Co-retarding agents for preparing purified brine
View Patent ↗The invention relates to a process to produce brine of improved purity by dissolving salt that contains a calcium sulfate source in water, in the presence of a retarding agent, while using one or more co-retardants to bind contaminants that could interfere with the retarding agents.
1. A process to make brine, by dissolving a NaCl salt source comprising a source of alkaline-earth metal sulfate in water, in the presence of at least one retarding agent to reduce the amount of alkaline-earth metal sulfate dissolved in said brine, wherein a co-retardant selected from the group consisting of flocculants, lignosulfonate polymers, (graft)copolymers of lignosulfonate and acrylic acid, polyacrylic acid, polyacrylamides, and biopolymers, and modified starch is used prior and/or during the dissolution step in an amount of from 0.1 mg/kg to 0.2 % by weight, based on the weight of the water, and wherein said at least one retarding agent has a performance such that a retardation of the dissolution (in g/l) is achieved of at least one of the alkaline-earth metal ions and/or sulfate ions of more than 20% when compared to a dissolution step wherein no retarding agent is used.
2. A process according to claim 1 , wherein the co-retardant is used in an amount of less than 0.1% by weight of the water.
3. A process as claimed in claim 2 wherein the co-retardant is used in an amount of less than 0.05% by weight of the water.
4. A process as claimed in claim 2 wherein the co-retardant is used in an amount of less than 0.02%, by weight of the water.
5. A process according to claim 1 wherein the retarding agent is selected from the group consisting of:
phospholipides,
hydrolyzed phospholipids,
alkylbenzene sulfonates, whereof the alkyl groups are linear or branched,
phosphates that are water-soluble,
ethoxylated compounds with one or more sulfite, sulfonate, sulfate, phosphite, phosphonate, phosphate, and/or carboxylgroups, and C 2 -C 40 alkyl compounds with one or more sulfite, sulfonate, sulfate, phosphite, phosphonate, phosphate, and/or carboxyl groups.
6. A brine obtained from the process of any one of claims 1 , 2 and 5 comprising traces of at least one retarding agent and of co-retardant.
7. An electrolysis process or evaporative crystallization process wherein the brine according to claim 6 is used, optionally after an additional purification step.
8. An electrolysis process as claimed in claim 7 which is a mercury, diaphragm, membrane, or chlorate electrolysis process.
9. An electrolysis process as claimed in claim 7 which is a membrane electrolysis process.