UV curable and electrically conductive adhesive for bonding magnetic disk drive components
View Patent ↗An electrically conductive adhesive includes a resin component, a photoinitiator, and metal-coated polymer beads. The beads have an average diameter and a very narrow size distribution around the average diameter. The adhesive is applied between a read/write head and a suspension to attach the two, and the adhesive is cured by exposure to an illumination and/or heat. The beads in the adhesive can form a monolayer between the read/write head and the suspension such that a spacing therebetween is equal to the average diameter of the beads. The metal coating of the beads provide electrical conductivity between the read/write head and the suspension.
1. An electrically conductive adhesive, comprising:
a binder including
a resin component; and
a photoinitiator; and
a filler including metal-coated polymer beads having a highly conductive and corrosion resistant material including a seed layer and an outer layer dispersed within the binder.
2. The electrically conductive adhesive of claim 1 , wherein the resin component includes an unsaturated monomer.
3. The electrically conductive adhesive of claim 1 , wherein the resin component includes an oligomer.
4. The electrically conductive adhesive of claim 1 , wherein the resin component includes a mono-functional acrylic monomer.
5. The electrically conductive adhesive of claim 4 , wherein the mono-functional acrylic monomer is selected from the group consisting of allylmethacrylate, tetrahydrofurfurylmethacrylate, isodecylmethacrylate, 2-(2-ethoxyethoxy) ethylacrylate, laurylmethacylate, stearyl methacrylate, lauryl acryalte, 2-phenoxyethyl acrylate, 2-phenoxyethyl methacrylate, isodecyl acrylate, isobornyl methacrylate, tetraethylene glycol dimethacrylate, polyethylene glycol dimethacrylate, diethylene glycol dimethacrylate, 1,6-hexanediol diacrylate, tripropylene glycol diacrylate, and dipropylene glycol diacrylate.
6. The electrically conductive adhesive of claim 1 , wherein the resin component includes a di-functional acrylic monomer.
7. The electrically conductive adhesive of claim 6 , wherein the di-functional acrylic monomer is selected from the group consisting of tetraethylene glycol dimethacrylate, polyethylene glycol dimethacrylate, diethylene glycol dimethacrylate, 1,6-hexanediol diacrylate, tripropylene glycol diacrylate, and dipropylene glycol diacrylate.
8. The electrically conductive adhesive of claim 1 , wherein the resin component includes a multi-functional acrylic monomer.
9. The electrically conductive adhesive of claim 8 , wherein the multi-functional acrylic monomer is selected from the group consisting of pentaerythritol triacrylate, ethoxylated trimethylolpropane triacrylate, propoxylated trimethyolopropane triacrylate, propoxylated glyceryl triacrylate, pentaerythritol tetraacrylate, di-trimethylolpropane tetraacrylate, di-pentaerythritol pentaacrylate, and ethoxylated pentaerythritol tetraacrylate.
10. The electrically conductive adhesive of claim 1 , wherein the resin component includes a urethane acrylate.
11. The electrically conductive adhesive of claim 1 , wherein the resin component includes an epoxy acrylate.
12. The electrically conductive adhesive of claim 1 , wherein the photoinitiator is a visible-light photoinitiator.
13. The electrically conductive adhesive of claim 1 , wherein the photoinitiator is a UV photoinitiator.
14. The electrically conductive adhesive of claim 1 , wherein the photoinitiator includes a UV photoinitiator and a visible-light photoinitiator.
15. The electrically conductive adhesive of claim 1 , wherein the photoinitiator is a mixture of two or more photoinitiators having different maximum absorption wavelengths.
16. The electrically conductive adhesive of claim 1 , wherein the photoinitiator is a UV photoinitiator of a free radical type.
17. The electrically conductive adhesive of claim 16 , wherein the UV photoinitiator is selected from the group consisting of 1-hydroxycyclohexyl phenyl ketone, 2-benzyl-2,N,N-dimethylamino-1-(4-morpholinophenyl)-1-butanone, 2-hydroxy-2-methyl-1-phenyl propane-1-one, a 50:50 blend of 2-hydroxy-2-methyl-1-phenyl propane-1-one and 2,4,6-trimethylbenzoyldiphenylphosphine oxide, 4-(2-hydroxyethoxy)Phenyl-(2-Propyl)Ketone, an alpha-amino acetophenone derivative, a mixture of 1-hydroxycyclohexyl phenyl ketone and benzophenone, 2,2-dimethoxy-2-phenylacetophenone, and trimethylbenzophenone blends.
18. The electrically conductive adhesive of claim 1 , wherein the photoinitiator is a UV photoinitiator of a cationic type.
19. The electrically conductive adhesive of claim 18 , wherein the UV photoinitiator is selected from the group consisting of triarylsulfonium hexafluoroantimonate salts and mixed triaryl sulfonium hexafluorophosphate salts.
