Method for producing soft magnetic hexagonal ferrite sintered material and soft magnetic hexagonal ferrite sintered material
View Patent ↗A soft hexagonal ferrite sintered material includes crystal particles of M-type hexagonal ferrite corresponding to a general chemical formula MFe 12 O 19 wherein M is at least one element selected from the group consisting of Ba, Sr and Pb. Crystal particles having particle diameters of 5 μm to 100 μm are extracted from a sintered material produced from a precursor powder mixture. The extracted particles as seed crystals are mixed with a calcined powder comprising fine crystals having the above composition and particle diameters of 0.5 μm to 3 μm, then is sintered until the intended particle growth of the crystal particles in the sintered material is achieved to give an average particle diameter of 30 μm to 500 μm.
1. A method for producing a soft magnetic hexagonal ferrite sintered material composed of crystal particles of M-type hexagonal ferrite corresponding to a general chemical formula MFe 12 O 19 wherein M is at least one element selected from the group consisting of Ba, Sr and Pb, the method comprising the steps of:
preparing a M-type hexagonal intermediate ferrite sintered material from a precursor powder mixture having a general chemical formula MFe 12 O 19 where M is the at least one element selected from the group consisting of Ba, Sr and Pb;
decomposing the intermediate sintered material by acid treating the intermediate sintered material to dissolve particle boundaries therein, thereby obtaining powder of flat particles of M-type hexagonal ferrite;
extracting powder having particle diameters of 5 μm to 100 μm to be used as seed crystals from the powder of flat particles;
preparing a mixture of the seed crystals and fine powder of M-type hexagonal ferrite having particle diameters of less than 5 μm; and
orienting the seed crystals in the mixture and subsequently sintering the mixture until the seed crystals grow to have an average particle diameter of 30 μm to 500 μm.
2. The method for producing a soft magnetic hexagonal ferrite sintered material according to claim 1 , wherein the mixing ratio of the seed crystals in the mixture is 3% by weight to 20% weight seed crystals, and the fine powder of M-type hexagonal ferrite includes fine crystals having particle diameters of 0.5 μm to 3 μm.
3. The method for producing a soft magnetic hexagonal ferrite sintered material according to claim 1 , further comprising the steps of:
rolling the mixture to form a sheet of the mixture; and
stacking a plurality of the sheets in layers, thereby orienting the seed crystals in the layers.
4. The method for producing a soft magnetic hexagonal ferrite sintered material according to claim 1 , wherein the intermediate sintered material is acid treated with an acid selected from the group consisting of hydrochloric acid, nitric acid, sulfuric acid, and a mixture thereof.
5. The method for producing a soft magnetic hexagonal ferrite sintered material according to claim 1 , wherein at least one auxiliary process selected from the group consisting of heat treatment, ultrasonication and adding a pro-oxidant is performed to the intermediate sintered material during the process of acid treating the intermediate sintered material.