coextruded.

4. A casing, as defined in claim 1 , wherein said multilayer film has a thickness of between about 40 to about 60 microns.

5. A casing, as defined in claim 1 , wherein said inner layer (a) comprises nylon 6.

6. A casing, as defined in claim 1 , wherein said outer layer (e) comprises nylon 6/66.

7. A casing as defined in claim 1 , wherein said inner adhesive layer and said outer adhesive layer are comprised of a maleic anhydride grafted LLDPE.

8. An encased foodstuff comprising a heat processed fat containing and protein containing foodstuff encased in a tubular, biaxially stretched, heat shrinkable, multilayer film, food casing comprising:

(a) from at least about 8% to about 15% by weight of the total weight of the casing, an inner layer comprising a polyamide that is meat-adhering;

(b) from at least about 15% to about 20% by weight of the total weight of the casing, an inner adhesive layer adjacent to said inner layer, comprising a LLDPE or blend of LLDPE and EVA;

(c) from at least about 3% to about 5% by weight of the total weight of the casing, a core layer adjacent to said inner adhesive layer comprising EVOH;

(d) from at least about 15% to about 20% by weight of the total weight of the casing, an outer adhesive layer adjacent to said core layer, comprising a LLDPE or blend of LLDPE and EVA; and

(e) from at least about 45% to about 55% by weight of the total weight of the casing, an outer layer comprising a copolyamide;

wherein said multilayer film has a shrinkage value of at least 15% in both the transverse direction and the machine direction at 90° C., wherein said foodstuff is in direct contact with said inner layer (a) and adheres thereto.

Assignments (18)
SECURITY INTEREST Recorded Apr 6, 2026
From: VISKASE COMPANIES, LLC (F/K/A VISKASE COMPANIES, INC.)
To: BANK OF AMERICA, N.A.
Reel/Frame 074285/0478 →
SECURITY INTEREST Recorded Apr 3, 2026
From: VISKASE COMPANIES, LLC
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 074269/0781 →
RELEASE OF SECURITY INTEREST Recorded Oct 9, 2020
From: UBS AG, STAMFORD BRANCH, AS COLLATERAL AGENT
To: VISKASE COMPANIES, INC.
Reel/Frame 054020/0852 →
RELEASE OF SECURITY INTEREST Recorded Oct 9, 2020
From: ICAHN ENTERPRISES HOLDINGS L.P.
To: VISKASE COMPANIES, INC.
Reel/Frame 054045/0332 →
SECURITY INTEREST Recorded Oct 9, 2020
From: VISKASE COMPANIES, INC.
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 054017/0185 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Feb 26, 2014
From: VISKASE COMPANIES, INC.
To: UBS AG, STAMFORD BRANCH, AS COLLATERAL AGENT
Reel/Frame 032360/0753 →
SECURITY AGREEMENT Recorded Feb 20, 2014
From: VISKASE COMPANIES, INC.
To: UBS AG, STAMFORD BRANCH
Reel/Frame 032288/0926 →
RELEASE OF SECURITY INTEREST Recorded Jan 31, 2014
From: U.S. BANK NATIONAL ASSOCIATION
To: VISKASE COMPANIES, INC.
Reel/Frame 032146/0802 →
MERGER Recorded Jan 24, 2014
From: VISKASE CORPORATION
To: VISKASE COMPANIES, INC.
Reel/Frame 032045/0226 →
SECURITY INTEREST Recorded May 6, 2010
From: ARNOS CORP.
To: ICAHN ENTERPRISES HOLDINGS L.P.
Reel/Frame 024342/0595 →
RELEASE OF SECURITY INTERESTS IN INTELLECTUAL PROPERTY Recorded Dec 23, 2009
From: U.S. BANK NATIONAL ASSOCIATION, AS SUCCESSOR COLLATERAL AGENT TO BANK OF AMERICA, N.A. (AS SUCCESSOR TO LASALLE BANK NATIONAL ASSOCIATION)
To: VISKASE COMPANIES, INC.
Reel/Frame 023691/0340 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Dec 23, 2009
From: VISKASE COMPANIES, INC.
To: U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 023691/0353 →
SECURITY AGREEMENT Recorded Feb 4, 2009
From: BANK OF AMERICA, N.A., AS SUCCESSOR TO LASALLE BANK NATIONAL ASSOCIATION
To: U.S. BANK NATIONAL ASSOCIATION
Reel/Frame 022203/0273 →
SECURITY AGREEMENT Recorded Nov 16, 2007
From: VISKASE COMPANIES, INC.
To: ARNOS CORP.
Reel/Frame 020119/0563 →
RELEASE OF SECURITY INTEREST Recorded Jul 13, 2004
From: ARNOS CORP.
To: VISKASE COMPANIES, INC.
Reel/Frame 014845/0857 →
SECURITY AGREEMENT Recorded Jul 2, 2004
From: VISKASE COMPANIES, INC.
To: LASALLE BANK NATIONAL ASSOCIATION
Reel/Frame 014815/0082 →
SECURITY AGREEMENT Recorded Apr 14, 2003
From: VISKASE COMPANIES, INC.
To: ARNOS CORP.
Reel/Frame 013913/0851 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 28, 2002
From: VICIK, STEPHEN J.; GLAWE, AMY L.
To: VISKASE CORPORATION
Reel/Frame 012935/0025 →