IP Library Granted Patent US 6,960,278
Granted Patent B2
US 6,960,278 · App. 10/234,255 · Granted Nov 1, 2005

Method of improving the properties of adhesion of a non-oxide ceramic substrate before gluing it

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Quick Facts
Patent No.
US 6,960,278
App. No.
10/234,255
Granted
Nov 1, 2005
Kind
B2
Abstract

A method of improving the properties of adhesion of a non-oxide ceramic substrate before gluing it includes the steps of irradiating the surface of the ceramic substrate using an excimer laser and applying a coupling agent to the irradiated surface.

Claims (21)

1. A method of improving the properties of adhesion of a non-oxide ceramic substrate before gluing part of a surface of the substrate, which substrate has disposed on another face thereof at least one power semiconductor component prior to performing the method, which method comprises the following steps:

irradiating the surface of said ceramic substrate to be glued using an excimer laser in order to modify the chemical bonds, and

applying a coupling agent to the irradiated surface leading to the formation of a chemical bond between the coupling agent and the oxidized surface resulting from the irradiation of the ceramic substrate.

2. The method claimed in claim 1 , wherein the energy density supplied by said excimer laser is from 0.5 to 2 J/cm 2 at a frequency from 1 to 100 Hz.

3. The method claimed in claim 1 , wherein said laser is a KrF excimer laser emitting at 248 nm.

4. The method claimed in claim 1 , wherein said laser is an ArF excimer laser emitting at 193 nm.

5. The method claimed in claim 1 , wherein said substrate is made of AlN, SiC or Si 3 N 4 .

6. The method claimed in claim 1 , wherein said coupling agent is an aqueous silane solution.

7. A method of assembly, comprising:

irradiating the surface to be glued of a non-oxide ceramic substrate using an excimer laser;

applying a coupling agent to the irradiated surface leading to the formation of a chemical bond between the coupling agent and the irradiated surface; and

gluing the ceramic substrate to a cooling liquid manifold by applying a modified epoxy resin to an interface of the coupling agent-covered surface of the ceramic substrate and the cooling manifold.

8. The method claimed in claim 7 , wherein said cooling liquid manifold is made of polyetherimide.

9. A method of improving the properties of adhesion of a non-oxide ceramic substrate before gluing said substrate, which method comprises the following steps:

irradiating the surface of said ceramic substrate to be glued using an excimer laser in order to modify the chemical bonds; and

applying a coupling agent to the irradiated surface leading to the formation of a chemical bond between the coupling agent and the oxidized surface resulting from the irradiation of the ceramic substrate;

wherein said coupling agent is an aqueous silane solution.

10. A method of improving the properties of adhesion of a non-oxide ceramic substrate before gluing said substrate, which method comprises the following steps:

irradiating the surface of said ceramic substrate to be glued using an excimer laser in order to modify the chemical bonds;

applying a coupling agent to the irradiated surface leading to the formation of a chemical bond between the coupling agent and the oxidized surface resulting from the irradiation of the ceramic substrate; and

applying a glue to part of the coupling agent-covered surface.

Assignments (5)
CHANGE OF ADDRESS Recorded Jul 31, 2017
From: ALSTOM TRANSPORT TECHNOLOGIES
To: ALSTOM TRANSPORT TECHNOLOGIES
Reel/Frame 043382/0290 →
CORRECTIVE ASSIGNMENT TO REMOVE ERRONEOUS FILED PATENT NO. 6250442 PREVIOUSLY RECORDED AT REEL: 035455 FRAME: 0513. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Aug 10, 2015
From: ALSTOM TRANSPORT SA
To: ALSTOM TRANSPORT TECHNOLOGIES
Reel/Frame 036344/0852 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 20, 2015
From: ALSTOM TRANSPORT SA
To: ALSTOM TRANSPORT TECHNOLOGIES
Reel/Frame 035455/0513 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 14, 2015
From: ALSTOM
To: ALSTOM TRANSPORT SA
Reel/Frame 035422/0967 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 30, 2002
From: PETITBON, ALAIN; EVIEUX, JEROME; BAZIARD, YVES
To: ALSTOM
Reel/Frame 013449/0516 →