Anti-foaming preparation and use thereof
View Patent ↗The anti-foaming preparations comprise aqueous formulations, which contain at least one substance, from the group of polyhydroxy compounds, non-ionic detergents and phosphoric acid esters and their salts, preferably alkyl polygluocosides, alkoxylated long-chain alcohols and an alkali salt of a phosphoric acid partial-ester. The particular advantage of said aqueous formulations is that they are stable when included in highly alkaline cleaning concentrates.
1. An antifoaming preparation which is suitable for providing a stable highly alkaline-aqueous cleaner comprising more than 40% by weight of alkali metal hydroxide, based on the total weight of the cleaner, the antifoaming preparation comprising
a) at least one alkyl polyglucoside;
b) at least one alkoxylated alkyl alcohol having 8 to 22 carbon atoms in the alkyl chain; and
c) at least one salt of a phosphoric partial ester of alkoxylated alkylphenol.
2. The preparation as claimed in claim 1 , wherein the content of alkali metal hydroxide in the resulting cleaner is greater than 70% by weight, based on the total weight of the cleaner.
3. The preparation as claimed in claim 1 , wherein the constituent b) is at least one compound from the group of mixed ethoxylates/propoxylates of branched or unbranched alkyl alcohols having 8 to 22 carbon atoms in the alkyl chain and of the group of terminally capped ethoxylates of branched or unbranched alkyl alcohols having 8 to 22 carbon atoms in the alkyl chain.
4. The preparation as claimed in claim 3 , wherein the constituent b) represents at least one compound from the group of ethoxylated and propoxylated alkyl alcohols having 12 to 22 carbon atoms in the alkyl moiety, group of butyl ethers of an ethoxylated alkyl alcohol having 12 to 22 carbon atoms in the alkyl moiety and group of methyl ethers of an ethoxylated alkyl alcohol having 12 to 22 carbon atoms in the alkyl moiety.
5. The preparation as claimed in claim 1 , wherein the component a) is at least one alkyl polyglucoside having 8 to 14 carbon atoms in the alkyl group and 1 to 5 glucose units.
6. The preparation as claimed in claim 1 , wherein based on the total preparation, the constituents are present in the following amounts:
a) 1 to 30% by weight and
b) 1 to 30% by weight and
c) 1 to 30% by weight.
7. The preparation as claimed in claim 6 , wherein based on the total based on the total preparation, the constituents are present in the following amounts:
a) 2 to 20% by weight and
b) 2 to 20% by weight and
c) 2 to 20% by weight.
8. The preparation as claimed in claim 1 , wherein the constituents (a):(b):(c) are present in a weight ratio of (1 to 2):(2:3):(1 to 2).
9. The preparation as claimed in claim 1 , wherein at least one component which can be detected by ion-selective determination is additionally present.
10. The preparation as claimed in claim 9 , wherein the component which can be detected by ion-selective determination is a halide.
11. The preparation as claimed in claim 9 , wherein the component which can be detected by ion-selective determination is present in a concentration of from 0.01 to 2% by weight, based on the total preparation.
12. A cleaner, which based on the total cleaner, comprises
A) 1 to 30% by weight of an anti-foaming preparation comprising:
a) at least one alkyl polyglucoside,
b) at least one alkoxylated alkyl alcohol having 8 to 22 carbon atoms in the alkyl chain, and
c) at least one salt of a phosphoric partial ester of alkoxylated alkylphenol; and
B) more than 40% by weight of alkali metal hydroxide.
13. The cleaner according to claim 12 , further comprising further active ingredients and additives.
14. A method for using a cleaner comprising:
cleaning with the cleaner in a cleaning operation where foaming is troublesome, the cleaner comprising:
A) 1 to 30% by weight of an anti-foaming preparation comprising:
a) at least one alkyl polyglucoside,
b) at least one alkoxylated alkyl alcohol having 8 to 22 carbon atoms in the alkyl chain, and
c) at least one salt of a phosphoric partial ester of alkoxylated alkylphenol; and
B) more than 40% by weight of alkali metal hydroxide.
15. The method according to claim 14 , wherein the cleaner is diluted for use to 0.05 to 6% by weight, based on the total cleaning solution.
16. The method according to claim 14 , wherein the cleaning operation comprises a cleaning process in the food industry.
17. The method according to claim 16 , wherein the cleaning operation comprises bottle cleaning.
18. The method according to claim 14 , wherein the cleaning operation comprises CIP cleaning.
19. The method according to claim 14 , wherein the cleaning operation comprises a cleaning process in the pharmaceutical or cosmetics industry.
20. The method according to claim 14 , wherein the cleaning operation comprises no addition of antifoams to the cleaner.
21. A cleaner, which based on the total cleaner, comprises
A) 1 to 10% by weight of an anti-foaming preparation comprising:
a) at least one alkyl polyglucoside,
b) at least one alkoxylated alkyl alcohol having 8 to 22 carbon atoms in the alkyl chain, and
c) at least one salt of a phosphoric partial ester; and
B) more than 70% by weight of alkali metal hydroxide.
22. The preparation as claimed in claim 21 , wherein the constituent c) is at least one alkali metal salt of a phosphoric acid partial ester of alkoxylated alkylphenol.