Weatherable resin compositions having low gloss appearances
View Patent ↗A low gloss thermoplastic molding composition comprising a grafted acrylate rubber (ASA) and a process for its preparation are disclosed. The composition contains an effective amount of a gloss-reducing agent that is the reaction product of (i) compound having two or more maleic anhydride groups per molecule and (ii) compound having two or more terminal primary amine groups per molecule. The incorporation of the gloss reducing agent in the inventive composition may be by blending the reaction product or, in the alternative, blending the reactants (i) and (ii) in the molten ASA under process conditions designed to bring about the in situ formation of the inventive gloss reducing agent.
1. A thermoplastic molding composition comprising a grafted acrylate rubber and an effective amount of a gloss reducing agent, said agent being the reaction product of
(i) a compound having two or more maleic anhydride groups per molecule, and
(ii) a compound having two or more terminal primary amine groups per molecule wherein
the grafted acrylate rubber is present in the composition in an amount of at least 85% and less than 98.4% and the gloss reducing agent is present in an amount greater than 1.6% and up to 15% the percents being relative to the weight of the composition.
2. The thermoplastic molding composition of claim 1 wherein the grafted acrylate rubber is present in the composition in an amount of 88 to 98% and the gloss reducing agent is present in an amount of 2% to 12% the percents being relative to the weight of the composition.
3. The thermoplastic molding composition of claim 1 wherein the grafted acrylate rubber is present in the composition in an amount of 92 to 97.9% and the gloss reducing agent is present in an amount of 2.1 to 8% the percents being relative to the weight of the composition.
4. The thermoplastic molding composition of claim 1 wherein the maleic anhydride compound is a compound having a number average molecular weight of at least 2000 g/mole.
5. The thermoplastic molding composition of claim 4 wherein the maleic anhydride compound includes in its molecular structure elements derived from (a) at least one vinyl monomer that contains no maleic anhydride functionality and (b) at least one maleic anhydride functional group.
6. The thermoplastic molding composition of claim 4 wherein the maleic anhydride compound has a number average molecular weight of 25,000 to 100,000 g/mole.
7. The thermoplastic molding composition of claim 4 wherein the maleic anhydride compound has a number average molecular weight of 3,000 to 75,000 g/mole.
8. The thermoplastic molding composition of claim 4 wherein the maleic anhydride compound contains 2 maleic anhydride functional groups per molecule.
9. The thermoplastic molding composition of claim 4 wherein the maleic anhydride compound contains 2 to 200 anhydride functional groups per molecule.
10. The thermoplastic molding composition of claim 4 wherein
the maleic anhydride compound contains 5 to 180 anhydride functional groups per molecule.
11. The thermoplastic molding composition of claim 5 wherein
(a) is a member selected from the group consisting of ethylene, propylene, styrene, acrylonitrile, (meth)acrylic acid ester, and vinyl acetate.
12. The thermoplastic molding composition of claim 1 wherein the maleic anhydride compound is a member selected from the group consisting of styrene-methyl methacrylate-maleic anhydride and styrene-maleic anhydride copolymers.
13. The thermoplastic molding composition of claim 1 wherein the amine compound contains polyolefinic or polyether structural elements.
14. The thermoplastic molding composition of claim 1 wherein the amine compound contains structural units derived from at least one member selected from the group consisting of polyethylene, polypropylene and polyether.
15. The thermoplastic molding composition of claim 1 wherein the amine compound contains structural units derived from polypropylene oxide.
16. The thermoplastic molding composition of claim 1 wherein the amine compound has number average molecular weight of 300 to 18,0000.
17. The thermoplastic molding composition of claim 1 wherein the amine compound has number average molecular weight of 400 to 15,000.
18. The thermoplastic molding composition of claim 1 wherein the amine compound has number average molecular weight of 700 to 10,000.
19. The thermoplastic molding composition of claim 1 wherein the amine compound is polypropylene oxide having a molecular weight of 4000 to 6000 and containing 3 terminal primary amine functional groups per molecule.