Donor sheet having a polymerizable, amorphous matrix with electrically active material disposed therein
View Patent ↗In a method of making an organic electroluminescent device, a transfer layer is solution coated on a donor substrate. The transfer layer includes a polymerizable, amorphous matrix with a light emitting material disposed in the matrix. The transfer layer is then selectively patterned on a receptor. The polymerizable, amorphous matrix is then polymerized. Examples of patterning methods include laser thermal transfer or thermal head transfer. The method and associated materials can be used to form, for example, organic electroluminescent devices.
1. A donor sheet comprising:
a substrate; and
a transfer layer disposed on the substrate, the transfer layer comprising a polymerizable, amorphous matrix and a light emitting material disposed in the matrix, wherein the polymerizable, amorphous matrix comprises at least one polymerizable, amorphous matrix-forming compound having an amorphous matrix-forming base structure and at least two polymerizable moieties coupled to the base structure, wherein the polymerizable moieties are independently selected from vinyl, perfluorovinylether, azide, pentadienyl, alkynyl, (meth)acrylate, phenylalkynyl, isocyanato, benzocyclobutane, hydroxyl, oxetane, thiirane, epoxide, and alkoxysilane moieties, wherein the base structure is selected from
wherein each R is independently a substituent comprising at least one functional group selected from alkenyl, alkenylene, aryl, arylene, heteroaryl, and heteroarylene, and further wherein the transfer layer is capable of being selectively thermally transferred from the donor sheet to a proximally located receptor.
2. The donor sheet of claim 1 , further comprising a light-to-heat conversion layer disposed between the substrate and the transfer layer.
3. The donor sheet of claim 1 , wherein the light emitting material comprises a light emitting polymer.
4. The donor sheet of claim 1 , wherein the light emitting material comprises a phosphorescent material.
5. A donor sheet comprising:
a substrate; and
a transfer layer disposed on the substrate, the transfer layer comprising: a polymerizable, amorphous matrix comprising at least one polymerizable, amorphous matrix-forming compound having an amorphous matrix-forming base structure and at least two polymerizable moieties coupled to the base structure, wherein the polymerizable moieties are independently selected from vinyl, perfluorovinylether, azide, pentadienyl, alkynyl, (meth)acrylate, phenylalkynyl, isocyanato, benzocyclobutane, hydroxyl, oxetane, thiirane, epoxide, and alkoxysilane moieties, wherein the base structure is selected from
wherein each R is independently a substituent comprising at least one functional group selected from alkenyl, alkenylene, aryl, arylene, heteroaryl, and heteroarylene, and
further wherein the transfer layer is capable of being selectively thermally transferred from the donor sheet to a proximally located receptor.
6. The donor sheet of claim 1 , wherein the light emitting material comprises a small molecule emitter.
7. The donor sheet of claim 1 , wherein the light emitting material comprises a fluorescent material.