Heat resistant pipe and method of manufacture thereof
View Patent ↗A heat resistant pipe is formed from a composition comprising polyphenylene ether resin and polystyrene resin. Pipes made from this composition possess superior thermal and pressure resistance. Their impact resistance and thermal expansion characteristics permit them to be utilized advantageously in all environments and during all seasons with little risk of failure.
1. A heat resistant pipe formed from a composition comprising based on the total weight of the composition:
about 5 to about 95 wt % polyphenylene ether resin;
about 5 to about 95 wt % polystyrene resin; and
an impact modifier selected from polyisoprenes, polybutadienes, polyacrylics, polyesters, acrylic acid-butadiene-styrene copolymers, and ethylene-propylene copolymers wherein the impact modifier is present at up to 7 wt %.
2. A heat resistant pipe formed from a composition consisting essentially of based on the total weight of the composition:
about 5 to about 95 wt % polyphenylene ether resin;
about 5 to about 95 wt % polystyrene resin; and
an additive selected from the group consisting of fibrous fillers, non-fibrous filers, antistatic agents, ultraviolet absorbers, flame retardants, and mixtures thereof.
3. A method of forming a pipe, comprising:
melt blending a composition comprising about 5 to about 95 wt % polyphenylene ether resin; about 5 to about 95 wt % polystyrene resin; and an impact modifier selected from polyisoprenes, polybutadienes, polyacrylics, polyesters, acrylic acid-butadiene-styrene copolymers, and ethylene-propylene copolymers; wherein the impact modifier is present at up to 7 weight percent; and
molding the molt blend.
4. A method of forming a pipe, comprising:
melt blending a composition consisting essentially of about 5 to about 95 wt % polyphenylene ether resin, about 5 to about 95 wt % polystyrene resin; and an additive selected from the group consisting of fibrous fillers, non-fibrous fillers, antistatic agents, ultraviolet absorbers, and mixtures thereof; and
molding the melt blend.
5. The heat resistant pipe of claim 1 , wherein the polyphenylene ether resin is selected from the group consisting of poly(2,6-dimethyl-1,4-phenylene)ether, poly(2,6-diethyl-1,4-phenylene)ether, poly(2-methyl-6-ethyl-1,4-phenylene)ether, poly(2-methyl-6-propyl-1,4-phenylene)ether, poly(2,6-dipropyl-1,4-phenylene)ether, poly(2-ethyl-6-propyl-1,4-phenylene)ether, poly(2,6-dimethoxy-1,4-phenylene)ether, poly(2,6-dichloromethyl-1,4-phenylene)ether, poly(2,6-dibromomethyl-1,4-phenylene)ether, poly(2,6-diphenyl-1,4-phenylene)ether, poly(2,6-ditolyl-1,4-phenylene)ether, poly(2,6-dichloro-1,4-phenylene)ether, poly(2,6-dibenzyl-1,4-phenylene)ether, poly(2,5-dimethyl-1,4-phenylene)ether, poly(2,6-dimethyl-1,4-phenylene-co-2,3,6-trimethyl-1,4-phenylene)ether, and combinations thereof.
6. The heat resistant pipe of claim 1 , wherein the polystyrene resin is selected from the group consisting of homopolystyrene, high impact polystyrene, and syndiotactic polystyrene.
7. The heat resistant pipe of claim 1 , wherein the polystyrene resin is syndiotactic polystyrene.
8. The heat resistant pipe of claim 1 , wherein the polystyrene resin is recycled resin.
9. The heat resistant pipe of claim 1 , wherein the composition further comprises a flame retardant.
10. The heat resistant pipe of claim 2 , wherein the polyphenylene ether resin is selected from the group consisting of poly(2,6-dimethyl-1,4-phenylene)ether, poly(2,6-diethyl-1,4-phenylene)ether, poly(2-methyl-6-ethyl-1,4-phenylene)ether, poly(2-methyl-6-propyl-1,4-phenylene)ether, poly(2,6-dipropyl-1,4-phenylene)ether, poly(2-ethyl-6-propyl-1,4-phenylene)ether, poly(2,6-dimethoxy-1,4-phenylene)ether, poly(2,6-dichloromethyl-1,4-phenylene)ether, poly(2,6-dibromomethyl-1,4-phenylene)ether, poly(2,6-diphenyl-1,4-phenylene)ether, poly(2,6-ditolyl-1,4-phenylene)ether, poly(2,6-dichloro-1,4-phenylene)ether, poly(2,6-dibenzyl-1,4-phenylene)ether, poly(2,5-dimethyl-1,4-phenylene)ether, poly(2,6-dimethyl-1,4-phenylene-co-2,3,6-trimethyl-1,4-phenylene)ether, and combinations thereof.
11. The heat resistant pipe of claim 2 , wherein the polystyrene resin is selected from the group consisting of homopolystyrene, high impact polystyrene, and syndiotactic polystyrene.
12. The heat resistant pipe of claim 2 , wherein the polystyrene resin is syndiotactic polystyrene.
13. The heat resistant pipe of claim 2 , wherein the polystyrene resin is recycled resin.
14. The heat resistant pipe of claim 2 , wherein the composition further comprises an impact modifier selected from polyisoprenes, polybutadienes, polyacrylics, polyesters, acrylic acid-butadiene-styrene copolymers, a ethylene-propylene copolymers; wherein the impact modifier is present at up to 7 wt %.
15. The heat resistant pipe of claim 2 ,
wherein the polyphenylene ether is poly(2,6-dimethyl-1,4-phenylene)ether, poly(2,6-di-ethyl-1,4-phenylene)ether, poly(2,6-dimethyl-1,4-phenylene-co-2,3,6-trimetheyl-1,4-phenylene)ether, or a combination thereof;
wherein the polystyrene is syndiotactic polystyrene; and
wherein the composition further comprises a flame retardant.
16. The method of forming a pipe of claim 3 , wherein the melt blending is carried out in a melt blender selected from the group consisting of an extruder, buss kneader, roll mill, ball mill, and combinations comprising a least one of the foregoing melt blenders.
17. The method of forming a pipe of claim 3 , wherein the molding is accomplished by injection molding, extrusion molding, blow molding, or vacuum forming.
18. The method of forming a pipe of claim 4 , wherein the melt blending is carried out in a melt blender selected from the group consisting of an extruder, buss kneader, roll mill, ball mill, and combinations comprising at least one of the foregoing melt blenders.
19. The method of forming a pipe of claim 4 , wherein the molding is accomplished by injection molding, extrusion molding, blow molding, or vacuum forming.