Aqueous composition
View Patent ↗The present invention relates to an aqueous composition comprising anionic organic polymeric particles and colloidal anionic silica-based particles. The anionic organic polymeric particles are obtainable by polymerising one or more ethylenically unsaturated monomers together with one or more polyfunctional branching agents and/or polyfunctional crosslinking agents. The anionic organic polymeric particles and the colloidal anionic silica-based particles in the aqueous composition are present in an amount of at least 0.01% by weight based on the total weight of the aqueous composition. The present invention further relates to a method for the preparation of the aqueous composition, uses of the aqueous composition and a process for the production or paper, in which the aqueous composition is added to a cellulosic suspension.
1. An aqueous composition comprising anionic organic polymeric particles and colloidal anionic silica-based particles having a specific surface area within the range of from 300 to 1000 m 2 /g, the anionic organic polymeric particles being obtained by polymerising one or more ethylenically unsaturated monomers together with one or more polyfunctional branching agents and/or polyfunctional crosslinking agents, the anionic organic polymeric particles and the colloidal anionic silica-based particles being present in an amount of within the range of from 1 to 45% by weight based on the total weight of the aqueous composition, the colloidal anionic silica-based particles being silica, aluminium-modified silica or amine-modified silica and being contained in a sol having an S-value within the range from 5 to 60% before mixing with the anionic organic polymeric particles.
2. The aqueous composition according to claim 1 , wherein the weight ratio of the colloidal anionic silica-based particles to the anionic organic polymeric particles ranges from 20:1 to 1:50.
3. The aqueous composition according to claim 1 , wherein the weight ratio of the colloidal anionic silica-based particles to the anionic organic polymeric particles ranges from 5:1 to 1:20.
4. The aqueous composition according to claim 1 , wherein the colloidal anionic silica-based particles are aluminium modified silica.
5. The aqueous composition according to claim 1 , wherein the anionic organic polymeric particles comprise one or more monomers selected from the group consisting of (meth)acrylic acids, alkyl (meth)acrylic acids, sulfoalkyl (meth)acrylic acids, unsaturated dicarboxylic acids, sulfonated styrenes, sulfoalkyl (meth)acrylamides, acrylamides, N-alkyl acrylamides, N,N-dialkyl-acrylamides, methacrylamides, vinylacetate, acrylonitrile, N-vinyl methylacetamide and N-vinyl pyrrolidone, and salts of said acids.
6. The aqueous composition according to claim 1 , wherein the polyfunctional branching agent and/or the polyfunctional crosslinking agent has at least two ethylenically unsaturated bonds.
7. The aqueous composition according to claim 1 , wherein the colloidal anionic silica-based particles have a specific surface area within the range of from 500 to 950 m 2 /g.
8. The aqueous composition according to claim 1 , wherein the colloidal anionic silica-based particles have a particle size in the range of from 1 to 1 nm.
9. The aqueous composition according to claim 1 , wherein the colloidal anionic silica-based particles are silica.
10. The aqueous composition according to claim 1 , wherein the colloidal anionic silica-based particles are amine-modified silica.