Thermoplastic resin composition
View Patent ↗The present invention relates to a thermoplastic resin composition which has an improved impact resistance while maintaining mechanical properties such as strength and rigidity. In the present invention, a thermoplastic resin (A) is mixed with a polytetrafluoroethylene-containing mixed powder (B) consisting of a polytetrafluoroethylene (b1) having a particle diameter of 10 μm or less and an organic polymer (b2). In this case, the polytetrafluoroethylene-containing mixed powder (B) is mixed so that the amount of a polytetrafluoroethylene component is from 0.0001 to 20 parts by weight based on 100 parts by weight of the thermoplastic resin (A), and a polymer having an epoxy group was used as the organic polymer (b2). The thermoplastic resin composition of the present invention can be widely used in the fields of automotive parts, electric and electronic parts, and precision instrument parts.
1. A thermoplastic resin composition comprising a thermoplastic resin (A) and a polytetrafluoroethylene-containing mixed powder (B) comprising:
a polytetrafluoroethylene (b1) having a particle diameter of 10 μm or less and
an organic polymer (b2),
wherein the polytetrafluoroethylene-containing mixed powder (B) is mixed so that the amount of a polytetrafluoroethylene component is from 0.0001 to 20 parts by weight based on 100 parts by weight of the thermoplastic resin (A), and
the organic polymer (b2) is a polyorganosiloxane graft copolymer which is prepared by graft-polymerizing a composite rubber comprising a polyorganosiloxane rubber and a polyalkyl (meth)acrylate rubber with one or more vinyl monomers containing at least one epoxy group-containing vinyl monomer.
2. The thermoplastic resin composition according to claim 1 , wherein the thermoplastic resin (A) comprises, as a main component, one or more thermoplastic resins selected from the group consisting of polyester resin, polyamide resin, polyarylene sulfide resin, and polyolefin resin.
3. A polytetrafluoroethylene-containing mixed powder comprising a polytetrafluoroethylene having a particle diameter of 10 μm or less and an organic polymer, wherein the organic polymer is a polyorganosiloxane graft copolymer which is prepared by graft-polymerizing a composite rubber comprising a polyorganosiloxane rubber and a polyalkyl (meth)acrylate rubber with one or more vinyl monomers containing at least one epoxy group-containing vinyl monomer.
4. A thermoplastic resin composition comprising a thermoplastic resin (A) and a polytetrafluoroethylene-containing mixed powder (B) consisting of a polytetrafluoroethylene (b1) having a particle diameter of 10 μm or less and an organic polymer (b2), wherein
the polytetrafluoroethylene-containing mixed powder (B) is mixed so that the amount of a polytetrafluoroethylene component is from 0.0001 to 20 parts by weight based on 100 parts by weight of the thermoplastic resin (A), and
the organic polymer (b2) is a rubber-like polymer having an epoxy group.
5. A thermoplastic resin composition comprising a thermoplastic resin (A) and a polytetrafluoroethylene-containing mixed powder (B) consisting of a polytetrafluoroethylene (b1) having a particle diameter of 10 μm or less and an organic polymer (b2), wherein
the polytetrafluoroethylene-containing mixed powder (B) is mixed so that the amount of a polytetrafluoroethylene component is from 0.0001 to 20 parts by weight based on 100 parts by weight of the thermoplastic resin (A), and
the organic polymer (b2) is a polymer having an epoxy group; wherein the thermoplastic resin (A) is at least one or more thermoplastic resins selected from the group consisting of polyester resin, polyamide resin, polyarylene sulfide resin, and polyolefin resin.
6. The thermoplastic resin composition according to claim 5 , wherein the organic polymer is a polyorganosiloxane graft copolymer which is prepared by graft polymerizing a composite rubber comprising a polyorganosiloxane rubber and a polyalkyl (meth)acrylate rubber with one or more vinyl monomers containing at least one epoxy group containing vinyl monomer.