Method for producing refined ethylene sulfite
View Patent ↗Refined ethylene sulfite exhibits an excellent storage stability when used as a constituent of an electrolyte. A method of producing same has a step of reacting ethylene glycol and thionyl chloride to producing raw ethylene sulfite, a rectifying step for rectifying the raw ethylene sulfite, and a refining process for refining the raw ethylene sulfite or the rectified ethylene sulfite conducted before or after the rectifying step. The refining process is at least one process selected from the group consisting of a washing process, a dehydration process by total reflux distillation, a second rectifying process, and an absorbing process. Refined ethylene sulfite produced according to the method contains chloroethanol in an amount of not more than 1000 ppm.
1. A method of refining raw ethylene sulfite comprising:
reacting ethylene glycol with thionyl chloride,
rectifying a material obtained by reacting ethylene glycol with thionyl chloride, and
applying further at least one process selected from the group consisting of washing with basic water, dehydration by refluxing, distillation and absorption.
2. A method for producing ethylene sulfite as set forth in claim 1 , wherein said method further comprises a simple distillation process of said raw ethylene sulfite or rectified ethylene sulfite which is conducted before said refining process.
3. A method for producing ethylene sulfite as set forth in claim 1 , wherein said absorbing process employs at least one absorbent selected from the group consisting of complex metal oxide, activated carbon and metal oxide.
4. A method of refining raw ethylene sulfite comprising:
reacting ethylene glycol with thionyl chloride,
applying a material obtained by reacting ethylene glycol with thionyl chloride, with at least one process selected from the group consisting of washing with basic water, dehydration by refluxing, distillation, and absorption, and
rectifying further a material thus obtained.
5. A method for producing ethylene sulfite as set forth in claim 4 , wherein said method further comprises a simple distillation process of said raw ethylene sulfite or rectified ethylene sulfite which is conducted before said refining process.
6. A method for producing ethylene sulfite as set forth in claim 4 , wherein said absorbing process employs at least one absorbent selected from the group consisting of complex metal oxide, activated carbon and metal oxide.