Retarding agents for preparing purified brine
View Patent ↗The invention relates to a process to produce brine of improved purity wherein a salt source, contaminated with sulphate ions and alkaline (earth) metal ions, is dissolved in water in the presence of an effective amount of a retarding agent comprising at least one low and at least one high molecular weight retarding agent. Said retarding agent effectively reduces the level of the alkaline (earth) metal sulphate dissolved in the brine, particularly the amount of calcium and sulphate. Preferably, the combination of the low and high molecular weight retarding agents is synergetic in the reduction of dissolved alkaline-earth metal sulphate.
1. A process of making a high purity brine from a salt source contaminated with sulfate ions and alkaline (earth) metal ions other than sodium, wherein said process comprises dissolving said salt source in water in the presence of at least a low and high molecular weight retarding agent, wherein said retarding agent comprises at least one low molecular weight compound and at least one high molecular weight compound, wherein
(I) said at least one low molecular weight retarding agent is selected from the group consisting essentially of alkylbeazene sulfonates, whereof the alkyl groups can be linear or branched, phosphate that an water-soluble, ethnylated compounds with one or more sulfite, sulfonate, sulfate, phosphite, phosphonate, phosphate, and/or carboxylgroups, and C 2 –C 40 alkyl compounds with one or more sulfite, sulionate, sulfate, phosphite, phosphonate, phosphate, and/or carboxyl groups, and
(II) said at least one high molecular weight retarding agent is selected from the group consisting essentially of lignosulfates, phospholipids, and polyacrylates.
2. A process of making a high purity brine from a malt source contaminated with sulfate ions and alkaline (earth) metal ions other than sodium, wherein said process comprises dissolving said salt source in water in the presence of at least a low molecular weight retarding agent having a molecular weight of less than 1,000 Dalton selected from the group consisting of: alkylbenzene sulfonates, whereof the alkyl groups can be linear or branched, phosphates that are water-soluble, ethoxylated compounds with one or more sulfite, mnifonate, sulfate, phosphite, phosphonate, phosphate, and/or carboxylgroups, and C 2 –C 40 alkyl compounds with one or more sulfite, sulfonate, sulfate, phosphite, phosphonate, phosphate, and/or carboxyl groups, and a high molecular weight retarding agent having a higher molecular weight than that of said low molecular weight retarding agent but being at least 500 Dalton and wherein said retarding agents are present in an amount effective to reduce the level of said sulfate ions and alkaline (earth) metal ions dissolved In said brine, thereby producing a high purity brine.
3. A process of making a high purity brine from a salt source contaminated with sulfate ions and alkaline (earth) metal ions other than sodium, wherein said process comprises dissolving said salt source in water in the presence of at least a low molecular weight retarding agent having a molecular weight of less than 1,000 Dalton and a high molecular weight retarding agent having a higher molecular weight than that of said low molecular weight retarding agent but being at least 500 Dalton, wherein said retarding agents comprise a mixture of low- and high-molecular weight phospholipids, and wherein said retarding agents are present in an amount effective to reduce the level of said sulfate ions and alkaline (earth) metal ions dissolved in said brine, thereby producing a high purity brine.
4. The process of claim 3 wherein said high molecular weight retarding agent is a high molecular weight phospholipid that is derived from yeast cells.