Coating composition with epoxy- polyester polymer
View Patent ↗A protective coating composition in an organic liquid carrier comprising a polymeric film forming binder, the polymeric binder comprising by weight: (a) 50% to 100% of an epoxy-polyester block copolymer being the reaction product of a preformed epoxy resin and a preformed carboxyl functional, and (b) 0 to 50% of a crosslinker where the sum of (a) and (b) is 100%, characterised in that the carboxyl functional polyester prepolymer is the reaction product of one or more polyols with one or more dicarboxylic acids or their anhydrides, where the dicarboxylic acids or anhydrides comprise a mixture of (i) 20% to 45% of an aromatic dicarboxylic acid or its anhydride, (ii) 55% to 80% of cyclohexane dicarboxylic acid, and (iii) 0 to 10% other aliphatic dicarboxylic acid, where the sum of (i), (ii), and (iii) is 100% based on the weight of the dicarboxylic acid and anhydride components.
1. A metal can protective coating composition in an organic liquid carrier comprising a polymeric film forming binder, the polymeric binder comprising by weight:
(a) 50 to 100% of an epoxy-polyester block copolymer being the reaction product of a preformed epoxy resin and a preformed carboxyl functional polyester prepolymer, having a residue of carboxy functional polyester esterified with the residue of the epoxy resin and (b) 0 to 50% of a crosslinker where the sum of (a) and (b) is 100%,
characterized in that the carboxyl functional polyester prepolymer is the reaction product of one or more polyols with one or more dicarboxylic acids or their anhydrides, where the dicarboxylic acids or anhydrides comprise a mixture of (i) 20% to 45% of an aromatic dicarboxylic acid or its anhydrides, (ii) 55 to 80% of cyclohexane dicarboxylic acid, and (iii) 0 to 10% other aliphatic dicarboxylic acid, where the sum of (i), (ii), and (iii) is 100% based on the weight of the dicarboxylic acid and anhydride components, whereby protective coatings from the protective coating composition have an amount of bisphenol A diglycidyl ether (BADGE) of less than 1 ppm.
2. A coating composition according to claim 1 which comprises 50% to 97% by weight of epoxy-polyester block copolymer and 3% to 50% by weight of the crosslinker.
3. A process of coating substrates selected from plastic, glass, metal or metal cans which comprises applying a layer of a composition as claimed in claim 1 and drying and curing it by heating.
4. A substrate selected from the group of plastic, glass or metal having a coating formed from the coating composition of claim 1 from its application to the substrate with drying and curing by heating.
5. A coating composition according to claim 1 , wherein the epoxy-polyester copolymer contains between 1 and 20 ester polymeric units.
6. A protective coating composition in an organic liquid carrier comprising a polymeric film forming binder, the polymeric binder comprising by weight:
(a) 50 to 100% of an epoxy-polyester block copolymer being the reaction product of a preformed epoxy resin and a preformed carboxyl functional polyester prepolymer; wherein the carboxyl functional polyester prepolymer is the reaction product of one or more polyols with one or more dicarboxylic acids or their anhydrides, where the dicarboxylic acids or anhydrides comprise a mixture of (i) 20% to 45% of an aromatic dicarboxylic acid or its anhydrides, (ii) 55 to 80% of cyclohexane dicarboxylic acid, and (iii) 0 to 10% other aliphatic dicarboxylic acid, where the sum of (i), (ii), and (iii) is 100% based on the weight of the dicarboxylic acid and anhydride components;
(b) 0 to 50% of a crosslinker for the sum of (a) and (b) that is 100%; and
(c) polyvinyl chloride (PVC) of a particle size of 0.5 to 12 microns, where the organic liquid carrier does not dissolve the PVC; and
where protective coatings from the protective coating composition have an amount of bisphenol A diglycidyl ether (BADGE) of less than 1 ppm.
7. A composition as claimed in claim 6 which comprises 20% to 70% of PVC based on the total weight of epoxy-polyester block copolymer plus crosslinker plus PVC.
8. A protective coating composition in an organic liquid carrier comprising a polymeric film forming binder, the polymeric binder comprising by weight:
(a) 50 to 100% of an epoxy-polyester block copolymer being the reaction product of a preformed epoxy resin and a preformed carboxyl functional polyester prepolymer; wherein the carboxyl functional polyester prepolymer is the reaction product of one or more polyols with one or more dicarboxylic acids or their anhydrides, where the dicarboxylic acids or anhydrides comprise a mixture of (i) 20% to 45% of an aromatic dicarboxylic acid or its anhydrides, (ii) 55 to 80% of cyclohexane dicarboxylic acid, and (iii) 0 to 10% other aliphatic dicarboxylic acid, where the sum of (i), (ii), and (iii) is 100% based on the weight of the dicarboxylic acid and anhydride components, wherein the epoxy-polyester block copolymer is reacted further with an organic monocarboxylic acid; and
(b) 0 to 50% of a crosslinker for the sum of (a) and (b) that is 100%.
9. A coating composition according to claim 8 where the monocarboxylic organic acid is a fatty acid.
10. A coating composition according to claim 9 where they fatty acid is coconut fatty acid.
11. A process of making a coating composition in an organic liquid carrier comprising a polymeric film forming binder, the polymeric binder comprising by weight:
(a) 50 to 100% of an epoxy-polyester block copolymer being the reaction product of a preformed epoxy resin and a preformed carboxyl functional polyester prepolymer, and (b) 0 to 50% of a crosslinker where the sum of (a) and (b) is 100%,
wherein the carboxyl functional polyester prepolymer is the reaction product of one or more polyols with one or more dicarboxylic acids or their anhydrides, where the dicarboxylic acids or anhydrides comprise a mixture of (i) 20% to 45% of an aromatic dicarboxylic acid or its anhydrides, (ii) 55 to 80% of cyclohexane dicarboxylic acid, and (iii) 0 to 10% other aliphatic dicarboxylic acid, where the sum of (i), (ii), and (iii) is 100% based on the weight of the dicarboxylic acid and anhydride components, whereby protective coatings from the protective coating composition have an amount of bisphenol A diglycidyl ether (BADGE) of less than 1 ppm which comprises the step of heating the epoxy-polyester block copolymer in the presence of phosphoric acid or a base prior to adding the block copolymer to the coating composition.
12. The process of claim 11 where the epoxy-polyester copolymer is heated with the phosphoric acid prior to adding the epoxy-polyester to the coating composition.
13. A coated plastic, glass or metal can having a coating of a protective coating composition in an organic liquid carrier comprising a polymeric film forming binder, the polymeric binder comprising by weight:
(a) 50 to 100% of an epoxy-polyester block copolymer being the reaction product of a preformed epoxy resin and a preformed carboxyl functional polyester prepolymer, and (b) 0 to 50% of a crosslinker where the sum of (a) and (b) is 100%,
characterized in that the carboxyl functional polyester prepolymer is the reaction product of one or more polyols with one or more dicarboxylic acids or their anhydrides, where the dicarboxylic acids or anhydrides comprise a mixture of (i) 20% to 45% of an aromatic dicarboxylic acid or its anhydrides, (ii) 55 to 80% of cyclohexane dicarboxylic acid, and (iii) 0 to 10% other aliphatic dicarboxylic acid, where the sum of (i), (ii), and (iii) is 100% based on the weight of the dicarboxylic acid and anhydride components, whereby protective coatings from the protective coating composition have an amount of bisphenol A diglycidyl ether (BADGE) of less than 1 ppm.