Solar thermal aerosol flow reaction process
View Patent ↗The present invention provides an environmentally beneficial process using concentrated sunlight to heat radiation absorbing particles to carry out highly endothermic gas phase chemical reactions ultimately resulting in the production of hydrogen or hydrogen synthesis gases.
1. A method for carrying out an environmentally benign high temperature chemical reaction to produce H 2 or synthesis gas for use as a “clean fuel”, comprising:
a) providing heat absorbing particles flowing in a gas stream comprising at least one reactant gas;
b) heating said heat absorbing particles by direct solar thermal heating;
c) allowing the hot particles to transfer heat to said flowing gas stream and heating said gas to a sufficiently elevated temperature for a sufficient residence time to carry out said reaction; wherein said chemical reaction is a dissociation reaction or reforming reaction.
2. The method of claim 1 , wherein said dissociation reaction dissociates natural gas to produce hydrogen gas, carbon, and residual hydrocarbon species.
3. The method of claim 2 wherein the carbon particles are amorphous and have particle sizes between 20 to 40 nanometers.
4. The method of claim 1 , wherein said dissociation reaction dissociates hydrogen sulfide to produce hydrogen and sulfur.
5. The method of claim 1 , wherein said reforming reaction reforms natural gas with carbon dioxide to produce a synthesis gas mixture of hydrogen and carbon monoxide.
6. The method of claim 1 wherein said absorbing particles comprises carbon; and wherein said carbon particles are generated by decomposition of acetylene or natural gas.
7. The method of claim 6 wherein said carbon particles are generated in-situ by the reaction.
8. The method of claim 1 wherein said process is carried out in an aerosol tube having a non-transparent wall section and a transparent or semi-transparent wall section; wherein said solar thermal heating enters the aerosol tube from the transparent or semi-transparent section of the tube; and wherein the non-transparent section of the aerosol tube is coated with a reflective material to maintain concentrated sunlight within said tube.
9. The method of claim 8 wherein said aerosol tube comprises material selected from graphite, quartz, and combinations thereof.
10. The method of claim 8 wherein said aerosol tube comprises inner graphite tube within an outer tube oriented in a concentric arrangement, and wherein said outer tube is at least partially transparent.
11. The method of claim 8 wherein said aerosol tube comprises inner graphite tube within an outer tube in a concentric arrangement, and wherein said outer tube comprises quartz or a transparent window.
12. The method of claim 8 wherein said transparent wall section has a circular spot, a concentric cylinder, or linear slot shape along the is of the aerosol tube.
13. The method of claim 1 wherein said elevated temperature is in the range of 500° K. to 3000° K.
14. The method of claim 13 wherein said elevated temperature is 2300° K.
15. The method of claim 1 wherein the absorbing particles are heated within an internal graphite tube by solar thermal radiation.
16. The method of claim 1 wherein said chemical reaction produces hydrogen gas.
17. The method of claim 1 wherein said as stream further comprises a product of said reaction.
18. The method of claim 1 wherein said stream comprises at least one component selected from the group consisting of methane, hydrogen, hydrogen sulfide, carbon monoxide, carbon dioxide, and water vapor.
19. The method of claim 1 wherein said heating rate is in the range of 1,000° K./second to 100,000,000° K./second.
20. The method of claim 1 wherein said residence time is 0.001 to 10 seconds.
21. The method of claim 20 wherein said residence time is 0.01 to approximately 0.64 seconds.
22. A method of carrying out a high temperature chemical reaction in a graphite transport tube comprising the steps of:
providing heat absorbing particles flowing in a gas stream comprising at least one reactant gas;
heating said heat absorbing particles by solar-thermal heating;
allowing the hot particles to transfer heat to said flowing gas stream and heating said gas to a sufficiently elevated temperature and for a sufficient residence time to carry out said reaction; wherein the said residence time is 0.001 to 1 seconds and the elevated temperature is in the range of 1500 K. to 1400K.
23. A method for carrying out an environmentally benign high temperature chemical reaction to produce H 2 or synthesis gas for use as a “clean fuel”, comprising:
a) providing heat absorbing particles flowing in a gas stream comprising at least one reactant gas;
b) heating said heat absorbing particles by direct solar thermal heating;
c) allowing the hot particles to transfer heat to said flowing gas stream heating said gas to a sufficiently elevated temperature for a sufficient residence time to carry out said reaction; wherein said chemical reaction is a reduction reaction.
24. The method of claim 23 , wherein said reduction reaction reduces water vapor with carbon to produce a synthesis gas mixture of hydrogen and carbon monoxide.