Production method of foamed polypropylene resin beads
View Patent ↗A method for producing expanded polypropylene resin particles wherein polypropylene resin particles impregnated with a physical blowing agent are heated along with an aqueous medium and a dispersant and are released and expanded at reduced pressure from the interior of a pressure-tight vessel, wherein the aforementioned aqueous medium has an electrical conductivity of from not less than 0.00 ms/m to not more than 20.00 mS/m. The resulting particles obtained are without inconsistencies caused by differences in the amount of dispersant adhering to the particles or the amount of dispersant added to prevent the particles from fusing together during the heat treatment step of the method.
1. A method for producing expanded particles by allowing polypropylene resin particles impregnated with a physical blowing agent, which have been heated along with an aqueous medium and a dispersant, to be released and expanded at reduced pressure from the interior of a pressure-tight vessel, wherein the dispersant comprises a mineral-based inorganic substance comprising an aluminosilicate based on a silica-alumina, wherein an aqueous medium with an electrical conductivity of from not less than 0.00 mS/m to not more than 20.00 mS/m is used as the aqueous medium.
2. A method for producing expanded polypropylene resin particles according to claim 1 , wherein the electrical conductivity of the aqueous medium is from not less than 0.01 mS/m to not more than 20.00 mS/m.
3. A method for producing expanded polypropylene resin particles according to claim 1 , wherein the electrical conductivity of the aqueous medium is from not less than 0.01 mS/m to not more than 17.00 mS/m.
4. A method for producing expanded polypropylene resin particles according to claim 1 , wherein the electrical conductivity of the aqueous medium is from not less than 0.02 mS/m to not more than 13.00 mS/m.
5. A method for producing expanded polypropylene resin particles according to claim 1 , wherein the mineral-based inorganic substance comprising an aluminosilicate based on silica-alumina consists of kaolin.
6. A method for producing expanded polypropylene resin particles according to claim 1 , wherein the mineral-based inorganic substance comprising an aluminosilicate based on silica-alumina is used in an amount of from not less than 0.004 weight part to not more than 1.000 weight part per 100 weight parts aqueous medium.
7. A method for producing expanded polypropylene resin particles according to claim 1 , wherein the mineral-based inorganic substance comprising an aluminosilicate based on silica-alumina is used in an amount of from not less than 0.010 weight part to not more than 0.400 weight part per 100 weight parts aqueous medium.
8. A method for producing expanded polypropylene resin particles according to claim 1 , wherein the physical blowing agent comprises a blowing agent based on an inorganic blowing agent.
9. A method for producing expanded polypropylene resin particles according to claim 1 , wherein a blowing agent based on an inorganic blowing agent is used as the physical blowing agent, and a mineral-based inorganic substance comprising an aluminosilicate based on silica-alumina is used as the dispersant.
10. A method for producing expanded polypropylene resin particles according to claim 8 , wherein the inorganic blowing agent consists of air.
11. A method for producing expanded polypropylene resin particles according to claim 8 , wherein the inorganic blowing agent consists of carbon dioxide.
12. A method for producing expanded polypropylene resin particles according to claim 8 , wherein the inorganic blowing agent comprises air and carbon dioxide.
13. A method for producing expanded polypropylene resin particles according to claim 1 , wherein air is used as the physical blowing agent, kaolin is used as the dispersant, and aluminum sulfate is used as a dispersion reinforcer.
14. A method for producing expanded polypropylene resin particles according to claim 1 , wherein the expanded particles have an apparent density of from not less than 100 g/L to not more than 500 g/L.
15. A method for producing expanded polypropylene resin particles according to claim 1 , wherein the endothermic peak of the expanded particles on a DSC curve, as determined by differential scanning calorimetry, is at least 2, and the heat quantity of the endothermic peak on the high temperature side of the endothermic peak is from not less than 2 J/g to not more than 20 J/g.
16. A method for producing expanded polypropylene resin particles according to claim 1 , wherein the amount of dispersant adhering to the surface of the expanded particles is from not less than 50 mg to not more than 200 mg per 100 g by weight of the resulting expanded particles (the sum weight of the weight of the expanded particles themselves and the weight of the dispersant adhering to the surface of the expanded particles).
17. A method for producing expanded polypropylene resin particles according to claim 9 , wherein the inorganic blowing agent consists of air.
18. A method for producing expanded polypropylene resin particles according to claim 9 , wherein the inorganic blowing agent consists of carbon dioxide.
19. A method for producing expanded polypropylene resin particles according to claim 9 , wherein the inorganic blowing agent comprises air and carbon dioxide.