Betaine esters
View Patent ↗The invention relates to compounds of the general formula (I) in which R a is an ethylenically unsaturated radical having 1 to 5 carbon atoms and containing at least one carbonyl function, and to their homopolymers and copolymers with compounds of the general formula (II) and to the use thereof in hair conditioning agents.
1. An oligomeric or polymeric compound prepared by copolymerization of from 0.5 to 100 mol % of a polymerizable betaine ester of claim 1 ; and 0 to 99.5 mol % of an ethylenically unsaturated comonomer of general formula (II)
in which
R x and R y are H, R w is H or CH 3 and R z is a radical —C(O)OR, —C(O)NR′R″ containing at least one carbonyl group, where R, R′ and R″ are H or hydrocarbon radicals having 1 to 18 carbon atoms.
2. An oligomeric or polymeric compound of claim 1 wherein from 20 to 70 mol % of said polymerizable betaine ester of general formula (I) and 30 to 80 mol % of said unsaturated comonomer of general formula (II) are employed.
3. An oligomeric or polymeric compound of claim 1 wherein from 40 to 60 mol % of said polymerizable betaine ester of general formula (I) and 60 to 40 mol % of said ethylenically unsaturated comonomer of general formula (II) are employed.
4. A polymeric compound as claimed in claim 1 comprising, as comonomers, compounds of formula (II) wherein R w and R x are H, R y and R z are radicals —C(O)OR, —C(O)NR′R″ containing a carbonyl group, where R, R′ and R″ are H or hydrocarbon radicals having 1 to 18 carbon atoms.
5. A polymeric compound as claimed in claim 1 comprising, as comonomers, compounds of formula (II) wherein R w , R x and R y are H and R z is an alkyl substituent-containing aromatic or heteroaromatic substituents.
6. A polymeric compound as claimed in claim 1 comprising, as comonomers, compounds of formula (II) wherein R w , R x and R y are H and R z is —(CH 2 ) a —OR′″, where R′″ is H or an alkyl radical having 1 to 22 carbon atoms or is a polyether derived exclusively from ethylene oxide or propylene oxide or butylene oxide or styrene oxide, which represents a block or random copolymer containing said radicals, and a is 0 or 1.
7. A polymeric compound as claimed in claim 1 comprising, as comonomers, at least one compound selected from the group
C 1 -C 18 -acrylic esters, methacrylic esters or maleic mono- or diesters,;
polyethylene glycol and polypropylene glycol acrylates and methacrylates;
C 2 -C 18 -alkoxy esters of acrylic and methacrylic acid;
C 2 -C 8 -hydroxyalkyl acrylates and methacrylates;
vinyl compoundsvinyl esters, vinyl ethers, halogenated vinyl compounds, allyl vinyl ketone, 4-vinylpridine, N-vinylpyrrolidone, vinylimidazole;
amides of acrylic acid and methacrylic acid; diallyldimethylammonium chloride (DADMAC); and
allyl compounds.