Impact-modified polymer composition
View Patent ↗A thermoplastic molding composition containing talc is disclosed. The composition wherein talc has a median particle size of less than 1000 nm further contains a polycarbonate and/or polyester-carbonate, and a graft polymer having as graft base a rubber having a glass transition temperature of below about 10° C. is suitable for preparing molded articles having improved mechanical properties, such as weld line strength, elongation at break and toughness at low temperatures.
1. A thermoplastic molding composition consisting of:
(A) at least one member selected from the group consisting of aromatic polycarbonate and polyester-carbonate;
(B) at least one graft polymer of,
(B.1) 5 to 95% relative to the weight of the graft polymer of a graft shell that includes the polymerized mixture of,
(B.1.1) 50 to 99 parts by weight of at least one member selected from the group consisting of vinylaromatic monomer, nucleus-substituted vinylaromatic monomer and (C 1 –C 8 )-alkyl ester of methacrylic acid, and
(B.1.2) 1 to 50 parts by weight of at least one member selected from the group consisting of vinyl cyanide, (C 1 –C 8 )-alkyl ester of (meth)acrylic acid, anhydrides of unsaturated carboxylic acids and imides of unsaturated carboxylic acids, the total of the parts by weights being 100, and
(B.2) 95 to 5% relative to the weight of the graft polymer of a graft base that contains a rubber having a glass transition temperature of below about 10° C., said graft base having a median particle size of 0.2 to 1 μm;
(C) talc having median particle diameter of less than 600 nm;
(D) at least one member selected from the group consisting of rubber-free vinyl (co)polymer and polyalkylene terephthalate;
(E) a phosphorous-containing compound represented by the following formula
wherein
R 1 , R 2 , R 3 and R 4 , independently of each other, denote a member selected from the group consisting of C 1 to C 8 -alkyl,
C 5 to C 6 -cycloalkyl, C 6 to C 20 -aryl and C 7 to C 12 -aralkyl,
each n independently of each other, denotes 0 or 1,
q denotes 0 to 30, and
X denotes a mono- or polynuclear aromatic radical having 6 to 30 carbon atoms or a linear or branched aliphatic radical having 2 to 30 carbon atoms;
(F) optionally an anti-dripping agent selected from the group consisting of fluorinated polyolefins and aramids; and
(G) optionally at least one member selected from the group consisting of nucleating agents, antistatics, stabilizers, fillers, reinforcing substances, dyestuffs, pigments, pentaerythritol tetrastearate and further flame proofing agents,
said further flame proofing agents being selected from the group consisting of decabromobisphenyl ether, tetrabromobisphenol, ammonium bromide, melamine, melamine-formaldehyde resins, Mg hydroxide, Al hydroxide, antimony oxides, barium metaborate, hydroxoantimonate, zirconium oxide, zirconium hydroxide, molybdenum oxide, ammonium molybdate, zinc borate, ammonium borate, barium metaborate, silicate, silicon oxide, tin oxide and combinations thereof.
2. The composition according to claim 1 wherein component A is present in an amount of 20 to 90% relative to the weight of the composition.
3. The composition according to claim 1 wherein the graft shell is a copolymer of styrene and acrylonitrile.
4. The composition according to claim 1 wherein the rubber is at least one member selected from the group consisting of diene, ethylene-propylene-diene terpolymer, acrylate, polyurethane, silicone, chloroprene and ethylene/vinyl acetate.
5. The composition according to claim 1 wherein the graft polymer is at least one member selected from the group consisting of emulsion-polymerize acrylonitrile-butadiene-styrene graft polymer and bulk-polymerized acrylonitrile-butadiene-styrene graft polymer.
6. The composition according to claim 1 wherein the graft polymer is present in an amount of 1 to 50% relative to the weight of the composition.
7. The composition according to claim 1 wherein the graft polymer is present in an amount of 2 to 30% relative to the weight of the composition.
8. The composition according to claim 1 wherein the talc is present in an amount of 0.1 to 30% relative to the weight of the composition.
9. The composition according to claim 1 wherein the talc is present in an amount of 1 to 15% relative to the weight of the composition.
10. The composition according to claim 1 wherein component D is present in a positive amount up to 50% relative to the weight of the composition.
11. The composition according to claim 1 wherein the phosphorus-containing compound (E) is represented by the following formula,
wherein q=0.5 to 30.
12. The composition according to claim 1 wherein component E is present in an amount of 1 to 40% based on the weight of the composition.
13. The composition according to claim 1 wherein component B is present in an amount of 2 to 10% based on the weight of the composition.
14. A method of using the composition of claim 1 comprising molding articles.
15. A molded article comprising the composition of claim 1 .
16. A thermoplastic molding composition consisting of:
(A) from 20 to 90% relative to the weight of the composition of at least one member selected from the group consisting of aromatic polycarbonate and polyester-carbonate;
(B) from 1 to 50% relative to the weight of the composition of at least one graft polymer of,
(B.1) 5 to 95% relative to the weight of the graft polymer of a graft shell that includes the polymerized mixture of,
(B.1.1) 50 to 99 parts by weight of at least one member selected from the group consisting of vinylaromatic monomer, nucleus-substituted vinylaromatic monomer and (C 1 –C 8 )-alkyl ester of methacrylic acid, and
(B.1.2) 1 to 50 parts by weight of at least one member selected from the group consisting of vinyl cyanide, (C 1 –C 8 )-alkyl ester of (meth)acrylic acid, anhydrides of unsaturated carboxylic acids and imides of unsaturated carboxylic acids, the total of the parts by weights being 100, and
(B.2) 95 to 5% relative to the weight of the graft polymer of a graft base that contains a rubber having a glass transition temperature of below about 10° C., said graft base having a median particle size of 0.2 to 1 μm;
(C) from 0.1 to 30% relative to the weight of the composition of talc having median particle diameter of less than 600 nm;
(D) from 0 to 50% relative to the weight of the composition of least one member selected from the group consisting of rubber-free vinyl (co)polymer and polyalkylene terephthalate;
(E) from 1 to 40% based on the weight of the composition of a phosphorous-containing compound represented by the following formula
wherein
R 1 , R 2 , R 3 and R 4 , independently of each other, denote a member selected from the group consisting of C 1 to C 8 -alkyl,
C 5 to C 6 -cycloalkyl, C 6 to C 20 -aryl and C 7 to C 12 -aralkyl,
each n independently of each other, denotes 0 or 1;
q denotes 0 to 30; and
X denotes a mono- or polynuclear aromatic radical having 6 to 30 carbon atoms or a linear or branched aliphatic radical having 2 to 30 carbon atoms;
(F) optionally from 0.05 to 10% based on the weight of the composition of an anti-dripping agent selected from the group consisting of fluorinated polyolefins and aramids; and
(G) optionally up to about 35% based on the weight of the composition of at least one member selected from the group consisting of nucleating agents, antistatics, stabilizers, fillers, reinforcing substances, dyestuffs, pigments, pentaerythritol tetrastearate and further flame proofing agents, said further flame proofing agents being selected from the group consisting of decabromobisphenyl ether, tetrabromobisphenol, ammonium bromide, melamine, melamine-formaldehyde resins, Mg hydroxide, Al hydroxide, antimony oxides, barium metaborate, hydroxoantimonate, zirconium oxide, zirconium hydroxide, molybdenum oxide, ammonium molybdate, zinc borate, ammonium borate, barium metaborate, silicate, silicon oxide, tin oxide and combinations thereof.