Integrated catalytic cracking and desulfurization system
View Patent ↗An integrated fluid catalytic cracking (FCC) and desulfurization system for processing hydrocarbon-containing fluids. The integrated system employs a cracking/desulfurization unit having a reactor, a regenerator, and a reducer. A mixture of solid FCC catalyst particulates and solid sulfur sorbent particulates are circulated through the reactor, regenerator, and reducer to provide for substantially continuous cracking and desulfurization of the hydrocarbon-containing fluid, as well as substantially continuous regeneration of both the FCC catalyst and the sulfur sorbent.
1. A process for simultaneously cracking and desulfurizing a hydrocarbon-containing fluid in a common reaction zone, said process comprising the steps of:
(a) contacting said hydrocarbon-containing fluid with a cracking catalyst in said reaction zone under reaction conditions sufficient to crack said hydrocarbon-containing fluid; and
(b) contacting said hydrocarbon-containing fluid with a sorbent in said reaction zone under said reaction conditions to thereby remove sulfur from said hydrocarbon-containing fluid, wherein said sorbent comprises a reduced-valence promoter metal component and zinc oxide, wherein said sorbent has a Davison Index value that is less than 10.
2. A process in accordance with claim 1 , wherein said sorbent comprises perlite.
3. A process in accordance with claim 1 , wherein said reduced-valence promoter metal component comprises a substitutional solid metal solution characterized by the formula M A Zn B , wherein M is a promoter metal and A and B are each numerical values in the range of 0.01 to 0.99.
4. A process in accordance with claim 1 , wherein said reduced-valence promoter metal component is nickel.
5. A process in accordance with claim 1 , wherein the weight ratio of said cracking catalyst to said sorbent in said reaction zone is in the range of from about 0.5:1 to about 50:1.
6. A process in accordance with claim 1 , wherein said reaction conditions are sufficient to provide a cracking conversion level of at least 20 percent and wherein said reaction conditions are sufficient to reduce the sulfur content of the hydrocarbon-containing fluid at least 50 percent.