Dispersant composition
View Patent ↗The present invention provides a sulfonated coal tar distillate salt polymer that is a condensation product of an aldehyde, preferably formaldehyde, and a sulfonated middle fraction obtained during coal tar distillation. The middle fraction includes from about 40% to about 95% by weight naphthalene and from about 5% to about 60% by weight of a plurality of compounds selected from the group consisting of quinoline, indene, biphenyl, indane, acenaphthene, anthracene, phenanthrene, methyl naphthalene, cresol, phenol, xylenol, and tetralin. The present invention also provides a method of forming a sulfonated coal tar distillate salt polymer. The method includes sulfonating the middle fraction to form a middle fraction sulfonic acid mass, optionally adding a first portion of water to the middle fraction sulfonic acid mass to form a mixture, reacting the mixture and an aldehyde to form a condensate, optionally adding a second portion of water to dilute the condensate, and adding a base to form a sulfonated middle fraction salt polymer. Sulfonated middle fraction salt polymers formed in accordance with the method of the invention are useful as dispersants and plasticizers in aqueous cementitious slurries.
1. An aqueous cementitious slurry comprising a hydratable solids portion and a dispersant comprising a sulfonated coal tar distillate salt polymer comprising a condensation product of an aldehyde and a sulfonated middle fraction comprising from about 40% to about 95% by weight naphthalene and from about 5% to about 60% by weight of a plurality of compounds selected from the group consisting of quinoline, indene, biphenyl, indane, acenaphthene, anthracene, phenanthrene, methyl naphthalene, cresol, phenol, xylenol, and tetralin.
2. The aqueous cementitious composition according to claim 1 wherein the hydratable solids portion comprises gypsum.
3. The aqueous cementitious composition according to claim 1 wherein the hydratable solids portion comprises Portland cement.
4. The aqueous cementitious composition according to claim 1 wherein the aqueous cementitious composition hardens to form concrete.
5. The cementitious composition according to claim 1 wherein the aqueous cementitious composition hardens to form mortar.
6. The cementitious composition according to claim 1 wherein the middle fraction that is used to prepare the sulfonated middle fraction distills at a temperature of from about 200±10° C. to about 250±10° C.