20. The electrically conductive adhesive of claim 1 wherein the binder further includes a thermal initiator.
21. The electrically conductive adhesive of claim 20 , wherein the thermal initiator is an organic peroxide.
22. The electrically conductive adhesive of claim 20 , wherein the thermal initiator is selected from the group consisting of benzoyl peroxide, soluble hydroperoxides, soluble azonitrile compounds, and mixtures thereof.
23. The electrically conductive adhesive of claim 1 wherein the binder further includes an adhesion promoter.
24. The electrically conductive adhesive of claim 23 wherein the adhesion promoter is selected from the group consisting of beta-(3,4-epoxycyclohexyl)ethyltrimethoxy silane, gamma-glycidoxypropyltrimethoxy silane, gamma-aminopropyl trimethoxysilane, and mixtures of ethoxy and methoxy methacrylate silane.
25. The electrically conductive adhesive of claim 1 wherein the binder further includes a wetting agent.
26. The electrically conductive adhesive of claim 1 , wherein the metal-coated polymer beads are arranged in a monolayer.
27. The electrically conductive adhesive of claim 26 , wherein the metal-coated polymer beads have an average diameter between about 15μ and about 30μ.
28. The electrically conductive adhesive of claim 26 , wherein the metal-coated polymer beads have an average diameter between about 15μ and about 20μ.
29. The electrically conductive adhesive of claim 26 , wherein the metal-coated polymer beads have an average diameter of about 18μ.
30. The electrically conductive adhesive of claim 26 , wherein the metal-coated polymer beads have an average diameter and a size distribution around the average diameter of about 1μ or less.
31. The electrically conductive adhesive of claim 1 , wherein the metal-coated polymer beads include a polymer with a glass transition temperature below room temperature.
32. The electrically conductive adhesive of claim 31 , wherein the glass transition temperature is between about −10° C. and 15° C.
33. The electrically conductive adhesive of claim 1 , wherein the metal-coated polymer beads include polystyrene.
34. The electrically conductive adhesive of claim 1 , wherein the metal-coated polymer beads include a polymer obtained through an emulsion polymerization of a vinyl monomer.
35. The electrically conductive adhesive of claim 34 , wherein the vinyl monomer is selected from the group consisting of methyl acrylate, ethyl acrylate, butyl acrylate, hexyl acrylate, 2-ethylhexyl acrylate, octyl acrylate, isooctyl acrylate, n-decyl acrylate, isodecyl acrylate, tert-butyl acrylate, methyl methacrylate, butyl methacrylate, hexyl methacrylate, isobutyl methacrylate, isopropyl methacrylate, 2-hydroxyethyl acrylate, acrylamide, sec-butyl methacrylate, cyclohexyl methacrylate, isodecyl methacrylate, isobornyl methacrylate, t-butylaminoethyl methacrylate, stearyl methacrylate, glycidyl methacrylate, dicyclopentenyl methacrylate, phenyl methacrylate, styrene, p-methyl styrene, methyl styrene, o,p-dimethyl styrene, o,p-diethyl styrene, p-chlorostyrene, isopropyl styrene, t-butyl styrene, o-methyl-p-isopropyl styrene, o,p-dichlorostyrene, conjugated diene monomers, isoprene, 1,3-pentadiene, 2-ethyl-1,3-butadiene, 4-methyl-1,3-pentadiene, 2-methyl-1,3-butadiene, piperylene (1,3-pentadiene), hydrocarbon analogs of 1,3-butadiene, vinylidene chloride, vinyl chloride, acrylic acid, methacrylic acid, fumaric acid, itaconic acid, maleic acid, aconitic acid, and copolymers made from monomer mixtures thereof.
36. The electrically conductive adhesive of claim 1 , wherein the layer of the highly conductive and corrosion resistant material can have a thickness between about 200 Å to about 1000 Å.
37. The electrically conductive adhesive of claim 1 , wherein the layer of the highly conductive and corrosion resistant material includes silver.
38. The electrically conductive adhesive of claim 1 , wherein the layer of the highly conductive and corrosion resistant material includes gold.
39. The electrically conductive adhesive of claim 1 , wherein the seed layer and the outer layer each have a thickness between about 200 Å to about 1000 Å.
40. The electrically conductive adhesive of claim 1 , wherein the seed layer and the outer layer each have a thickness of about 500 Å.
41. The electrically conductive adhesive of claim 1 , wherein the seed layer is formed of electroless nickel and the outer layer is formed of gold.
42. The electrically conductive adhesive of claim 1 , wherein a ratio by weight of metal-coated polymer beads to binder is between about 20% and about 80%.
43. The electrically conductive adhesive of claim 1 wherein the filler further includes an electrically conductive material selected from the group consisting of metal flakes, metal powders, metal-coated glass beads, metal-coated flakes, metal-coated mica, and mixtures thereof.
44. The electrically conductive adhesive of claim 1 , wherein the cured adhesive has a resistivity of less than 1200% for an applied voltage of 1V as measured between a read/write head and a suspension.